UNLEADED 91 PETROL (ULP)

Hazard statements (CLP)

H224, H304, H315, H319, H336, H340, H350, H360, H372, H411

Code

Statements

H224

Extremely flammable liquid and vapour

SECTION 2: Hazards identification

GHS classification of the substance/mixture Classified as Hazardous according to the Globally Harmonised System of Classification and labelling of Chemicals (GHS) including Work, Health and Safety regulations, Australia Classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. (7th edition) Flammable liquids: Category 1 Skin corrosion/irritation: Category 2 Eye damage/irritation: Category 2A Germ cell mutagenicity: Category 1B Carcinogenicity: Category 1B Reproductive toxicity: Category 1A Specific target organ toxicity (single exposure): Category 3 (Narcotic) Specific target organ toxicity (repeated exposure): Category 1 Aspiration hazard: Category 1 Hazardous to the Aquatic Environment - Long-Term Hazard: Category 2

Signal word

DANGER Hazard Statement (s) H224 Extremely flammable liquid and vapour H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H319 Causes serious eye irritation H336 May cause drowsiness or dizziness H340 May cause genetic defects H350 May cause cancer H360 May damage fertility or the unborn child H372 Causes damage to organs through prolonged or repeated exposure H411 Toxic to aquatic life with long lasting effects Pictogram (s) Flame,Exclamation mark,Health hazard,Environment Precautionary Statement–Prevention P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P233 Keep container tightly closed P240 Ground and bond container and receiving equipment P241 Use explosion-proof [electrical/ventilating/lighting] equipment P242 Use non-sparking tools P243 Take action to prevent static discharges P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash skin thoroughly after handling P270 Do not eat, drink or smoke when using this product P271 Use only outdoors or in a well-ventilated area P273 Avoid release to the environment P280 Wear protective gloves/protective clothing/eye protection/face protection

Response

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P370+P378 In case of fire: Use to extinguish. P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P308+P313 IF exposed or concerned: Get medical advice/attention. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312 Call a POISON CENTER/doctor if you feel unwell. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor P331 Do NOT induce vomiting. P314 Get medical advice/attention if you feel unwell. P391 Collect spillage.

Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Precautionary Statement–Disposal P501 Dispose of contents/container to an approved waste disposal plant.

Further information

This product contains an Ototoxic substance. Combination with noise exposure, even at safe levels, could still cause auditory injuries and hearing loss.

Other physicochemical hazards

Material can accumulate static charges which may cause an ignition. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Small leaks of this material can result in groundwater contamination levels above taste and odor thresholds for ether oxygenates (methyl tertiary butyl ether, ethyl tertiary butyl ether, tertiary amyl methyl ether or diisopropyl ether).Groundwater becomes unpalatable well below ether oxygenate concentrations that could affect human health.

Health hazards

High-pressure injection under skin may cause serious damage. May be irritating to the eyes, nose, throat, and lungs. Exposure to benzene is associated with cancer (acute myeloid leukaemia and myelodysplastic syndrome), damage to the blood-producing system, and serious blood disorders (see Section 11).

Environmental hazards

Ether oxygenates are significantly more soluble than other components of gasoline like benzene, toluene, ethyl benzene and xylenes (BTEX) if released into groundwater. Ether oxygenates may also biodegrade more slowly, have the potential to move farther and faster in groundwater and have the potential to contaminate larger areas of groundwater than BTEX if released into groundwater. Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

2.1 Classification of the substance or mixture

Classified as Hazardous according to the Globally Harmonised System of Classification and labelling of Chemicals (GHS) including Work, Health and Safety regulations, Australia. Classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road and Rail. (7th edition) Flammable liquids: Category 1 Skin corrosion/irritation: Category 2 Eye damage/irritation: Category 2A Germ cell mutagenicity: Category 1B Carcinogenicity: Category 1B Reproductive toxicity: Category 1A Specific target organ toxicity (single exposure): Category 3 (Narcotic) Specific target organ toxicity (repeated exposure): Category 1 Aspiration hazard: Category 1 Hazardous to the Aquatic Environment - Long-Term Hazard: Category 2 Signal Word (s) DANGER Hazard Statement (s) H224 Extremely flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H360 May damage fertility or the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. Pictogram (s) Flame,Exclamation mark,Health hazard,Environment