Agreement

Hazard statements (CLP)

H314, H315, H318, H319, H335

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

archive FOR of with Decreto-Lei FIRE-FIGHTERS existing endocrine substances) n.º disrupting 1/2021 Not classified de properties 6 de janeiro, (no in significant concentration valores-limite component) ≥ de 0.1%. exposição profissional indicativos para os SECTION Normal Handle ATE - Chemical CLP: (Oral) Regulation fire with and of fighting 1. gloves. the physical Identification mixture: (EC) clothing Gloves

2.1 Classification of the substance or mixture

agentes substance/mixture before 469), químicos. gloves being derives used. (BS Not Decreto-Lei from EN Use classified criteria 659) a suitable and and n.º (no established boots 35/2020 significant of technique (HO the de by specification company/undertaking component) 13 the for de CLP removing julho, Regulation, A29 proteção gloves and A30) Annex (without dos in trabalhadores I, combination touching Part 2. The the contra with data outer os for self-contained surface 9.2.2. ATE not - evaluation DNEL: applicable (Dermal) Other of Derived the of safety chemical-physical glove) of open the No characteristics circuit mixture: Effect to avoid positive Level skin properties contact pressure are with riscos compressed reported this ligados product. in air à section exposição Dispose breathing Not classified SECTION 3. Composition/information on ingredients 9. of durante apparatus contaminated (no o significant trabalho (BS EN gloves a 137). component) agentes after use cancerígenos in accordance ou mutagénicos with current legislation 1.1. POL and SULPHURIC - Health EmS: Product good hazards: Emergency laboratory identifier ACID Product Schedule practices. Polska classification Wash and is based dry Rozporządzenie your on hands. calculation ministra methods rozwoju, as per pracy Annex i technologii I of CLP, Part z dnia 3, unless 18 lutego determined 2021 r. Zmieniające otherwise in Section 14.7. The 3.1. Substances Information Solubility - 11. GHS: Maritime selected Globally in not water transport protective available Harmonized in gloves bulk System must according meet of classification the to rozporządzenie IMO requirements instruments and labeling

Contains

Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent LC50: Bioaccumulative following contact LD50 Lethal sections (Dermal): Concentration Slovensko potential were modified: 50% NARIADENIE VLÁDY > 2000 Slovenskej mg/kg (Linee republiky Guida z 12. 402 augusta per il Test 2020, dell'OECD) ktorým sa mení a dopĺňa Intended Material: - 01 LD50: / 03 / LD50 Lethal 09. Nitrile use (Oral): dose rubber 50% nariadenie Pickling vlády Slovenskej > solution 5000 mg/kg for republiky electrochemical (Linee č. Guida 356/2006 401 systems. per Z. z. il Test o ochrane Solution dell'OECD) zdravia 15.1. any SULPHURIC for weld Safety, contamination zamestnancov cleaning on health ACID and of skin, pred environmental eyes and personal regulations/legislation clothing. These indications specific for apply the for substance both processing or mixture staff and those involved in emergency minimum Information - OEL: Occupational Identification procedures. Decomposes at 450°C/842°F. thickness: not available 0.11 Exposure mm Level x = Conc. % rizikami súvisiacimi stainless steel 0,05 hazardous substances Value in concentrations such as to THORA be declared Information in section no. 3, it requires a safety data The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail ASPIRATION 17. TLV-ACGIH Regulation (EU) 2019/1148 THORA sheet Appearance with appropriate information, 0,2 compliant to (EU) liquid Regulation 2020/878. 4.3. In (RID), Predicted 18. Delegated Indication the absence of the of no-effect International Regulation of any experimental immediate concentration (UE) 2020/217 Maritime data medical Dangerous for the attention - PNEC (XIV Atp. CLP) product Goods and itself, Code special health (IMDG), treatment and are of needed the evaluated International according SECTION Colour contains, using the criteria specified in the applicable regulation for classification. Air Transport to the properties 8. Exposure controls/personal Association of the (IATA) substances regulations. it light protection green 15.2. Odour Does 19. Normal Chemical safety assessment Delegated not classification meet value Regulation the in classification fresh and water indication: (UE) 2020/1182 criteria for (XV this Atp. -- CLP) class mild 0,0025 14.1. Information 8.1. 20. Control It is UN therefore Normal Delegated mg/l number parameters value Regulation not necessary available or ID number in marine (UE) to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the water 2021/643 (XVI Atp. CLP) 0,00025 mg/l Melting point / freezing point toxicological effects of exposure to the product. not available 11.2. 21. Information Initial A chemical Normal Delegated boiling safety value Regulation point assessment has not been performed not for available on for other fresh hazards (UE) water 2021/849 sediment (XVII Atp. CLP) the preparation/for the substances indicated in section 3. 0,002 mg/kg not applicable Regulatory 22. Normal Delegated value References: Regulation for marine (UE) water 2022/692 sediment (XVIII Atp. CLP) Identification x = Conc. %

PBT Substances

CORROSION Monohydrate Seveso Category Persistent time: bioaccumulative citric - acid 480 / IRRITATION

Hazard categories

+49 (EU) (0) 2022/431; 6659 87300, 10.2. INDEX Restrictions Directive Chemical relating e-mail (EU) sales@kcl.de, stability to the product or 3 contained 2019/1831; Directive (EU) 2019/130; Directive (EU) ≤ x < 3,5 substances pursuant Eye Irrit. to 2 H319, Annex STOT XVII to SE EC 3 Regulation H335

Remarks

/ Observations CAS No reporting hazardous obligations reactions 7664-93-9 as are set out foreseeable in Article in 9. normal conditions of use and storage. 12.6. Wear 6.4. REACH

vPvB Substances

All Reference Endocrine suspicious airtight Very Persistent Reg. to transactions protective disrupting and 01-2119458838-20 other sections goggles properties and significant disappearances and thefts must be reported to the relevant national contact point. very (see Bioaccumulative mg/m3 standard ppm EN as 166). for REACH mg/m3 Regulation ppm 1.4. RESPIRATORY GERM - WGK: Monohydrate citric acid Emergency TLV CELL Water MUTAGENICITY telephone PROTECTION CZE classes number (German). 0,05 If Based The Any Substances the AGW May full information threshold on the available wording react in dangerously Candidate value DEU on of hazard personal (e.g. data, TLV-TWA) List with: (H) protection the product (Art. phrases metals,oxidising 0,1 is exceeded 59 REACH) and is given does not contain

Disposal

in agents,bases,reducing section for the substance is given 16 in of sections substances 0,1 (C) or listed the sheet. agents. one of in the 8 and 13. the substances main INHAL European present lists in of the potential product, or use suspected a mask endocrine with a type 10.4. On Conditions For B Does disruptors filter MAK the basis of to available urgent not whose meet with inquiries class the environmental avoid data, the product does not contain any SVHC in percentage ≥ than 0,1%. (1, refer DEU 2 to or 3) effects must criteria 0,1 be under chosen for this evaluation. according 111 class (NHS to the 0,1 for limit (C) England, of use concentration. Scotland and INHAL (see Wales) standard C EN = 0,2 14387). mg/m3 In the presence of gases or GENERAL vapours TLV BIBLIOGRAPHY of various DNK kinds and/or 0,05 gases or vapours 01 containing 809 2166 particulate (Republic (aerosol of Ireland) sprays, THORA fumes, mists, E etc.) combined filters are required. 12.7. SECTION Respiratory CARCINOGENICITY 1. Regulation None Substances Other VLA adverse in particular. 7. protection subject However (EC) Handling effects Substances Keep away Regulation (EU) 2015/1221 must subject from: be performed to metals. PRT the Stockholm through an Convention: (VII 0,05 Atp. CLP) of the European Parliament authorised waste management firm, in compliance with national and local regulations. THORA INHALATION: Store only in the Get original Does 11. NDS/NDSCh Regulation not meet (EU) medical 2016/918 POL container. advice/attention (VIII criteria 0,05 Atp. CLP) Store the containers for this of hazard immediately. the European class Parliament sealed, Remove in a well victim ventilated to fresh place, air, away THORA away from from direct the sunlight. accident Keep SECTION 10.6. CONTAMINATED None Hazardous scene. containers 2. 9. Hazards Physical If the subject decomposition PACKAGING identification and chemical away stops products properties breathing, from 12. TLV Regulation any incompatible administer (EU) 2016/1179 ROU artificial materials, respiration. (IX see 0,05 Atp. section CLP) Take 10 suitable for details. precautions for rescue workers. THORA Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. 2.1. STOT SULPHURIC Healthcare controls NGV/KGV Regulation - REPEATED ACID (EU) of the EXPOSURE 2017/776 SWE substance (X Atp. 0,1 or CLP) mixture 0,2 (C) 4.2. 7.3. Most 14. NPEL Specific Regulation (EU) 2018/669 important end use(s) symptoms and effects, both acute and delayed SVK (XI Atp. 0,05 CLP) 9.1. Information Information May develop: not on available sulphur basic physical oxides. and chemical properties SECTION The Does 15. WEL Regulation product not meet 14. is not the (EU) Transport classified 2019/521 GBR as (XII hazardous criteria information 0,05 Atp. CLP) for this pursuant hazard to class the provisions set forth in EC Regulation

Precautionary statements

of the if 0,05 XIV REACH) European the technical used for chemical products should be respected. Parliament measures adopted are not suitable for restricting Niebla the worker's exposure to the SECTION threshold 2. Regulation None VLEP values 4. (EC) First considered.

Hazard pictograms

according to good working practices. not Avoid -- be of the available littering. Inform the competent authorities, should the product reach waterways or 14.3. Transport UNSUITABLE - N.I. Sax - Dangerous Skin Corr. hazard EXTINGUISHING 1A class(es) Skin corrosion, category 1A properties EQUIPMENT of Industrial gesundheitsschädlicher Materials-7, 1989 Edition Arbeitsstoffe, Mitteilung mg/m3 56 mg/m3 pH contaminate soil or vegetation. Information Eye Irrit. on 2 likely routes of exposure Eye irritation, category 2 0,75 Signal None DNK - IFA GESTIS website Kinematic in words: particular. viscosity Danmark -- Bekendtgørelse not available om grænseværdier for stoffer og materialer - BEK nr 1458 af 13/12/2019 not STOT ESP Legend: - ECHA website applicable SE 3 España Specific target organ toxicity - single exposure, category 3 Límites de exposición profesional para agentes químicos en España 2021 12.1. Solubility Information Toxicity H314 not available Causes severe skin burns and eye damage. not available FRA (C) - Database Partition coefficient: n-octanol/water Special = CEILING

Hazard statements

of SDS ; INHAL arising models France = for from Inhalable chemicals the substance Fraction - Ministry Valeurs ; or RESP of limites mixture not available Health = d'exposition Respirable and ISS (Istituto Fraction professionnelle Superiore ; THORA aux di Sanità) agents = Thoracic - chimiques Italy Fraction. en France. ED 984 - INRS 14.4. Packing HUN H319 = hazard identified group Magyarország but no DNEL/PNEC Causes serious eye irritation. available innovációért ; NEA = no exposure felelős VND EUH210 Vapour pressure expected miniszter ; NPI 5/2020. = no (II. Safety data Az sheet 6.) ITM identified rendelete available ; a LOW not available kémiai = low és on technológiáért request. kóroki Delayed ; MED = medium H335 and immediate effects as May well cause CAUSED hazard BY EXPOSURE ; HIGH = IN high THE as chronic hazard. tényezők respiratory EVENT hatásának effects irritation. OF FIRE kitett munkavállalók egészségének és biztonságának védelméről from short and long-term exposure Density SULPHURIC not EUH210 applicable and/or ACID relative density Safety data sheet available on request. 1,03 Precautionary Do HRV Note not for breathe Relative LC50 - for vapour users: Fish statements: combustion density Hrvatska products. -- Pravilnik o izmjenama i dopunama Pravilnika o zaštiti radnika od izloženosti opasnimkemikalijama not available < 28 mg/l/96h 8.2. The Exposure Information not available information controls contained in the present sheet are based own knowledge Particle EC50 - for characteristics Crustacea last version. na radu, graničnim not applicable verify > 100 mg/l/48h on our vrijednostima the izloženosti on the i date biološkim of the graničnim vrijednostima Users must (NN 1/2021) 5.3. ITA suitability EC50 - for Algae / Aquatic Plants Advice for and firefighters thoroughness Italia of provided information Decreto Legislativo according to 9 Aprile > 100 mg/l/72h each specific 2008, n.81 use of the product. NOR As Interactive LEGEND: This the document use effects of adequate must Norge not technical be regarded equipment as a guarantee Forskrift must always om on endring any take specific priority i forskrift product over om personal property. tiltaksverdier protective og grenseverdier equipment, make for fysiske sure that og kjemiske the workplace faktorer is i ... / >>

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%. 3.1. Substances Information not relevant 3.2. Mixtures