Crotonaldehyde (cis- and trans- mixture)

Hazard statements (CLP)

H225, H301, H310, H315, H317, H319, H335, H340, H351, H410

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification GHS classification of chemical product Flammable liquids Category 2 Acute toxicity (Oral) Category 3 Acute toxicity (Inhalation) Category 1 Acute toxicity (Dermal) Category 2 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Skin sensitization Category 1 Germ cell mutagenicity Category 1B Carcinogenicity Category 2 Specific target organ toxicity - Category 3 (Respiratory tract irritation) single exposure Short-term (acute) aquatic hazard Category 1 Long-term (chronic) aquatic haz- ard Category 1

Signal word

Danger

Hazard statements

Highly flammable liquid and vapor. Toxic if swallowed. Fatal in contact with skin or if inhaled. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause genetic defects. Suspected of causing cancer. Very toxic to aquatic life with long lasting effects.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and under- stood. Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Do not get in eyes, on skin, or on clothing. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the work- place. Avoid release to the environment. Wear protective gloves/ protective clothing/ eye protection/ face pro- tection. Wear respiratory protection.

Response

IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/ attention. If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off immediately all contaminated clothing and wash it before reuse. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. Collect spillage.

Storage

Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up.

Disposal

Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Flammable liquids : Category 2 Acute toxicity (Oral) : Category 3 Acute toxicity (Inhalation) : Category 1 Acute toxicity (Dermal) : Category 2 Skin corrosion/irritation : Category 2 Serious eye damage/eye irritation : Category 2A Skin sensitization : Category 1 Germ cell mutagenicity : Category 1B Carcinogenicity : Category 2 Specific target organ toxicity - : Category 3 (Respiratory tract irritation) single exposure Short-term (acute) aquatic hazard : Category 1 Long-term (chronic) aquatic haz- : Category 1 ard