VULKEM 116 LV GRAY 30 CTG/CS

Hazard statements (CLP)

H317, H334, H340, H350, H401

Code

Statements

H317

May cause an allergic skin reaction

SECTION 2: Hazards identification

Hazard Classification

Health hazards

Respiratory sensitizer Category 1 Skin sensitizer Category 1 Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1A Unknown toxicity - Health Acute toxicity, oral 34.06 % Acute toxicity, dermal 41.27 % Acute toxicity, inhalation, vapor 97.73 % Acute toxicity, inhalation, dust or mist 99.12 %

Environmental hazards

Acute hazards to the aquatic Category 2 Unknown toxicity - Environment Acute hazards to the aquatic 78.43 % Chronic hazards to the aquatic 100 %

Signal word

Danger

Hazard statements

May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause genetic defects. May cause cancer. Toxic to aquatic life. Precautionary

Prevention

Avoid breathing dust/fume/gas/mist/vapors/spray. [In case of inadequate ventilation] wear respiratory protection. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Avoid release to the environment.

Response

If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER/doctor. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. If exposed or concerned: Get medical advice/attention. Specific treatment (see this label). Wash contaminated clothing before reuse.

Storage

Store locked up.

Disposal

Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Other hazards which do not None. result in GHS classification

2.1 Classification of the substance or mixture

Health Hazards Respiratory sensitizer Category 1 Skin sensitizer Category 1 Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1A Unknown toxicity - Health Acute toxicity, oral 34.06 % Acute toxicity, dermal 41.27 % Acute toxicity, inhalation, vapor 97.73 % Acute toxicity, inhalation, dust or mist 99.12 % Environmental Hazards Acute hazards to the aquatic Category 2 environment Unknown toxicity - Environment Acute hazards to the aquatic 78.43 % environment Chronic hazards to the aquatic 100 % environment Label Elements Hazard Symbol: Signal Word: Danger Hazard Statement: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause genetic defects. May cause cancer. Toxic to aquatic life. Precautionary Statement: Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. [In case of inadequate ventilation] wear respiratory protection. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Avoid release to the environment. Response: If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER/doctor. IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. If exposed or concerned: Get medical advice/attention. Specific treatment (see this label). Wash contaminated clothing before reuse. Storage: Store locked up. Disposal: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Other hazards which do not None. result in GHS classification: 3. Composition/information on ingredients Mixtures Chemical Identity CAS number Content in percent (%)* Calcium Carbonate 1317-65-3 10 - 30% (Limestone) Titanium dioxide 13463-67-7 3 - 7% Polyethylene 9002-88-4 3 - 7% Heavy aromatic naphtha 64742-94-5 1 - 5% Aromatic petroleum distillates 64742-95-6 0.5 - 1.5% 1,2,4-Trimethylbenzene 95-63-6 0.5 - 1.5% 4,4'-Methylene 101-68-8 0.5 - 1.5% bis(phenylisocyanate) Aluminum oxide 1344-28-1 0.1 - 1% Polymethylene polyphenyl 9016-87-9 0.1 - 1% isocyanate 1,3,5-Trimethylbenzene 108-67-8 0.1 - 1% Crystalline Silica (Quartz)/ 14808-60-7 0.1 - 1% Silica Sand * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Ingestion: Call a POISON CENTER/doctor/.../if you feel unwell. Rinse mouth. Inhalation: Call a physician or poison control center immediately. If breathing stops, provide artificial respiration. Move to fresh air. If breathing is difficult, give oxygen. Skin Contact: If skin irritation occurs: Get medical advice/attention. Destroy or thoroughly clean contaminated shoes. Immediately remove contaminated clothing and shoes and wash skin with soap and plenty of water. If skin irritation or an allergic skin reaction develops, get medical attention. Eye contact: Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses. If eye irritation persists: Get medical advice/attention. Most important symptoms/effects, acute and delayed Symptoms: May cause skin and eye irritation. Indication of immediate medical attention and special treatment needed Treatment: Symptoms may be delayed. 5. Fire-fighting measures General Fire Hazards: No unusual fire or explosion hazards noted. Suitable (and unsuitable) extinguishing media Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials. media: Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media: Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical: Special protective equipment and precautions for firefighters Special fire fighting No data available. procedures: Special protective equipment Self-contained breathing apparatus and full protective clothing must be for fire-fighters: worn in case of fire. 6. Accidental release measures Personal precautions, Ventilate closed spaces before entering them. Evacuate area. See Section protective equipment and 8 of the SDS for Personal Protective Equipment. Keep upwind. Keep emergency procedures: unauthorized personnel away. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Methods and material for Collect spillage in containers, seal securely and deliver for disposal containment and cleaning according to local regulations. up: Notification Procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Environmental Precautions: Avoid release to the environment. Prevent further leakage or spillage if safe to do so. 7. Handling and storage Precautions for safe handling: Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Wash hands thoroughly after handling. Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is above accepted level. Use mechanical ventilation in case of handling which causes formation of dust. Conditions for safe storage, Store locked up. including any incompatibilities: 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits Chemical Identity type Exposure Limit Values Source Calcium Carbonate PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air (Limestone) - Total Contaminants (29 CFR 1910.1000) dust. (02 2006) Calcium Carbonate PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air (Limestone) - Contaminants (29 CFR 1910.1000) Respirable fraction. (02 2006) Titanium dioxide TWA 10 mg/m3 US. ACGIH Threshold Limit Values (2011) Titanium dioxide - Total PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air dust. Contaminants (29 CFR 1910.1000) (02 2006) Polyethylene - TWA 10 mg/m3 US. ACGIH Threshold Limit Values Inhalable particles. (03 2015) Polyethylene - TWA 3 mg/m3 US. ACGIH Threshold Limit Values Respirable particles. (03 2015) Polyethylene -