Monarch 100 Insecticide

Hazard statements (CLP)

H302, H312, H315, H317, H320, H332, H335, H372, H410

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

SUSMP Classification

S5

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER Acute Toxicity Oral Category 4 Acute Toxicity Dermal Category 4 Skin Irritation Category 2 Skin Sensitisation Category 1 Serious eye irritation Category 2B Acute Toxicity Inhalation Category 4 Specific Target Organ Toxicity - Single Exposure Category 3 Specific Target Organ toxicity - repeated exposure Category 1 Hazardous to aquatic environment Short term/Chronic Category 1

Hazard statements

H302: Harmful if swallowed. H312: Harmful in contact with skin. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H320: Causes eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H372: Causes damage to organs through prolonged or repeated exposure. H410: Very toxic to aquatic life with long lasting effects.

Prevention

P102: Keep out of reach of children. P260: Do not breathe fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P314: Get medical advice or attention if you feel unwell. P352: Wash with plenty of soap and water. P362: Take off contaminated clothing and wash before reuse. P301+P312 IF SWALLOWED Call a POISON CENTRE or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: Not combustible. Use extinguishing media suited to burning materials.

Storage

P405: Store locked up. P410: Protect from sunlight. P403+P233: Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Off-white to brown liquid suspension. Odour: No data re odour.

Health hazards

In a toxicity study involving rats, the clinical signs of toxicity did not reach their peak until two days after treatment in some animals, and deaths did not occur until four days after treatment. Some signs of toxicity and body-weight loss were still evident when the observation period ended at day 7 after treatment. In rabbits, skin contact Fipronil induced deaths and one or more clinical signs of toxicity including convulsions, sluggishness, salivation, spasms, tremors, hyperactivity, diarrhoea, emaciation, and perioral and perinasal red discolouration in all groups except that at the lowest dose (100 mg/kg). Clinical signs of oral toxicity included tremors and convulsions of various types, effects on activity or gait, hunched posture, wetness in various body areas, and seizures. LD50 (Oral), Rat 92mg/kg LD50 (Oral), Mouse 91mg/kg LD50 (Dermal), Rat >2000mg/kg LD50 (Dermal), Rabbit 445mg/kg LC50 (Inhal, 4hr), Mouse 0.36-0.42mg/kg This product is harmful by inhalation, in contact with skin, and if swallowed, irritating to eyes and skin, possible skin sensitiser.