PIC PLUS

Hazard statements (CLP)

H284, H301, H304, H312, H315, H317, H318, H319, H330, H370, H372, H400, H400+H410, H410

SECTION 2: Hazards identification

Note: Supplemental information is [bracketed] or noted as such in Section 2 GHS Classification H330 Acute Toxicity - Inhalation, Category 1 for Product H301 Acute Toxicity - Oral, Category 3 H312 Acute Toxicity - Dermal, Category 4 H315 Skin Corrosion/Irritation, Category 2 H318 Eye Damage/Irritation, Category 1 [liquid contact] H319 Eye Damage/Irritation, Category 2A [vapour contact] H317 Skin Sensitization, Category 1B H370 Specific Target Organ Toxicity, Single Exposure, Category 1 (respiratory, hemal) H372 Specific Target Organ Toxicity, Repeat Exposure, Category 1 (respiratory, hemal, liver) H304 Aspiration Hazard, Category 1 H400 Hazardous to the Aquatic Environment, Short Term (Acute) Hazard, Category 1 H410 Hazardous to the Aquatic Environment, Long Term (Chronic) Hazard, Category 1 Additional GHS Classification for Product When it is Under Pressure in H284 Chemicals Under Pressure, Category 3 Cylinder

Signal word

DANGER Fatal if inhaled. H330 Toxic if swallowed. H301 Harmful in contact with skin. H312 Causes skin irritation. H315 GHS Causes serious eye damage. [liquid contact] H318 Causes serious eye irritation. [vapour contact] H319 Hazard Statements May cause an allergic skin reaction. H317 Causes damage to respiratory system and hemal system by inhalation. H370 Causes damage to respiratory system, hemal system, and liver through prolonged or repeated exposure. H372 Very toxic to aquatic life with long lasting effects. H400+H410 Additional GHS Hazard Statement When Product Under Chemical under pressure: May explode if heated. H284 Pressure in Cylinder

Prevention

• Do not breathe gas or vapours. P260 • Do not get in eyes, on skin, or on clothing. P262 • Wash hands and face thoroughly after handling. Do not touch eyes. P264+P265 • Use only outdoors or in a well-ventilated area. P271 • Wear protective gloves, protective clothing, eye/face and respiratory protection. [See section 8 of SDS] P280+P284 • Do not eat, drink, or smoke when using this product. P270 • Contaminated work clothing should not be allowed out of the workplace. P272 • Avoid release to the environment, [except for authorised use]. P273

Response

[First Aid, See Section 4 of SDS for additional information] • IF INHALED: Remove person to fresh air and keep comfortable for breathing. Get emergency medical help immediately. Specific treatment is urgent (see Section 4 of SDS). P304+P340+P316+P320 • IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get emergency medical help immediately [for liquid contact]. [For vapor contact], If eye irritation persists: Get medical help. P305+P354+P338+P316+P337+P317 • IF ON SKIN: Take off contaminated clothing. Wash with plenty of water. Get medical help. Specific treatment (see Section 4 of SDS). If skin irritation or rash occurs: Get medical help. Wash contaminated clothing before reuse. P302+P362+P352+P317+P321+P333+P317+P364 • IF SWALLOWED: Get emergency medical help immediately. [Dab material from mouth with dry cloth first, if possible] Rinse mouth. Do NOT induce vomiting. Specific treatment (see Section 4 of SDS). P301+P316+P330+P331+P321 • IF exposed or concerned: Get emergency medical help immediately. P308+P316 • Get medical help if you feel unwell. P319

Storage

[See Section 7 for additional information] • Store in a well-ventilated place. Keep container tightly closed. Store locked up. P403+P233+P405

Disposal

[See Section 13 for additional information] • Collect spillage. P391 • Dispose of contents and container in accordance with government regulations. P501 Closed cylinders may rupture or burst if heated by fire. Additional Precautionary • Keep away from heat/open flames. P210 Statements for Product • [Store away from combustible materials. P220] When it is Under Pressure • Stop leak if safe to do so. P376 in Cylinder • [In case of fire: Evacuate area. Fight fire remotely due to the risk of cylinder rupture. P370+P380+P375 (modified)]

2.3 Other hazards

None.

2.1 Classification of the substance or mixture

H330 Acute Toxicity - Inhalation, Category 1 for Product H301 Acute Toxicity - Oral, Category 3 H312 Acute Toxicity - Dermal, Category 4 H315 Skin Corrosion/Irritation, Category 2 H318 Eye Damage/Irritation, Category 1 [liquid contact] H319 Eye Damage/Irritation, Category 2A [vapour contact] H317 Skin Sensitization, Category 1B H370 Specific Target Organ Toxicity, Single Exposure, Category 1 (respiratory, hemal) H372 Specific Target Organ Toxicity, Repeat Exposure, Category 1 (respiratory, hemal, liver) H304 Aspiration Hazard, Category 1 H400 Hazardous to the Aquatic Environment, Short Term (Acute) Hazard, Category 1 H410 Hazardous to the Aquatic Environment, Long Term (Chronic) Hazard, Category 1 Additional GHS Classification for Product When it is Under Pressure in H284 Chemicals Under Pressure, Category 3 Cylinder Signal Word DANGER • Fatal if inhaled. H330 • Toxic if swallowed. H301 • Harmful in contact with skin. H312 • Causes skin irritation. H315 GHS • Causes serious eye damage. [liquid contact] H318 • Causes serious eye irritation. [vapour contact] H319 Hazard Statements • May cause an allergic skin reaction. H317 • Causes damage to respiratory system and hemal system by inhalation. H370 • Causes damage to respiratory system, hemal system, and liver through prolonged or repeated exposure. H372 • Very toxic to aquatic life with long lasting effects. H400+H410 Additional GHS Hazard Statement When Product Under • Chemical under pressure: May explode if heated. H284 Pressure in Cylinder