PC 509 Z ACRYL INIT

Hazard statements (CLP)

H271, H302, H315, H317, H319, H334, H335

Code

Statements

H271

May cause fire or explosion; strong oxidiser

2.1 Classification of the substance or mixture

EC 67/548 or EC 1999/45 O; R8 Xn; R22 Xi; R36/37/38 R42/43

Hazard categories

Regulation EC 1272/2008 (CLP)

Health hazards

Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) Skin irritation - Category 2 - Warning Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) Respiratory sensitization - Category 1 - Danger (CLP : Resp. Sens. 1) Skin sensitisation - Category 1 - Warning (CLP : Skin Sens. 1) Specific Target Organ Toxicity - Single exposure - Respiratory tract irritation - Category 3 - Warning (CLP : STOT SE 3) SECTION 2. Hazards identification (continued)

Physical hazards

Oxidizing solids - Category 1 - Danger (CLP : Ox. Sol. 1)

2.2 Label elements

EC 67/548 or EC 1999/45 Regulation EC 1272/2008 (CLP)

Hazard pictograms

ê X ê O : Harmful. Oxidizing. M œ M “ : SGH03 - SGH08 (Precautionary £ [ Æ Ê Æ ; =

R-phrase(s)

R08 - Contact with combustible material may cause fire. R22 - Harmful if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. R42/43 - May cause sensitization by inhalation and skin contact.

S-phrase(s)

S22 - Do not breathe dust. S24 - Avoid contact with skin. S37 - Wear suitable gloves. S45 - In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible).

Signal word

Danger

Hazard statements

H271 - May cause fire or explosion; strong oxidiser. H302 - Harmful if swallowed. H319 - Causes serious eye irritation. H315 - Causes skin irritation. H335 - May cause respiratory irritation. H317 - May cause an allergic skin reaction. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. ™ ± ÷ ê û

Prevention

P221 - Take any precaution to avoid mixing with combustibles… P280 - Wear protective gloves/protective clothing/eye protection/face protection. P210C - Keep away from heat.

Response

P301+P312+P330 - IF SWALLOWED : Call a POISON CENTER or doctor if you feel unwell. Rinse mouth. P302+P352+P362+P332+P313+P321 - IF ON SKIN : Wash with plenty of soap and water. Take off contaminated clothing and wash before reuse. If skin irritation occurs : Get medical advice. Specific treatment. P304+P341 - IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. SECTION 2. Hazards identification (continued) P305+P351+P338+P337+P313 - IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists : Get medical advice. P306+P360 - IF ON CLOTHING: rinse immediately contaminated clothing and skin with plenty of water before removing clothes. P371+P380+P375 - In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P378 - Use for extinction : All extinguishing media can be used. - Disposal considerations : P501C - Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

2.3 Other hazards

None under normal conditions.