Tri-Form 60 EC

Hazard statements (CLP)

H226, H283, H301, H301+H311, H304, H311, H314, H314+H318, H317, H318, H319, H330, H351, H370, H372, H400, H400+H410, H410

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

NOTE: Supplemental information is [bracketed] or noted as such in Section 2. GHS Classification H226 Flammable Liquids, Category 3 for Product H330 Acute Toxicity - Inhalation, Category 1 H301 Acute Toxicity - Oral, Category 3 H311 Acute Toxicity - Dermal, Category 3 H314 Skin Corrosion, Category 1C H318 Serious Eye Damage, Category 1 [liquid contact] H319 Eye Irritation, Category 2A [vapour contact] H304 Skin Sensitisation, Category 1B H351 Carcinogenicity, Category 2 (oral route) H370 Specific Target Organ Toxicity, Single Exposure, Category 3 respiratory system/hemal system) H372 Specific Target Organ Toxicity, Repeat Exposure, Category 1 respiratory system/hemal system/liver) H304 Aspiration Hazard, Category 1 H400 Hazardous to the Aquatic Environment, Short Term (Acute) Hazard, Category 1 H410 Hazardous to the Aquatic Environment, Long Term (Chronic) Hazard, Category 1 Additional GHS Classification for Product When it is Under Pressure in Cylinder H283 Chemicals Under Pressure, Category 2

Signal word

DANGER H226 Flammable liquid and vapour H330 Fatal if inhaled H301+H311 Toxic if swallowed or in contact with skin H314+H318 Causes severe skin burns and eye damage H319 Causes serious eye irritation. [vapour contact] GHS H317 May cause an allergic skin reaction Hazard Statements H351 Suspected of causing cancer by the oral route H370 Causes damage to the respiratory system and hemal system by inhalation H372 Causes damage to respiratory system, hemal system, and liver through prolonged or repeated exposure H304 May be fatal if swallowed and enters airways H400+H410 Very toxic to aquatic life and with long lasting effects Additional GHS Hazard Statement When H283 Flammable chemical under pressure: May explode if heated Product Under Pressure in Cylinder

Prevention

• Obtain, read, and follow all safety instructions before use. • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. • Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use non-sparking tools. Take action to prevent static discharges. • Do not breathe gas or vapours. • [Do not get in eyes, on skin, or on clothing.] • Wear protective gloves, protective clothing, eye protection, and respiratory protection. [See section 8 of SDS.] • Wash hands and face thoroughly after handling. Do not touch eyes. • Do not eat, drink, or smoke when using this product. • Use only outdoors or in a well-ventilated area. • Contaminated work clothing should not be allowed out of the workplace. • Avoid release to the environment, [except for authorised use].

Response

• IF INHALED: Remove person to fresh air and keep comfortable for breathing. Get emergency medical help immediately. Specific treatment is urgent (see Section 4 of SDS). • IF IN EYES: Immediately rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get emergency medical help immediately [for liquid contact]. [For vapour contact], if eye irritation persists, get medical help. • IF ON SKIN (or hair): Take off immediately all contaminated clothing. Immediately rinse with water for several minutes. Get emergency medical help immediately. Specific treatment (see Section 4 of SDS). Wash contaminated clothing before reuse. • IF SWALLOWED: Get emergency medical help immediately. [Dab material from mouth with dry cloth first, if possible.] Rinse mouth. Do NOT induce vomiting. • IF exposed or concerned: Get emergency medical help immediately. • If skin irritation or rash occurs: Get medical help. • Get medical help if you feel unwell. • In case of fire: Use dry chemical or alcohol-resistant foam to extinguish.

Storage

[See Section 7 for additional information.] • Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.

Disposal

[See Section 13 for additional information.] • Collect spillage. • Dispose of contents and container in accordance with government regulations. [Closed cylinders may rupture or burst if heated by fire.] Additional Precautionary • Store away from combustible materials. Statements for Product • Do not spray on an open flame or other ignition source. When it is Under Pressure • In case of leakage, eliminate all ignition sources. Stop leak if safe to do so. in Cylinder • In case of fire: Use dry chemical or alcohol-resistant foam to extinguish. [Evacuate area. Fight fire remotely due to the risk of cylinder rupture].

2.1 Classification of the substance or mixture

H226 Flammable Liquids, Category 3 for Product H330 Acute Toxicity - Inhalation, Category 1 H301 Acute Toxicity - Oral, Category 3 H311 Acute Toxicity - Dermal, Category 3 H314 Skin Corrosion, Category 1C H318 Serious Eye Damage, Category 1 [liquid contact] H319 Eye Irritation, Category 2A [vapour contact] H304 Skin Sensitisation, Category 1B H351 Carcinogenicity, Category 2 (oral route) H370 Specific Target Organ Toxicity, Single Exposure, Category 3 (respiratory system/hemal system) H372 Specific Target Organ Toxicity, Repeat Exposure, Category 1 (respiratory system/hemal system/liver) H304 Aspiration Hazard, Category 1 H400 Hazardous to the Aquatic Environment, Short Term (Acute) Hazard, Category 1 H410 Hazardous to the Aquatic Environment, Long Term (Chronic) Hazard, Category 1 Additional GHS Classification for Product When it is Under Pressure in Cylinder H283 Chemicals Under Pressure, Category 2 Signal Word DANGER H226 Flammable liquid and vapour. H330 Fatal if inhaled. H301+H311 Toxic if swallowed or in contact with skin. H314+H318 Causes severe skin burns and eye damage. H319 Causes serious eye irritation. [vapour contact] GHS H317 May cause an allergic skin reaction. Hazard Statements H351 Suspected of causing cancer by the oral route. H370 Causes damage to the respiratory system and hemal system by inhalation. H372 Causes damage to respiratory system, hemal system, and liver through prolonged or repeated exposure. H304 May be fatal if swallowed and enters airways. H400+H410 Very toxic to aquatic life and with long lasting effects. Additional GHS Hazard Statement When H283 Flammable chemical under pressure: May explode if heated. Product Under Pressure in Cylinder