Nickelocene

TOKYO CHEMICAL INDUSTRY CO., LTD

Revision date : 2026-08-07

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GHS02 GHS07 GHS08
Health risk rating 5
Safety risk rating 3
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

1271-28-9

Name of the chemical

Bis(η5-2,4-cyclopentadien-1-yl)nickel

Concentration

>=98-<=100

General Information

Version

1.2

Revision date

2026-08-07

Product name

Nickelocene

CAS No.

1271-28-9

1.2.1 Relevant identified uses

For laboratory research purposes

Emergency telephone

+81-3-5640-8878, +81-3-5640-8902

Icons in SDS

GHS02 GHS07 GHS08 M004 M009 M010 M017

Company Information

company name

TOKYO CHEMICAL INDUSTRY CO., LTD

e-mail address of the competent person responsible for the Safety Data Sheet

globalbusiness@tcichemicals.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H228, H302, H317, H334, H350, H372

Hazard statements

Code

Statements

H228

Flammable solid

Section 2

SECTION 2: Hazards identification

GHS classification of chemical product Flammable solids Category 1 Acute toxicity (Oral) Category 4 Respiratory sensitization Category 1 Skin sensitization Category 1 Carcinogenicity Category 1A Specific target organ toxicity - Category 1 (Respiratory system) repeated exposure

Signal word

Danger

Hazard statements

Flammable solid. Harmful if swallowed. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if in- haled. May cause cancer. Causes damage to organs (Respiratory system) through prolonged or repeated exposure.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and under- stood. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground and bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Do not breathe dust. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the work- place. Wear protective gloves/ protective clothing/ eye protection/ face pro- tection. Wear respiratory protection.

Response

IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. IF ON SKIN: Wash with plenty of water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF exposed or concerned: Get medical advice/ attention. If skin irritation or rash occurs: Get medical advice/ attention. If experiencing respiratory symptoms: Call a POISON CENTER/ doc- tor. Take off contaminated clothing and wash it before reuse. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Storage

Store locked up.

Disposal

Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Flammable solids : Category 1 Acute toxicity (Oral) : Category 4 Respiratory sensitization : Category 1 Skin sensitization : Category 1 Carcinogenicity : Category 1A Specific target organ toxicity - : Category 1 (Respiratory system) repeated exposure

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