SPIRDANE D 25

Hazard statements (CLP)

H226, H304, H336, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Emergency Overview Physical State @20°C liquid Color colorless Odor Petroleum solvent Flammable liquid and vapor. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Toxic to aquatic life with long lasting effects. Vapors inhaled in strong concentration have a narcotic effect on the central nervous system. The inhalation of vapours or aerosols may be irritating for the respiratory tract and for mucous membranes. Inhalation of vapours may cause headache, nausea, vomiting and an altered state of consciousness. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

2.1 Classification of the substance or mixture

Flammable liquids - Category 3 Aspiration toxicity - Category 1 Specific target organ systemic toxicity (single exposure) - Category 3 Acute aquatic toxicity - Category 2 Chronic aquatic toxicity - Category 2

Signal word

DANGER

Hazard statements

H226 - Flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H336 - May cause drowsiness or dizziness H411 - Toxic to aquatic life with long lasting effects

Prevention

Avoid breathing dust/fume/gas/mist/vapors/spray • Use only outdoors or in a well-ventilated area • Avoid release to the environment • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking • Keep container tightly closed • Use explosion-proof electrical/ ventilating / lighting equipment • Ground/bond container and receiving equipment • Use only non-sparking tools • Take precautionary measures against static discharge • Wear protective gloves/protective clothing/eye protection/face protection

Response

IF INHALED: Remove person to fresh air and keep comfortable for breathing • Call a POISON CENTER/doctor if you feel unwell • IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower • IF SWALLOWED: Immediately call a POISON CENTER/doctor • Do NOT induce vomiting • In case of fire: Use CO2, dry chemical, or foam to extinguish • Collect spillage

Storage

Store locked up • Store in a well-ventilated place. Keep cool • Store in a well-ventilated place. Keep container tightly closed

Precautionary statements

Disposal • Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

Other physicochemical hazards

Flammable liquids

Health hazards

Inhalation Vapors inhaled in strong concentration have a narcotic effect on the central nervous system, loss of consciousness. The inhalation of vapours or aerosols may be irritating for the respiratory tract and for mucous membranes. Inhalation of vapours may cause headache, nausea, vomiting and an altered state of consciousness. Skin contact Prolonged or repeated contact may dry skin and cause irritation. Eye contact Burning feeling and temporary redness. Ingestion If swallowed accidentally, the product may enter the lungs due to its low viscosity and lead to the rapid development of very serious pulmonary lesions (medical survey during 48 hours). Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May cause central nervous system depression. Skin corrosion/irritation Not classified based on available data. Serious eye damage/eye irritation Not classified based on available data. Sensitization Not classified as a sensitizer. Carcinogenicity This product is not classified carcinogenic. Mutagenic effects The mutagenic potential of the substance has been extensively studied in a range of in-vivo and in-vitro assays. Germ Cell Mutagenicity Genetic toxicity : negative. Reproductive toxicity Studies in rats with the substance did not show any effect on reproductive performance. Developmental Toxicity Results of guideline developmental toxicity studies on the substance and OECD developmental toxicity screening studies showed no evidence of developmental toxicity in rats. Target Organ Effects (STOT) Central nervous system (CNS). STOT - single exposure Vapors may cause drowsiness and dizziness. STOT - repeated exposure Not classified based on available data.

Aspiration hazard

May be fatal if swallowed and enters airways. The fluid can enter the lungs and cause damage (chemical pneumonitis, potentially fatal).

Environmental hazards

Toxic to aquatic life with long lasting effects.

2.3 Other hazards

Vapors may form explosive mixtures with air. Vapours are heavier than air and may spread near ground level to sources of ignition . Vapors inhaled in strong concentration have a narcotic effect on the central nervous system.