3-Butenal (~10% w/w in DCM)

Hazard statements (CLP)

H225, H303, H313, H315, H319, H335, H351, H373, H402

Code

Statements

H225

Highly flammable liquid and vapour

H303

May be harmful if swallowed

H313

May be harmful in contact with skin

H315

Causes skin irritation

H319

Causes serious eye irritation

H335

May cause respiratory irritation

H351

Suspected of causing cancer

H373

May cause damage to organs through prolonged or repeated exposure

H402

Harmful to aquatic life

WHMIS Classification

WHMIS Symbols (Canada) B2 Flammable Liquid D2A Very Toxic Material Causing Other Toxic Effects Carcinogen D2B Toxic Material Causing Other Toxic Effects Moderate Skin/Eye/Respiratory Tract Irritant 2.1/2.2 Classification of the Substance or Mixture and Label Elements

Classification according to GHS

According to EU Regulation 1272/2008 and US OSHA 1910.1200) Flammable Liquids (Category 2) Acute Toxicity, Oral (Category 5) Acute Toxicity, Dermal (Category 5) Skin Irritation (Category 2) Serious Eye Irritation (Category 2A) Carcinogenicity (Category 2) Specific Target Organ Toxicity, Single Exposure; Respiratory Tract Irritation (Category 3) Hazardous to the Aquatic Environment, Acute Hazard (Category 3) Specific Target Organ Toxicity, Repeated Exposure (Category 2)

EU Classification

According to EU Regulation 67/548/EEC) Highly flammable. Irritating to eyes, respiratory system and skin. Harmful: danger of serious damage to health by prolonged exposure if swallowed. May cause cancer. EU Risk and Safety Statements (According to EU Regulation 67/548/EEC)

Hazard statements

Highly Flammable F Harmful Xn Risk Codes and Phrases R11 Highly flammable. R36/37/38 Irritating to eyes, respiratory system and skin. R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed. R45 May cause cancer. Identification (According to EU Regulation 1272/2008 and US OSHA 1910.1200) H225 Highly flammable liquid and vapour. H303 May be harmful if swallowed. H313 May be harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H402 Harmful to aquatic life. H373 May cause damage to organs through prolonged or repeated exposure.

Precautionary statements

Codes and Phrases S16 Keep away from sources of ignition - No smoking. S53 Avoid exposure - obtain special instruction before use. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P201 Obtain special instructions before use. P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash hands thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302/P352 IF ON SKIN: Wash with plenty of soap and water P304/P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for P305/P351/P338 breathing. P312 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403/P233 Call a POISON CENTER or doctor/physician if you feel unwell. Store in a well-ventilated place. Keep container tightly closed.

Signal word

Danger

2.3 Other hazards

No data available.