UNOCAL DIESEL 12

Hazard statements (CLP)

H227

Code

Statements

H227

Combustible liquid

Aspiration hazard

DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. IF VICTIM IS DROWSY OR UNCONSCIOUS, F'LACE ON THE LEFT SIDE WITH THE HEAD DOWN. IF POSSIBLE, DO NOT LEAVE VICTIM UNATTENDED. SEEK MEDICAL ATTENTION. SECTION III - HEALTH HAZARDS/ROUTES OF ENTRY EYE CONTACT: THIS MATERIAL MAY CAUSE MILD EYE IRRITATION. DIRECT CONTACT WITH THE LIQUID OR EXPOSURE TO VAPORS OR MISTS MAY CAUSE STINGING, TEARING AND REDNESS. SKIN CONTACT: I THIS MATERIAL IS A SKIN IRRITANT. PROLONGED OR REPEATED CONTACT MAY CAUSE SEVERE IRRITATION INCLUDING REDNESS AND BURNING, DRYING AND CRACKING OF THE SKIN, AND SEVERE SKIN DAMAGE. NO HARMFUL EFFECTS ARE EXPECTED FROM SKIN ABSORPTION OF THIS MATERIAL. I 19290 000802 UNION OIL CO. Product Name: UNOCAL DIESEL 12 Page 3 Product Code No: 01602 Issue Date: 05/09/90 Status: FINAL SECTION III - HEALTH HAZARDS/ROUTES OF ENTRY , " PERSONS WITH PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS MATERIAL. INHALATION (BREATHING): WHILE THIS MATERIAL HAS A LOW DEGREE OF TOXICITY, BREATHING HIGH CONCENTRATIONS OF VAPORS OR MISTS MAY CAUSE IRRITATION OF THE NOSE AND THROAT AND SIGNS OF NERVOUS SYSTEM DEPRESSION (e.g. HEADACHE, DROWSINESS, DIZZINESS, LOSS OF COORDINATION, AND FATIGUE) . INGESTION (SNAllOHING): WHILE THIS MATERIAL HAS A LOW DEGREE OF TOXICITY, INGESTION OF EXCESSIVE QUANTITIES MAY CAUSE IRRITATION OF THE DIGESTIVE TRACT AND SIGNS OF NERVOUS SYSTEM DEPRESSION (e.g. HEADACHE, DROWSINESS, DIZZINESS, LOSS OF COORDINATION, AND FATIGUE). ASPIRATION HAZARD - THIS MATERIAL CAN ENTER LUNGS DURING SWALLOWING OR VOMITING AND CAUSE LUNG INFLAMMATION AND DAMAGE. COMMENTS: DIESEL EXHAUST IS A PROBABLE HUMAN CANCER HAZARD, BUT IT HAS NOT BEEN IDENTIFIED AS A CARCINOGEN BY IARC, NTP OR OSHA. SECTION IV - SPECIAL PROTECTION INFORMATION VENTI LA TI ON: IF CURRENT VENTILATION PRACTICES ARE NOT ADEQUATE TO MAINTAIN AIRBORNE CONCENTRATIONS BELOW THE ESTABLISHED EXPOSURE LIMITS (SEE SECTION I), ADDITIONAL VENTILATION OR EXHAUST SYSTEMS MAY BE REQUIRED. WHERE EXPLOSIVE MIXTURES MAY BE PRESENT, ELECTRICAL • SYSTEMS SAFE FOR SUCH LOCATIONS MUST BE USED. RESPIRATORY PROTECTION: THE USE OF RESPIRATORY PROTECTION IS ADVISED WHEN CONCENTRATIONS EXCEED THE ESTABLISHED EXPOSURE LIMITS (SEE SECTION I). DEPENDING ON THE AIRBORNE CONCENTRATION, USE A RESPIRATOR OR GAS MASK WITH APPROPRIATE CARTRIDGES AND CANNISTERS (NIOSH APPROVED, IF AVAILABLE) OR SUPPLIED AIR EQUIPMENT. PROTECTIVE GLOVES: THE USE OF GLOVES IMPERMEABLE TO THE SPECIFIC MATERIAL HANDLED IS ADVISED TO PREVENT SKIN CONTACT AND POSSIBLE IRRITATION. EYE PROTECTION: APPROVED EYE PROTECTION TO SAFEGUARD AGAINST POTENTIAL EYE CONTACT, IRRITATION OR INJURY IS RECOMMENDED. OTHER PROTECTIVE EQUIPMENT: IT IS SUGGESTED THAT A SOURCE OF CLEAN WATER BE AVAILABLE IN THE WORK AREA FOR FLUSHING EYES AND SKIN. IMPERVIOUS CLOTHING SHOULD BE WORN AS NEEDED. SECTION V - REACTIVITY DATA e REACTIVITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND HANDLING. I r # 19291 000802 UNION OIL CO. Product Name: UNOCAL DIESEL 12 Page 4 Product Code No: 01602 Issue Date: 05/09/90 Status: FINAL SECTION V - REACTIVITY DATA CONDITIONS AFFECTING REACTIVITY: AVOID CONTACT WITH ANY SOURCE OF HEAT OR FLAME. INCOMPATIBLE MATERIALS: AVOID CONTACT WITH STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS: COMBUSTION MAY YIELD MAJOR AMOUNTS OF OXIDES OF CARBON AND MINOR AMOUNTS OF OXIDES OF SULFUR AND NITROGEN. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR POLYMERIZATION CONDITIONS TO AVOID: NONE KNOWN SECTION VI - SPILL AND LEAK PROCEDURES ***HIGHWAY OR RAILWAY SPILLS*** Call CHEMTREC (800) 424-9300 Cont. U.S. (Collect) (202) 483-7616 from Alaska & Hawaii 4It PRECAUTIONS IN CASE OF RELEASE OR SPILL: COMBUSTIBLE. KEEP ALL SOURCES OF IGNITION AWAY FROM SPILL/RELEASE. STAY UPWIND AND AWAY FROM SPILL/RELEASE. ISOLATE HAZARD AREA AND LIMIT ENTRY TO AUTHORIZED PERSONNEL. STOP SPIll/RELEASE IF IT CAN BE DONE WITHOUT RISK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT INCLUDING RESPIRATORY PROTECTION AS CONDITIONS WARRANT (SEE SECTION IV). PREVENT SPILLED MATERIAL FROM ENTERING SEWERS, STORM DRAINS, OTHER UNAUTHORIZED TREATMENT DRAINAGE SYSTEMS AND NATURAL WATERWAYS. DIKE FAR AHEAD OF SPILL FOR LATER RECOVERY OR DISPOSAL. SPILLED MATERIAL MAY BE ABSORBED INTO AN APPROPRIATE ABSORBENT MATERIAL. NOTIFY FIRE AUTHORITIES AND APPROPRIATE FEDERAL, STATE AND LOCAL AGENCIES. IMMEDIATE CLEANUP OF ANY SPILL IS RECOMMENDED. IF SPILL OF ANY AMOUNT IS MADE INTO OR UPON U.S. NAVIGABLE WATERS, THE CONTIGUOUS ZONE, OR ADJOINING SHORELINES, NOTIFY THE NATIONAL RESPONSE CENTER (PHONE NUMBER 800-424-8802). WASTE DISPOSAL METHOD: DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL, COUNTY, STATE. AND FEDERAL REGULATIONS. SECTION VII - STORAGE AND SPECIAL PRECAUTIONS HANDLING AND STORAGE PRECAUTIONS: KEEP CONTAINER(S) TIGHTLY CLOSED. USE AND STORE THIS MATERIAL IN COOL, DRY, WELL VENTILATED AREAS AWAY FROM HEAT AND ALL SOURCES OF IGNITION. POST AREA "NO SMOKING OR OPEN FLAME." BOND AND GROUND ALL EQUIPMENT WHEN TRANSFERRING FROM ONE VESSEL TO ANOTHER. STORE ONLY IN APPROVED CONTAINERS. KEEP AWAY FROM ANY INCOMPATIBLE MATERIALS (SEE SECTION V). PROTECT CONTAINER(S) AGAINST PHYSICAL DAMAGE. THE USE OF EXPLOSION-PROOF EQUIPMENT IS RECOMMENDED AND MAY BE REQUIRED (SEE APPROPRIATE FIRE I CODES). DO NOT ENTER CONFINED SPACES SUCH AS TANKS OR PITS WITHOUT FOLLOWING PROPER ! • ENTRY PROCEDURES SUCH AS ASTM D-4276. OUTDOOR OR DETACHED STORAGE IS PREFERRED. INDOOR STORAGE SHOULD MEET OSHA STANDARDS AND APPROPRIATE FIRE CODES. THE USE OF RESPIRATORY PROTECTION IS ADVISED WHEN CONCENTRATIONS EXCEED ANY ESTABLISHED EXPOSURE LIMITS (SEE SECTIONS I AND IV). WASH THOROUGHLY AFTER HANDLING. DO NOT WEAR CONTAMINATED CLOTHING OR SHOES. USE GOOD PERSONAL HYGIENE PRACTICE. "EMPTY" CONTAINERS RETAIN RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT. WELD, BRAZE, SOLDER, DRILL. GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. "EMPTY" DRUMS SHOULD BE COMPLETELY DRAINED. PROPERLY BUNGED AND PROMPTLY • SHIPPED TO THE SUPPLIER OR A DRUM RECONDITIONER. ALL OTHER CONTAINERS SHOULD BE # 19292 000802 UNION OIL CO . Product Name: UNOCAL DIESEL #2 Page 5 Product Code No: 01602 Issue Date: 05/09/90 Status: FINAL SECTION VII - STORAGE AND SPECIAL PRECAUTIONS DISPOSED OF IN AN ENVIRONMENTALLY SAFE MANNER AND IN ACCORDANCE WITH GOVERNMENTAL REGULATIONS. BEFORE WORKING ON OR IN TANKS WHICH CONTAIN OR HAVE CONTAINED THIS PRODUCT, REFER TO OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION REGULATIONS, ANSI Z49.1, AND OTHER GOVERNMENTAL AND INDUSTRIAL REFERENCES PERTAINING TO CLEANING, REPAIRING, WELDING, OR OTHER CONTEMPLATED OPERATIONS. SECTION VIII - FIRE AND EXPLOSION HAZARD DATA HAZARD RANKING NFPA HEALTH HAZARD: 0 0 LEAST = FLASH POINT

2.1 Classification of the substance or mixture

COMBUSTIBLE LIQUID PRECAUTIONARY WARNING NARNING MAY CAUSE SEVERE SKIN IRRITATION AFTER PROLONGED OR REPEATED CONTACT. BREATHING DIESEL EXHAUST MAY CAUSE LUNG CANCER. ASPIRATION HAZARD IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. COMBUSTIBLE. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. AVOID BREATHING EXHAUST FUMES. DO NOT TASTE OR SWALLOW. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. KEEP AWAY FROM HEAT, SPARKS, FLAMES OR OTHER SOURCES OF IGNITION (e.g. STATIC ELECTRICITY, PILOT LIGHTS OR MECHANICAL/ELECTRICAL EQUIPMENT). DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, GRIND OR DRILL ON OR NEAR CONTAINER. "EMPTY" CONTAINER RETAINS RESIDUE (LIQUID AND/OR VAPOR) AND MAY EXPLODE IN HEAT OF A FIRE. SECTION I - COMPONENTS PERCENT EXPOSURE LIMIT UNITS AGENCY TYPE HAZARDOUS COHPONENTS DI ESEL OIL NO. 2 CAS I: 68476-34-6 >98 400.000 ppm OSHA HIA BIPHENYL CAS I: 92-52-4 0.0 - 1. 0 0.200 ppm ACGIH HIA 0.200 ppm MSHA HIA 0.200 ppm OSHA HIA 0.200 ppm CAL OSHA HIA I 19289 000802 UNION OIL CO. Product Name: UNOCAL DIESEL #2 Page 2 Product Code No: 01602 Issue Date: 05/09/90 Status: FINAL SECTION I - COMPONENTS PERCENT EXPOSURE LIMIT UNITS AGENCY TYPE NAPHTHALENE CAS I: 91-20-3 0.0 - 1.0 10.000 ppm ACGIH TWA 15.000 ppm ACGIH STEl 10.000 ppm MSHA TWA 10.000 ppm OSHA TWA 15.000 ppm OSHA STEL 10.000 ppm CAL OSHA TWA