Skin Sens. 1, H317

SECTION 2: Hazards identification

account. SECTION 4: First aid measures 2.1 Classification of the substance or mixture Classification according to Regulation (EC) 1272/2008 (CLP) 4.1 Description of first aid measures Hazard class Hazard category Hazard statement Inhalation Eye Irrit. 2 H319-Causes serious eye irritation. Remove person from danger area. STOT SE 3 H335-May cause respiratory irritation. Supply person with fresh air and consult doctor according to symptoms. Skin Irrit. 2 If the person is unconscious, place in a stable side position and consult a doctor. H315-Causes skin irritation. Respiratory arrest - Artificial respiration apparatus necessary. Resp. Sens. 1 H334-May cause allergy or asthma Skin contact symptoms or breathing difficulties if inhaled. Wipe off residual product carefully with a soft, dry cloth. Skin Sens. 1 H317-May cause an allergic skin reaction. Remove polluted, soaked clothing immediately, wash thoroughly with plenty of water and soap, in case of Carc. 2 H351-Suspected of causing cancer. irritation of the skin (flare), consult a doctor. STOT RE 2 Dab away with polyethylene glycol 400 H373-May cause damage to organs through Eye contact prolonged or repeated exposure by Remove contact lenses. inhalation (respiratory tract). Wash thoroughly for several minutes using copious water - call doctor immediately, have Data Sheet available. Ingestion 2.2 Label elements Rinse the mouth thoroughly with water. Labeling according to Regulation (EC) 1272/2008 (CLP) Do not induce vomiting - give copious water to drink. Consult doctor immediately. Never pour anything into the mouth of an unconscious person! 4.2 Most important symptoms and effects, both acute and delayed If applicable delayed symptoms and effects can be found in section 11 and the absorption route in section 4.1. The following may occur: Dermatitis (skin inflammation) Drying of the skin. Allergic contact eczema Discoloration of the skin Irritant to mucosa of the nose and throat Coughing Headaches Danger Effect on the central nervous system Asthmatic symptoms In case of sensitivity, concentrations below the limit value may already result in asthmatic symptoms. H319-Causes serious eye irritation. H335-May cause respiratory irritation. H315-Causes skin Respiratory distress irritation. H334-May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317- In certain cases, the symptoms of poisoning may only appear after an extended period / after several hours. May cause an allergic skin reaction. H351-Suspected of causing cancer. H373-May cause 4.3 Indication of any immediate medical attention and special treatment needed damage to organs through prolonged or repeated exposure by inhalation (respiratory tract). In case of irritation of the lungs, perform first-aid with controlled-dosage aerosol dexamethasone. Pulmonary oedema prophylaxis P201-Obtain special instructions before use. P260-Do not breathe vapours or spray. P280-Wear Medical supervision necessary due to possibility of delayed reaction. protective gloves / protective clothing and eye protection / face protection. P284-Wear respiratory protection. SECTION 5: Firefighting measures P302+P352-IF ON SKIN Wash with plenty of water and soap. P304+P340-IF INHALED Remove person to fresh air and keep comfortable for breathing. P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. 5.1 Extinguishing media Continue rinsing. P308+P313-IF exposed or concerned: Get medical advice / attention. Suitable extinguishing media EUH204-Contains isocyanates. May produce an allergic reaction. CO2 Extinction powder Foam Dibutyl tin dilaurate Water jet spray Methylenediphenyl diisocyanate, modified Unsuitable extinguishing media High volume water jet 2.3 Other hazards 5.2 Special hazards arising from the substance or mixture The mixture does not contain any vPvB substance (vPvB = very persistent, very bioaccumulative) or is not In case of fire the following can develop: included under XIII of the regulation (EC) 1907/2006 (< 0,1 %). Oxides of carbon Oxides of nitrogen (8) = Inhalable fraction (2017/164/EU). (9) = Respirable fraction (2017/164/EU). (10) = Short-term exposure Safety data sheet according to Regulation (EC) No 1907/2006, Annex II limit value in relation to a reference period of 1 minute (2017/164/EU). | BMGV = Biological monitoring Revision date / version: 18.08.2017 / 0009 guidance value EH40. BGW = "Biologischer Grenzwert" (biological limit value, Germany) | Other information: Replacing version dated / version: 07.03.2017 / 0008 Sen = Capable of causing occupational asthma. Sk = Can be absorbed through skin. Carc = Capable of Valid from: 18.08.2017 causing cancer and/or heritable genetic damage. PDF print date: 22.08.2017 ** = The exposure limit for this substance is repealed through the TRGS 900 (Germany) of January 2006 with TRADEPUR LTM4 the goal of revision. (TRADEPUR LTM4) Propylene carbonate Area of application