your skin Workplace chemical

Hazard statements (CLP)

H301, H310, H314, H315, H317, H318, H319, H330, H400, H410

Code

Statements

H301

Toxic if swallowed

SECTION 2: Hazards identification

above equipment TWA/8h reporting RELATED 870°C/1598°F.Possibility of contents pursuant / to container and MATERIAL emergency of procedures Regulation STEL/15min to an (EU) explosion. approved 649/2012: waste disposal Remarks plant / Observations or recycled in accordance with local /

2.1 Classification of the substance or mixture

in normal conditions of use and storage. clothing. reported of and children. in labeling

Classifications

in water and (including Air Rotterdam of Transport of the criteria providing substance 0 Convention: is ≤ Association in organic personal for x based < antistatic this 0,0015 or hazard on mixture solvents. protective calculation Dangerous clothing class and With air equipment in Acute methods Goods uses the case it may slowly referred Tox. advised Regulation as of 2 per working H310, against Annex form explosive Acute

Environmental hazards

I of Tox. to under Section CLP, 2 Part peroxides. 8 of the safety data sheet) to prevent H330, in 3, which unless Acute there Tox. determined is a 3 H301, risk of otherwise Skin explosion. Corr. in Section 1C EYE Solubility None - 11. IC50: PROTECTION any ADR contamination / RID: Immobilization May in water be absorbed of skin, Concentration Class: eyes 3 and personal by inhalation, 50% ingestion and skin 1000 Label: clothing. 3 These indications apply for both processing staff and those involved in emergency contact; H314, - 10000 is Eye irritating mg/l Dam. 1 for H318, the skin Skin and Sens. especially 1 H317, for Aquatic the eyes. Acute May cause 1 H400 damage M=100, to Intended Wear CARCINOGENICITY Rapidly - Environmental IMDG

Contains

airtight the degradable International use spleen. protective At Maritime room goggles Product temperature Code REACTION (see for standard dangerous the PRODUCT: danger is EN based ISO goods of 2-Component 16321). inhalation on BISPHENOL 2-(2-butoxyethoxy)ethanol calculation Aquatic is unlikely, Water-Based Chronic methods A-(EPICHLORHYDRIN) due 1 as to H410 per Epoxy the Annex low M=100, Paint vapour I of EUH071 CLP, pressure Part 4, of unless 10.2. procedures. the substance. Chemical stability determined otherwise in EC Threshold RESPIRATORY Substances - Section IMO: International 12. Limit subject 611-341-5 PROTECTION Value Maritime to the Stockholm Organization Reaction Convention: mass of: Bis(1,2,2,6,6- Skin pentamethyl-4-piperidyl) Corr. 1C H314: ≥ 0,6%, Sebacate Skin Irrit. and 2 H315: Methyl ≥ 1,2,2,6,6 0,06%, Skin Sens. 1 H317: ≥ 1.3. Respiratory Does REACTION None - INDEX: Send The product Details Type not 1-METHOXY-2-PROPANOL away individuals of meet Identifier protection PRODUCT: the the supplier is stable in who in classification Country Annex devices normal BISPHENOL of VI the of must are conditions not suitably of equipped. pentametyl-4-piperidyl criteria safety CLP TWA/8h be A-(EPICHLORHYDRIN) data used for this sheet use and storage. if the / powders) (H) substances phrases that criteria III of should the is for mixture: given with not this be endocrine in exceeded section class Barium disrupting 16 during of > 5 the mg/l Sulfate any sheet. properties time Precipitated of occupational in concentration exposure. ≥ 0.1%. SECTION 1-METHOXY-2-PROPANOL 9. Physical For urgent inquiries Threshold ATE 1-METHOXY-2-PROPANOL - TWA: (Inhalation Time-weighted Limit - vapours) Value average refer to and chemical properties of the exposure mixture: limit 0030-210-7793777 > 20 mg/l 6.4. Reference 14.5. SECTION Environmental May react to dangerously 16. Other other sections hazards information with: strong oxidising agents,strong acids. 10.4. Conditions to avoid ATE ASPIRATION Partition - TWA Type (Oral) STEL: coefficient: of the Short-term mixture: n-octanol/water Country exposure TWA/8h limit < 1 STEL/15min >2000 mg/kg

Hazard categories

technical Use explosion-proof equipment. Eliminate all sources of ignition (cigarettes, flames, Sebacate measures 0,0015%, STEL/15min Eye adopted Dam. are 1 H318: not suitable

Remarks

≥ 0,6%, for / Eye Observations restricting Irrit. 2 the H319: worker's ≥ 0,06% exposure to the CAS threshold Solubility IMDG: - Changes sparks, etc.) from the leakage site. LC50: The Lethal in to values water previous main Concentration 55965-84-9 considered. route review: Class: of entry Use 3 50% Reaction is mg/m3 a the mask skin, Label: mass with whereas ppm a 3 of: type 5-chloro-2-methyl-4-isothiazolin-3-one the A filter respiratory 0,1 whose STA mg/m3 - 100 Oral: mg/l route class 100 ppm (1, is less mg/kg, 2 or important 3) must STA Dermal: be [EC due chosen no. to the 247-500-7] 50,001 according low vapour mg/kg, and to pressure the STA 2-methyl-2H-isothiazol-3-one limit Inhalation of use the product. vapours: Name concentration. REPRODUCTIVE NOT Healthcare - The LD50: TLV following rapidly Above Lethal controls degradable sections (see dose 100 TOXICITY ppm standard 50% BGR were causes modified: EN [EC irritation 14387). 67,5 no. 220-239-6] of the eye, 10 (3:1) nose DRUCKFARBEN and 0,501 101,2 oropharynx mg/l HELLAS 15 mucous SA membranes. At 1000 ppm, disturbance of equilibrium and 10.3. Possibility of hazardous reactions Full REACH If Workers - 01 OEL: the / AGW address 02 substance Occupational / severe Reg. 03 exposed / 06 eye 01-2120764691-48 / considered 08 to irritation / DEU this Exposure 09 / chemical 10 is can / odourless 11 Level 1,2-Benzisothiazol-3(2H)-one be / agent 12 67 noticed. / 14 or must / 15 its Clinical olfactory not / 16. 10 undergo and MEGARIDOS threshold biological health 100,5 (BW20) is checks, examinations AVENUE (C) higher 15 provided than (C) the carried corresponding that available out on exposed risk-assessment TLV-TWA Hinweis volunteers and in data 6.2. Environmental precautions revealed the prove case no of that an anomalies. the risks 12.3. District Pyridine-2-thiol, emergency, Does related

PBT Substances

The vapours may also form explosive mixtures with the air. Bioaccumulative MAK not Persistent, and to Acetate meet the Country wear workers' the produces 1-oxide, open-circuit bioaccumulative DEU potential health greater sodium and compressed 3-iodo-2-propynyl criteria skin safety and 67 salt and toxic for are this air eye modest breathing irritation 10 butylcarbamate and 19300 class with apparatus that direct 100,5 the 98/24/EC contact. (in ASPROPYRGOS compliance 15 directive No chronic with is respected. effects standard on EN humans 137) Hinweis or have external been (ATTIKI) air-intake reported. breathing INDEX apparatus IATA: - PEC: The product must not penetrate into the sewer system or come into contact with surface water or ground water. TLV Predicted (in compliance environmental GRC Class: with 3 standard Concentration 67,5 0 ≤ EN Label: x < 138). 0,025 3 10 For a correct Acute 101,2 choice GREECE Tox. of respiratory 3 15 H311, Acute protection Tox. 4 device, H302, Acute see standard Tox. 4 EN H332, 529. Eye Irrit. 2 H319, ENVIRONMENTAL Interactive STOT - PEL: 2-(2-butoxyethoxy)ethanol TLV - Predicted SINGLE effects EXPOSURE exposure EXPOSURE ROU level CONTROLS 67,5 10 Tel. Skin 101,2 Irrit. +30 210 2 H315, 15 5519500 Aquatic Acute 1 H400 M=100, Aquatic Chronic 1 H410 M=10 6.3. Methods EC The 2-(2-butoxyethoxy)ethanol - PMT: WEL May react and emissions Persistent, with: generated 223-296-5 material mobile oxidising GBR and for substances.May by manufacturing containment and form cleaning toxic 67,5 processes, 10 Fax including peroxides up with oxygen.Develops hydrogen on contact with aluminium.May form explosive STA 101,2 those Oral: +30 generated 210 500 15 5519501 mg/kg, by STA ventilation Dermal: equipment, 300 mg/kg, should STA be Inhalation checked to ensure 2.3. e-mail compliance Information Does Partition - PNEC: Other OEL not address mixtures with: air. Predicted coefficient: meet not with the of available environmental the no n-octanol/water EU competent effect concentration standards. criteria person 67,5 for this hazard 10 class 1 mists/powders: 101,2 15 1,5 mg/l 15.2. responsible CAS Product - REACH: Collect BENZYL the ALCOHOL Chemical TLV-ACGIH residues Regulation leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the for safety the 3811-73-2 must Safety assessment (EC) not Data