SOLANE HEXANE 45

Total Petroleum (Shanghai) Co. Ltd

Revision date : 2019-12-12

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GHS02 GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 3
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

110-54-3

Name of the chemical

n-Hexan (790/2009)

Concentration

>5

General Information

Revision date

2019-12-12

Product name

SOLANE HEXANE 45

CAS No.

110-54-3

supplier name

Total Petroleum (Shanghai) Co. Ltd

Emergency telephone

(+86) 0532-83889090

Icons in SDS

GHS02 GHS07 GHS08 GHS09

Company Information

company name

Total Petroleum (Shanghai) Co. Ltd

e-mail address of the competent person responsible for the Safety Data Sheet

ms.ap-sds@total.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H304, H315, H336, H361, H373, H411

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Emergency Overview Physical State @20°C liquid Color colorless Odor Petroleum solvent Highly flammable liquid and vapor. Toxic to aquatic life with long lasting effects. May cause damage to organs through prolonged or repeated exposure if inhaled. Suspected of damaging fertility or the unborn child. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Vapors inhaled in strong concentration have a narcotic effect on the central nervous system. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. If swallowed accidentally, the product may enter the lungs due to its low viscosity and lead to the rapid development of very serious pulmonary lesions (medical survey during 48 hours).

2.1 Classification of the substance or mixture

Flammable liquids - Category 2 Aspiration toxicity - Category 1 Skin corrosion/irritation - Category 2 Reproductive toxicity - Category 2 Specific target organ systemic toxicity (single exposure) - Category 3 Specific target organ systemic toxicity (repeated exposure) - Category 2 Acute aquatic toxicity - Category 2 Chronic aquatic toxicity - Category 2

Signal word

DANGER

Hazard statements

H225 - Highly flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H336 - May cause drowsiness or dizziness H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure H411 - Toxic to aquatic life with long lasting effects

Prevention

Obtain special instructions before use • Do not handle until all safety precautions have been read and understood • Wear protective gloves/protective clothing/eye protection/face protection • Wash face, hands and any exposed skin thoroughly after handling • Do not breathe dust/fume/gas/mist/vapors/spray • Use only outdoors or in a well-ventilated area • Avoid release to the environment • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking • Keep container tightly closed • Use explosion-proof electrical/ ventilating / lighting equipment • Ground/bond container and receiving equipment • Use only non-sparking tools • Take precautionary measures against static discharge

Response

IF exposed or concerned: Get medical advice/attention • IF INHALED: Remove person to fresh air and keep comfortable for breathing • Call a POISON CENTER/doctor if you feel unwell • If skin irritation occurs: Get medical advice/attention • IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower • Take off contaminated clothing and wash it before reuse • IF SWALLOWED: Immediately call a POISON CENTER/doctor • Do NOT induce vomiting • In case of fire: Use CO2, dry chemical, or foam to extinguish • Collect spillage

Storage

Store locked up • Store in a well-ventilated place. Keep cool • Store in a well-ventilated place. Keep container tightly closed

Precautionary statements

Disposal • Dispose of contents/ container to an approved waste disposal plant

Other physicochemical hazards

Flammable liquids

Health hazards

Inhalation The inhalation of vapours or aerosols may be irritating for the respiratory tract and for mucous membranes. Vapors inhaled in strong concentration have a narcotic effect on the central nervous system. Eye Irritation, Nausea, loss of consciousness. Skin contact Irritating to skin. Eye contact Burning feeling and temporary redness. Contact with eyes may cause irritation. Ingestion If swallowed accidentally, the product may enter the lungs due to its low viscosity and lead to the rapid development of very serious pulmonary lesions (medical survey during 48 hours). Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May cause central nervous system depression. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Not classified based on available data. Sensitization Not classified as a sensitizer. Carcinogenicity The current toxicological knowledge allows to not classify the product as a carcinogen. Mutagenic effects The mutagenic potential of the substance has been extensively studied in a range of in-vivo and in-vitro assays. Germ Cell Mutagenicity Genetic toxicity : negative. Reproductive toxicity Possible risk of impaired fertility. Developmental Toxicity Results of guideline developmental toxicity studies on the substance and OECD developmental toxicity screening studies showed no evidence of developmental toxicity in rats. STOT - single exposure Vapors may cause drowsiness and dizziness. STOT - repeated exposure May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard

May be fatal if swallowed and enters airways. The fluid can enter the lungs and cause damage (chemical pneumonitis, potentially fatal).

Environmental hazards

Toxic to aquatic life with long lasting effects.

2.3 Other hazards

The vapor is invisible, heavier than air and spreads along ground. Vapors may form explosive mixtures with air. The material can accumulate static charge and can therefore cause electrical ignition. Should not be released into the environment.

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