Note: Ingredients listed on restricted chemical lists
EC/CAS
215-222-5/1314-13-2
Name of the chemical
Zinc oxide; C.I. 77947
Concentration
≥75
General Information
Version
1.1
Revision date
2026-05-12
Product name
TIP TOP PRIMER HG 21
Manufacturer Name
TIP TOP Oberflaechenschutz Elbe GmbH
Emergency telephone
+49 (0) 6132 - 84463
Icons in SDS
Company Information
company name
TIP TOP Oberflaechenschutz Elbe GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
sds@gbk-ingelheim.de
GHS Information
Signal word
(GB CLP
Hazard Codes
Hazard statements (CLP)
H226, H304, H312, H312+H332, H315, H317, H319, H332, H335, H373, H411
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Classification of the substance or mixture Classification according to GB CLP (SI 2019:720 as amended) Flammable liquids, Category 3 H226 Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhalation:dust,mist) Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Skin sensitisation, Category 1 H317 Specific target organ toxicity – Single exposure, Category 3, Respiratory H335 tract irritation Specific target organ toxicity – Repeated exposure, Category 2 H373 Aspiration hazard, Category 1 H304 Hazardous to the aquatic environment – Chronic Hazard, Category 2 H411 Full text of H- and EUH-statements: see section 16
Adverse physicochemical, human health and environmental effects
Flammable liquid and vapour. May be fatal if swallowed and enters airways. Harmful in contact with skin or if inhaled. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects
2.2 Label elements
Labelling according to GB CLP (SI 2019:720 as amended)
Hazard pictograms
(GB CLP) GHS02 GHS07 GHS08 GHS09
Signal word
(GB CLP) : Danger
Contains
p-benzoquinone dioxime; 1,1'-(1,3-phenylene)bis-1H-pyrrole-2,5-dione; Reaction mass of ethylbenzene and m-xylene and p-xylene
Hazard statements
(GB CLP) : H226 - Flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H312+H332 - Harmful in contact with skin or if inhaled. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H373 - May cause damage to organs through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects.
Precautionary statements
(GB CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER, a doctor. P331 - Do NOT induce vomiting. P302+P352 - IF ON SKIN: Wash with plenty of water. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P273 - Avoid release to the environment.
Other hazards which do not result in classification
Vapours may form explosive mixture with air.
Results of PBT and vPvB assessment
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with UK REACH Annex XIII Results of Endocrine Disruptor assessment The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of UK REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in GB BPR and GB PPP at a concentration equal to or greater than 0,1 %
2.1 Classification of the substance or mixture
Classification according to GB CLP (SI 2019:720 as amended) Flammable liquids, Category 3 H226 Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhalation:dust,mist) Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Skin sensitisation, Category 1 H317 Specific target organ toxicity – Single exposure, Category 3, Respiratory H335 tract irritation Specific target organ toxicity – Repeated exposure, Category 2 H373 Aspiration hazard, Category 1 H304 Hazardous to the aquatic environment – Chronic Hazard, Category 2 H411 Full text of H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Flammable liquid and vapour. May be fatal if swallowed and enters airways. Harmful in contact with skin or if inhaled. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects.