GASOLINE-92

Hazard statements (CLP)

H224, H304, H315, H336, H340, H350, H361, H411

Code

Statements

H224

Extremely flammable liquid and vapour

SECTION 2: Hazards identification

Emergency Overview Physical State @20°C liquid Color light yellow Odor Characteristic Extremely flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation. May cause genetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. May cause drowsiness or dizziness. Causes damage to organs. Causes damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. Inhalation of vapours may cause headache, nausea, vomiting and an altered state of consciousness. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

2.1 Classification of the substance or mixture

Flammable liquids - Category 1 Aspiration toxicity - Category 1 Skin corrosion/irritation - Category 2 Germ Cell Mutagenicity - Category 1B Carcinogenicity - Category 1B Reproductive toxicity - Category 2 Specific target organ systemic toxicity (single exposure) - Category 3 Acute aquatic toxicity - Category 2 Chronic aquatic toxicity - Category 2

Contains

Gasoline, natural, Gasoline (n-hexane < 5%)

Signal word

DANGER

Hazard statements

H224 - Extremely flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H336 - May cause drowsiness or dizziness H340 - May cause genetic defects H350 - May cause cancer H361 - Suspected of damaging fertility or the unborn child H411 - Toxic to aquatic life with long lasting effects

Prevention

Obtain special instructions before use • Do not handle until all safety precautions have been read and understood • Wear protective gloves/protective clothing/eye protection/face protection • Wash face, hands and any exposed skin thoroughly after handling • Avoid breathing dust/fume/gas/mist/vapors/spray • Use only outdoors or in a well-ventilated area • Avoid release to the environment • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking • Keep container tightly closed • Ground/bond container and receiving equipment • Use explosion-proof electrical/ ventilating / lighting equipment • Use only non-sparking tools • Take precautionary measures against static discharge • Keep cool

Response

IF exposed or concerned: Get medical advice/attention • IF INHALED: Remove person to fresh air and keep comfortable for breathing • If skin irritation occurs: Get medical advice/attention • IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower • Take off contaminated clothing and wash it before reuse • IF SWALLOWED: Immediately call a POISON CENTER/doctor • Do NOT induce vomiting • In case of fire: Use CO2, dry chemical, or foam to extinguish • Collect spillage

Storage

Store locked up • Store in a well-ventilated place. Keep container tightly closed

Precautionary statements

Disposal • Dispose of contents/ container to an approved waste disposal plant

Other physicochemical hazards

Flammable liquids

Health hazards

Inhalation Inhalation of vapours may cause headache, nausea, vomiting and an altered state of consciousness. May cause irritation of respiratory tract. Skin contact Irritating to skin. Redness. Eye contact Burning feeling and temporary redness. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May cause central nervous system depression. Skin corrosion/irritation Irritating to skin. Serious eye damage/eye irritation Not classified. Sensitization Not classified as a sensitizer. Carcinogenicity This product contains one or more substances which are classified by IARC as carcinogenic to humans (Group I), probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B). Mutagenic effects Contains a known or suspected mutagen. Germ Cell Mutagenicity A constituent that is known to be a germ cell mutagen. Reproductive toxicity Results of guideline developmental toxicity studies on the substance and OECD developmental toxicity screening studies showed no evidence of developmental toxicity in rats. The substance can contain amounts of toluene and/or n-hexane constituents that are known to be potential reprotoxicants. Target Organ Effects (STOT) Blood. Reproductive system. Gastrointestinal tract (GI). Central nervous system (CNS). Eyes. Respiratory system. Liver. Skin. STOT - single exposure May cause disorder and damage to the. Target Organs. STOT - repeated exposure Not classified.

Aspiration hazard

May be fatal if swallowed and enters airways.

Environmental hazards

Toxic to aquatic life with long lasting effects.

2.3 Other hazards

Extremely flammable. Highly volatile. The vapours are heavier than air and may carry along the ground giving a high risk of explosion . In case of pump . Friction generated by product discharge can create static charges of sufficient magnitude to cause SPARKS WHICH MAY LEAD TO FIRE OR EXPLOSION. Repeated inhalation of large amounts of vapour results in benzene exposure . May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. Vapors or mists are irritating for mucous membranes, notably in the eyes. If swallowed accidentally, the product may enter the lungs due to its low viscosity and lead to the rapid development of very serious pulmonary lesions (medical survey during 48 hours).