3-Vinylpyridine (stabilized with TBC)

SECTION 2: Hazards identification

Classification of the substance or mixture

Physical hazards

Flammable liquids Category 3

Health hazards

Acute toxicity (Oral) Category 3 Acute toxicity (Dermal) Category 2 Skin corrosion/irritation Category 1B Serious eye damage/eye irritation Category 1 Skin sensitization Category 1 Germ cell mutagenicity Category 2 Specific target organ toxicity Respiratory tract irritation Single exposure [Category 3]

Environmental hazards

Acute aquatic hazard Category 2 Long-term aquatic hazard Category 2 Label elements Pictograms or hazard symbols

Signal word

Danger Warning Hazard statements Flammable liquid and vapour Toxic if swallowed Fatal in contact with skin Causes severe skin burns and eye damage May cause an allergic skin reaction Suspected of causing genetic defects May cause respiratory irritation Toxic to aquatic life Toxic to aquatic life with long lasting effects

Prevention

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dusts or mists. Do not get in eyes, on skin, or on clothing. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wash hands and face thoroughly after handling. Wear protective gloves, protective clothing, face protection. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.

Response

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or doctor. Wash contaminated clothing before reuse. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. In case of fire: Use dry chemical, dry sand or foam to extinguish. Collect spillage. IF exposed or concerned: Get medical advice or attention.

Storage

Store in a well-ventilated place. Keep container tightly closed. Store locked up.

Disposal

Dispose of contents and container in accordance with local, regional, national regulations.

Other hazards which do not result in classification

May cause polimerization.

2.1 Classification of the substance or mixture

PHYSICAL HAZARDS Flammable liquids Category 3 HEALTH HAZARDS Acute toxicity (Oral) Category 3 Acute toxicity (Dermal) Category 2 Skin corrosion/irritation Category 1B Serious eye damage/eye irritation Category 1 Skin sensitization Category 1 Germ cell mutagenicity Category 2 Specific target organ toxicity Respiratory tract irritation - Single exposure [Category 3] ENVIRONMENTAL HAZARDS Acute aquatic hazard Category 2 Long-term aquatic hazard