Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
14808-60-7
Name of the chemical
Silica, crystalline
Concentration
N/A
EC/CAS
26447-40-5
Name of the chemical
Methylenediphenyl diisocyanate (see also specific isomers)
Concentration
N/A
General Information
Revision date
2015-06-22
Product name
TNEME-ZINC REDDISH GRAY
Product Synonyms
SERIES 90-97 PART A
Emergency telephone
800-535-5053 (Infotrac
Icons in SDS
Company Information
company name
Tnemec Company, Inc.
GHS Information
Signal word
Danger
Section 2
2.1 Classification of the substance or mixture
OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Inhalation (Vapors) Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Respiratory sensitization Category 1 Skin sensitization Category 1 Carcinogenicity Category 1A Specific target organ toxicity (single exposure) Category 1 Specific target organ toxicity (repeated exposure) Category 1 Aspiration toxicity Category 1 Flammable Liquids Category 2
2.2 Label elements
EMERGENCY OVERVIEW Danger
Hazard statements
Harmful if inhaled Causes skin irritation Causes serious eye damage May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause an allergic skin reaction May cause cancer Causes damage to organs Causes damage to organs through prolonged or repeated exposure May be fatal if swallowed and enters airways Highly flammable liquid and vapor Appearance opaque Physical state liquid Odor aromatic
Prevention
Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Use only outdoors or in a well-ventilated area Wash face, hands and any exposed skin thoroughly after handling In case of inadequate ventilation wear respiratory protection Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Do not breathe dust/fume/gas/mist/vapors/spray Do not eat, drink or smoke when using this product Keep away from heat/sparks/open flames/hot surfaces. — No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/mixing/equipment Use only non-sparking tools Take precautionary measures against static discharge
Response
IF exposed: Call a POISON CENTER or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician If skin irritation or rash occurs: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting In case of fire: Use CO2, dry chemical, or foam for extinction
Storage
Store locked up Store in a well-ventilated place. Keep cool Keep away from children
Disposal
Dispose of contents/container to an approved waste disposal plant
Further information
Toxic to aquatic life with long lasting effects Cancer hazard. Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure). Respirable crystalline silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs Acute Toxicity 4.65729 % of the mixture consists of ingredient(s) of unknown toxicity.