Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
N/A
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
General Information
Revision date
2014-03-21
Product name
TSE-EcoWῑnd T211A
Manufacturer Name
TSE Industries, Inc
Icons in SDS
Company Information
company name
TSE Industries, Inc
Section 2
SECTION 2: Hazards identification
Emergency Overview Musty smelling, brown liquid with sensitization potential. Burns, but is not ignited easily. Eye Contact: Flush eyes with copious amounts of water, preferably lukewarm, for at least 15 minutes and seek medical attention. Skin Contact: Remove contaminated clothing and wash contact area thoroughly with soap and water. Wash contaminated clothing thoroughly before reuse. Ingestion: DO NOT INDUCE VOMITING. Give 1 to 2 cups of milk or water to drink. DO NOT GIVE ANYTHING TO AN UNCONSCIOUS PERSON. Seek medical attention immediately. Inhalation: Move to an area free from risk of further exposure. Administer oxygen or artificial respiration as needed. Obtain medical attention. The following ratings are subjective. They are provided as a quick hazard guide only. Read the entire MSDS before using the product. Hazard Rating System: Health Flammability Reactivity Incompatibility PPE NFPA: 3 1 See Section 5 & 10 -- HMIS: 3* 1 -- X 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe, * = chronic health hazard
Potential health effects
Signs, and Symptoms of Exposure
Principle Routes of Exposure
Skin contact from liquid and aerosols. Inhalation although MDI is low in volatility, an inhalation hazard can exist from MDI aerosols or vapors formed during heating, foaming or spraying. Acute Inhalation: MDI vapors or mist at concentrations above the TLV can irritate (burning sensation) the mucous membranes in the respiratory tract (nose, throat, lungs) causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced lung function (breathing obstruction). Persons with a pre-existing, non-specific bronchial hyper-reactivity can respond to concentrations below the TLV with similar symptoms as well as asthma attack. Exposure well above the TLV may lead to bronchitis, bronchial spasm and pulmonary edema (fluid in lungs). These effects are usually reversible. Chemical or hypersensitive pneumonitis, with flu-like symptoms (e.g., fever, chills) has also been reported. These symptoms can be delayed up to several hours after exposure. Chronic Inhalation: With repeated overexposures or a single large dose, certain individuals develop isocyanate sensitization (chemical asthma) which may cause them to react to a later exposure at levels well below the TLV. These symptoms, which can include chest tightness, wheezing, cough, shortness of breath or asthma attack, could be immediate or delayed (up to several hours after exposure). Similar to many non-specific asthmatic responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust, cold air or other irritants. This increased lung sensitivity can persist for weeks and in severe cases for several years. Overexposure to isocyanates has also been reported to cause lung damage (including decrease in lung function) which may be permanent. Sensitization can be either temporary or permanent. Acute Skin Contact: Isocyanates react with skin protein and moisture and can cause irritation that may include the following symptoms: reddening, swelling, rash, scaling or blistering. Cured material is difficult to remove. Chronic Skin Contact: Prolonged contact can cause reddening, swelling, rash, scaling, blistering, and in some cases, allergic sensitization. Individuals who have skin sensitization can develop these symptoms from contact with liquid or vapors. Animal tests have indicated that respiratory sensitization can result from skin contact with MDI. This data reinforces the need to prevent direct skin contact with MDI. Acute Eye Contact: Liquid, aerosols or vapors are irritating and can cause tearing, reddening, and swelling. If left untreated, corneal damage can occur and injury is slow to heal. However, damage is usually reversible. Acute Ingestion: Can result in irritation and corrosive action in the mouth, stomach tissue, and digestive tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea. Carcinogenicity: Neither MDI nor polymeric MDI are listed by the NTP, IARC or regulated by OSHA as carcinogens. Exposure Limits: Exposure limits have not been established for this product. Use the exposure limits in Section 2 of this MSDS for MDI.