Formula PB-33 Part A

Classification (GHS-US)

OSHA Skin Irritation: Category 1 Eye Irritation: Category 1 Respiratory Irritation: STOT SE Category 3 Corrosive to Metals: Category 1

2.2 Label elements

GHS-US Labeling

Signal word

DANGER

Hazard statements

Causes severe skin burns and serious eye damage. May cause respiratory irritation. May be corrosive to metals.

Precautionary statements

Keep only in original container. Store locked up. Do not breathe mists, vapors, or spray. Wash hands thoroughly after handling. Do not eat, drink, or smoke when using this product. Use only in a well-ventilated area. Wear protective gloves, clothing, eye, and face protection. If swallowed rinse mouth. Do NOT induce vomiting. If on skin or hair: Take off all contaminated clothing. Rinse skin with water or shower. Wash clothing before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses if easy to do. If eye irritation persists, get medical attention. Contact a doctor or poison control center immediately if the product is swallowed or inhaled. Absorb spillage to prevent material damage. Dispose of contents in accordance with local/state/federal regulations

Principle Routes of Exposure

Absorption, Inhalation, Ingestion Target Organs: Eyes, Skin Acute Effects Inhalation: Not expected to be a relevant route of exposure. However, high vapor or aerosol mist concentrations may be irritating to the nose, throat and upper respiratory tract. Prolonged exposure may cause burning and/or bleeding in nasal cavities. Eye Contact: Material can cause severe eye irritation. Symptoms may include inflammation, redness and tearing. Can injure eye tissues. Skin Contact: Material can cause skin burns. Symptoms may include redness and burning of the skin and other skin damage. Blistering may occur. Progressive ulceration will occur if treatment is not immediate. Ingestion: Ingestion will cause gastrointestinal irritation. Symptoms may include abdominal discomfort, nausea, vomiting and diarrhea. Corrosive burns may appear around the lips.

Potential chronic health

No product information available

Ingredient(s) with unknown acute toxicity

No data available 3.1. Substance ALL SPECIFIC HAZARDOUS COMPONENTS (IF ANY), REQUIRED TO BE INDENTIFIED BY FEDERAL AND/OR STATE LAW, ARE IDENTIFIED BY COMPONENT NAME AND CASRN NUMBER AND LISTED IN REQUIRED SECTIONS 3, 8, 14 AND 15 OF THIS SDS. 3.2. Mixture CAS Number Component % Proprietary Acid Solution <10 7664-93-9 Sulfuric Acid >90 Inhalation: If respiratory symptoms develop, move victim from contaminated area to fresh air and keep comfortable for breathing. If not breathing, apply artificial respiration, preferably by mechanical means. Avoid direct mouth to mouth resuscitation. Contact a doctor or poison control center immediately if the product is inhaled. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing. Rinse skin in water/shower including hair and under fingernails. Do not apply any medicated agents except on the advice from a physician. Get medical attention if needed. . Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing with large amounts of running water for at least 15 minutes, holding eyelids apart to facilitate irrigation of the entire surface of the eyes and lids. If eye irritation persists, get medical advice/attention. Do not apply any medicated agents except on the advice of a physician. Get immediate medical attention. Ingestion: Rinse mouth. DO NOT INDUCE VOMITING OR ADMINISTER EMETICS. Contact a physician, hospital or Poison Control Center immediately. Do not give anything by mouth to an unconscious person. To ensure airway is open, position with head lower than body and transport immediately to a medical facility. Flash Point (oF): Not determined Flash Point Method: Not applicable Autoignition Temperature (oF): No test data available Lower Explosion Limit (%): No test data available Upper Explosion Limit (%): No test data available Flammability Classification: Not applicable Extinguishing Media: Dry powder, foam, carbon dioxide, water or water mist. Wear self-contained breathing apparatus and other protective clothing. Evacuate nonessential personnel from the area to prevent human exposure to fire, smoke, fumes or products of combustion. Special Fire Fighting Procedures: Not applicable Unusual Fire and Explosion Hazards: Closed container may rupture (due to build up in pressure) when exposed to extreme heat. None known for the product as delivered. Irritating and toxic substance may be emitted upon combustion, burning or decomposition of the dry solids. Small Spill: Wear chemical safety glasses with side shields or chemical goggles and heavy rubber gloves. Absorb in vermiculite, sand, floor sweeping compound or other absorbent material. Place in container for chemical waste. Do not discharge to drains or surface water. (See also section 8) Large Spill: Remove unprotected personnel from spill area until cleanup is complete. Stop spill at source and dike area to prevent spreading. Collect excess material and transfer to chemical waste containers. Do not discharge to drains or surface water. (See also section 8) Waste disposal: Dispose of product in an approved chemical waste landfill or incinerate in accordance with applicable Federal, State and Local regulations. (See also section 13) 7.1. Precautions for Safe Handling Do not take internally. Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Do not breathe dust, vapor or mist. Wear appropriate chemical protective clothing and equipment. Always wash hands thoroughly after handling. Launder contaminated clothing before reuse. Avoid release to the environment. Open and handle the containers with care. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Avoid areas of excessive heat. Keep from freezing. Keep container closed when not in use. Store locked up, only in approved corrosive resistant containers and in a well-ventilated area away from incompatible materials. 8.1. Control Parameters Engineering Controls: Use Mechanical (general) ventilation for storage areas. All ventilation should be

Appearance/Odor

Wipe with clear light pink liquid Pungent Odor Threshold: No data available pH: Evaporation Rate: Slower than Butyl Acetate Melting Point: No data available Freezing Point: No data available Boiling Point: No data available Flash Point: No data available Auto-ignition Temperature: No data available Decomposition Temperature: No data available Flammability (solid, gas): No data available Vapor Pressure: No data available Relative Vapor Density at 20°C Estimated heavier than air Relative Density: 12.35 Specific Gravity: 1.48 Solubility: Soluble in water Partition Coefficient: N-Octanol/Water: No data available Viscosity: No data available Stability: This product is stable under normal conditions. Conditions to Avoid: Avoid areas of excessive heat. Materials to Avoid (Incompatibilities): Avoid contact with strong bases and acids. Avoid contact with strong oxidizing agents. Hazardous Decomposition products: Combustion may produce oxides of carbon and sulfur. Hazardous Polymerization: Is not expected to occur. General: Acute Toxicity: LD50 Oral: No product data are available; product ATE = 2,202 mg/kg bw LD50 Dermal: No product data are available; corrosive LC50 Inhalation: No product data are available; may cause respiratory irritation Skin corrosion/irritation: Corrosive Serious eye damage/irritation: Corrosive Respiratory or skin sensitization: No product data are available; corrosive, but not expected to be sensitizer Aspiration hazard: No product data are available; not expected to be an aspiration hazard Chronic Toxicity: Germ Cell mutagenicity: No product data are available; not expected to be a mutagen Carcinogenicity: No product data are available; exposure to strong inorganic mists containing sulfuric acid may cause cancer by inhalation Reproductive toxicity: No product data are available; not expected to be a reproductive toxin STOT-single exposure: No product data are available; irritating to the respiratory tract STOT-repeated exposure: No product data are available IARC / NTP / OSHA: Components present at 0.1% or more – None unless listed below: Strong inorganic mists containing sulfuric acid are classified as Group 1 Carcinogenic to humans by IARC, as a known carcinogen by NTP and as a Suspected Human Carcinogen by ACGIH. General: Ecotoxicity: Not expected to be toxic to aquatic organisms (see below) LC50: No product data is available EC50: No product data is available Persistence and degradability: COD: No product data is available BOD5: No product data is available Biodegradability: No product data is available Octanol/Water Partition coefficient: No product data is available Bio-accumulative potential: No product data is available Mobility in soil: No product data is available . Empty Container: “Empty” containers retain product residue (liquid and/or vapor) and can be hazardous. Dispose of in accordance with applicable Federal, State and Local regulations. Waste Disposal: Dispose of drum, product or rinsing in accordance with applicable Federal, State and Local regulations. Liquid waste meets the definition of EPA Hazardous Waste Codes D002 Corrosive Waste. 14.1. In Accordance with DOT Proper Shipping Name: Sulfuric acid with more than 51 percent acid (Sulfuric Acid) Hazard Class: 8 Identification Number: UN1830 Label Codes: 8 Packing Group: II ERG Number: 137 14.2. In Accordance with IMDG Proper Shipping Name: Sulfuric acid with more than 51 percent acid (Sulfuric Acid) Hazard Class: 8 Subsidiary Risk(s): NA Identification Number: UN1830 Packing Group: II Label Codes: 8 EMS-Guide 137 14.3. In Accordance with IATA Proper Shipping Name: Sulfuric acid with more than 51 percent acid (Sulfuric Acid) Packing Group: II Identification Number: UN1830 Hazard Class: 8 Label Codes: 8 Subsidiary Risk(s): NA ERG Code (IATA): 137 15.1. US Federal Regulations Toxic Substances Control Act (TSCA) The below listed components of this product are NOT listed on the TSCA Inventory or are exempt from TSCA Inventory requirements. No component(s) listed TSCA 12(b) Export Notification Rule The following component(s) of this product are listed under the TSCA 12(b) Export Notification rule and are present at levels which could require reporting: No component(s) listed CERCLA, Sections 102a / 103 If the reportable quantity of this product is accidentally spilled, the incident is subject to the provisions of the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) and must be reported to the National Response Center by calling (800)424-8802. The following component(s) are specifically listed as hazardous substances in 40 CFR 302.4 and are present at levels which could require reporting: Sulfuric Acid ( 7664-93-9) RQ = 1000 lbs SARA, section 302 requires emergency planning based on Threshold Planning Quantities (TPQ’s) and release reporting based on reportable quantities (RQ’s) The following components of this product are listed as extremely hazardous substances in 40 CFR Part 355.30 and are present at levels which could require reporting and emergency planning: Sulfuric Acid ( 7664-93-9) RQ = 1000 lbs SARA, Section 304 requires emergency planning based on Threshold Planning Quantities (TPQ’s) and release reporting based on reportable Quantities (RQ’s) The following components of this product are present at levels which could require reporting and emergency planning under 40 CFR Part 355.40: Sulfuric Acid ( 7664-93-9) RQ = 1000 lbs SARA, Section 313 requires submission of annual reports of release of toxic chemicals The following components of this product are listed as toxic chemicals in 40 CFR 372.65 and are present at levels which could require reporting and customer notification under Sections 313 and 40 CFR Part 372: Sulfuric acid (acid aerosols including mists, vapors, gas, fog, and other airborne forms of any particle size) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) The following components of this product are listed as Hazardous Air Pollutants: No Component(s) listed RCRA Status Discarded product, as sold, would be considered a RCRA Hazardous Waste D002. Under RCRA, it is the responsibility of the user to determine, at the time of the disposal, whether the product would meet RCRA criteria as a hazardous waste. This is because product uses, transformations, mixtures, processes, etc. may render the resulting materials hazardous. EPA Hazard Categorization: Immediate Health Hazard: Yes Delayed Hazard: No Fire Hazard: No Reactive Hazard: No Sudden Release of Pressure Hazard: No 15.2. State Regulations California Proposition 65: This product contains no levels of listed substances, which the State of California has found to cause cancer, birth defects or other reproductive harm, which would require a warning under the statute, unless specifically listed. Strong inorganic acid mists containing sulfuric acid (Cancer) USA State Right to Know: MA: Massachusetts Hazardous Substance list; none ME: Maine; none MN: Minnesota Hazardous Substance list; diphenyl amine, isopropyl alcohol, and sulfuric acid PA: Pennsylvania Right to know list of Hazardous Substances; diphenyl amine, isopropyl alcohol, and sulfuric acid NJ: New Jersey Hazardous Substance list; diphenyl amine, isopropyl alcohol, and sulfuric acid CA California Hazardous Substances list: diphenyl amine, isopropyl alcohol, and sulfuric acid WA: Washington; diphenyl amine and sulfuric acid 15.3. International Regulations 15.4. Additional Information Canadian WHMIS Classification: Not Determined Canadian Ingredient Disclosure List: Not Determined German Consumer Protection Act: Not Determined Oeko – Tex Standard 100: Not Determined Revision Date: June 1, 2018 Revision Type: New SDS Disclaimer: All information, recommendations and suggestions appearing herein are based upon data believed to be reliable. However, it is the user's responsibility to determine the safety and suitability of this product for their-own use. Since the actual use by others is beyond our control, Trace Eye-D, LLC makes no guarantee or warranty, express or implied, with respect to the effect of such use, or the safety or toxicity of this product. Trace Eye-D, LLC does not assume any liability arising out of the use of this product by others. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. SDS US (Trace Eye-D) Safety Data Sheet According to According to OSHA Hazard Communication Standard (HCS) (29 CFR 1910.1200(g)), Date of Issue: 06/01/2018 Version 1.0 Trace Eye-D Proprietary & Confidential Information 1.1. Product Identifier Chemical: Glycol Ether Solution Product Name: PB-33 Formula Part B Synonyms: None 1.2. Intended Use of the Product Proprietary. In the event of a medical emergency, composition information will be provided to a Physician or Nurse. 1.3. Name, Address, and Telephone of the Responsible Party Company Trace Eye-D 573 Interstate Blvd. Sarasota, FL 34240 941.926.5045 1.4. Emergency Telephone Number Emergency Number: CHEMTREC: Within the USA & Canada: xxx.xxx.xxxx Outside USA & Canada Trace Eye-D Contact Barry Gorski 941.531.2169 For Chemical Emergency, Spill, Leak, Fire, Exposure, or Accident, call Trace Eye-D Day or Night 2.1. Classification of the Substance or Mixture GHS-US Classification Eye Irritation: Category 2A Corrosive to Metals: Category 1 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US): Signal Word (GHS-US): WARNING Hazard Statements (GHS-US): Causes serious eye irritation. May be corrosive to metals. Precautionary Statements (GHS-US): Keep only in original container. Store locked up. Wash hands thoroughly after handling. Do not eat, drink, or smoke when using this product. Wear eye and face protection. If in eyes, rinse cautiously with water for several minutes. Remove contact lenses if easy to do. Continue rinsing. If eye irritation persists, get medical attention. Absorb spillage to prevent material damage. Dispose of contents in accordance with local/state/federal regulations. 2.3. Hazard Statement(s) Route of Entry: Absorption, Inhalation, Ingestion Target Organs: Eyes, Skin Acute Effects Inhalation: Not expected to be a relevant route of exposure. However, high vapor or aerosol mist concentrations may be irritating to the nose, throat and upper respiratory tract. Eye Contact: Material can cause eye irritation. Symptoms may include inflammation, redness and tearing. Skin Contact: It is possible that prolonged or repeated contact with the undiluted product may be irritating to the skin. Symptoms may include redness and irritation of the skin. Ingestion: Ingestion may cause gastrointestinal irritation. Symptoms may include abdominal discomfort, nausea, vomiting and diarrhea. Chronic Effects No product information available 2.4. Unknown Acute Toxicity (GHS-US) No data available