TRIMOL RESINS 15,34,35,36,40,41

SECTION 2: Hazards identification

Corrosive – Causes burns Harmful if swallowed May cause sensitisation by skin contact Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. CORROSIVE 3. COMPOSITION

Hazardous Ingredients

CAS Nos. EC No. Weight %

Hazard statements

Trimethlhexamethylene diamine 25620-58-0 247-134-8 100 C (Corrosive) R22,34,43,52/53 4. FIRST AID CONTACT WITH SKIN: Wash with plenty of soap and water. If irritation persists, obtain medical advice. CONTACT WITH EYES: Wash out with water for several minutes and seek medical advice. INGESTION: Give plenty of water – if possible, charcoal slurry. Do not induce vomiting. INHALATON: Remove to fresh air. If symptoms persist, seek medical advice.

Further information

Treat symptomatically. 5. FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: Dry powder or foam. For small fires use CO2, never use water jet. SPECIAL PROTECTIVE EQUIPMENT: For fires in confined spaces, use breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear suitable protective clothing appropriate to the amount involved, which may include eye/face protection, PVC or synthetic rubber gloves, protective footwear and overalls. ENVIRONMENTAL PRECAUTIONS: Do not allow to enter public sewers and watercourses If this cannot be avoided, inform the appropriate authority. CLEAN-UP PROCEDURES: Absorb in dry sand or earth or similar absorbents and shovel into a suitable closed container for disposal according to item 13. 7. HANDLING AND STORAGE HANDLING PRECAUTIONS: Ensure adequate ventilation in work areas. Keep away from sources of ignition – no smoking. Handle and open container with care. STORAGE INFORMATION: Keep containers tightly closed in a cool place, out of direct sunlight. Keep stored well ventilated. Keep away from food and feeding stuffs. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Wear protective clothing should be worn, including eye protection, boots and PVC or synthetic rubber gloves. In case of insufficient ventilation, wear suitable respiratory protective equipment. Wash hands and exposed skin before meals and after work. Do not eat, drink or smoke whilst handling the product. EXPOSURE LIMITS None prescribed in EH40 9. PHYSICAL AND CHEMICAL PROPERTIES Oxidising Appearance Clear, colourless liquid None Properties Odour Amine - like Vapour Pressure 6Pa (20°C) pH 11.3 (50% in water) Relative density 0.86-0.87 (20°C) Boiling Point >200°C Bulk density Not Relevant Melting Point Not relevant Viscosity 5mPa.s (25°) Flash Point >180°C (CC) Solubility Miscible in water Autoignition No data Partition Coefficient No data temperature Explosive No data Other data properties 10. STABILITY / REACTIVITY STABILITY: Stable under normal conditions of use. CONDITIONS TO AVOID: High temperatures, formation of aerosols, static discharges. MATERIALS TO AVOID: Strong oxidising agents, acids and bases. The information contained in this data is to the best of our knowledge accurate at the date of publication, but we cannot accept responsibility that it is sufficient or correct in all cases. The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the product. Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper explosive limit.

TOXICOLOGICAL INFORMATION

LD50 (rat, oral) 910mg/kg. Eye irritation (rabbit) corrosive. Skin irritation (rabbit) Corrosive Dermal sensitisation (guinea pig): sensitiser.

ECOLOGICAL INFORMATION

MOBILITY: Avoid soil penetration. DEGRADABILITY: Not easily biodegradable. ACCUMULATION: There is potential for bioaccumulation. Biomagnification is unlikely. ECTOTOXICITY: Toxic to aquatic organisms: LC50 (fish) 96h 1000mg/litre, EC50 (daphnia) 24h 31.5mg/litre EC50 (algae) 72h 29.5mg/litre), IC50 (bacteria) 3h 100mg/litre) 13. DISPOSAL INFORMATION DISPOSAL OF PRODUCT: Chemical residues are normally regarded as special waste. Incinerate in compliance with the Environmental Protection Act 1990 (Process Guidance Note IPR5/1) DISPOSAL OF PACKAGING: Uncleaned packaging should be treated as for the product. After cleaning, can be landfilled. 14. TRANSPORT INFORMATION UN No. 2327 PROPER SHIPPING NAME Trimethylhexamethylene diamines, solution ADR/RID Class 8. Item 53(c) IMCO MFAG Table No. 320 EmS No. 8.05 IATO/IACO Class 8 PACKING GROUP 3 LABEL Corrosive 15. REGULATORY INFORMATION

2.1 Classification of the substance or mixture

Corrosive LABEL INFORMATION R34: Causes burns R22: Harmful if swallowed R43: May cause sensitisation by skin contact R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. S45: In case of accident or if you feel unwell, seek medical advice (show the label where possible). Refer to other relevant legislation such as Health and Safety at Work etc., Act (HSWA), the Control of Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act. The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as required by health and safety legislation.