Tri-Clor Fumigant

Hazard statements (CLP)

H314, H319, H330+H300, H370+H372, H400+H410

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

GHS Classification Note: Supplemental information is [bracketed] or noted as such in Section 2.

2.1 Classification of the substance or mixture

Acute Toxicity – Inhalation, Category 1 • Acute Toxicity – Oral, Category 2 • Skin Corrosion/Irritation, Category 1C [liquid contact] • Eye Damage/Irritation, Category 1 [liquid contact] • Eye Irritation, Category 2A [vapor contact] • Specific Target Organ Toxicity, Single Exposure, Category 1 (respiratory) • Specific Target Organ Toxicity, Repeat Exposure, Category 1 (respiratory) • Hazardous to the Aquatic Environment, Short Term (Acute) Hazard, Category 1 • Hazardous to the Aquatic Environment, Long Term (Chronic) Hazard, Category 1

Signal word

DANGER • Fatal if inhaled or swallowed. H330+H300 GHS • Causes severe skin burns and eye damage. [liquid contact] H314

Hazard statements

Causes serious eye irritation. [vapor contact] H319 • Causes damage to the respiratory system from single exposure or through prolonged or repeated exposure by inhalation. H370+H372 • Very toxic to aquatic life with long lasting effects. H400 +H410

Prevention

Do not breathe gas or vapors. P260 • Use only outdoors or in a well-ventilated area. P271 • Wear protective gloves, eye and respiratory protection. [See section 8 of SDS]. P280+P284 • Wash hands and face thoroughly after handling. P264 • Do not eat, drink, or smoke when using this product. P270 • Avoid release to the environment, [except for authorized use] P273

Response

First Aid, See Section 4 for additional information] • IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a physician or poison control center. P304+P340+P310 • IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor, [for liquid contact] [For vapor contact], if eye irritation persists, get medical advice. P305+P351+P338+P310+P337+P313 • IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or doctor. P303+P361+P353+P310 • IF SWALLOWED: Immediately call a POISON CENTER or doctor. [Dab material from mouth with dry cloth first, if possible] Rinse mouth. Do NOT induce vomiting. P310+P301+P330+P331 • Get medical advice if you feel unwell. P314 • Wash contaminated clothing before reuse. P363

Storage

See Section 7 for additional information] • Store in a well-ventilated place. Keep container tightly closed. Store locked up. P403+P233+P405

Disposal

See Section 13 for additional information] • Collect spillage. P391 • Dispose of contents and container in accordance with government regulations. P501

2.3 Other hazards

None Closed cylinders may rupture or burst if heated by fire. • Keep away from heat/open flames. P210

Additional information

Store away from combustible materials. P220 • In case of fire: Evacuate area. Fight fire remotely due to the risk of cylinder rupture. P370+P380+P375 (modified)