Tigris Flumioxazin 51WDG

Hazard statements (CLP)

H361, H410

Code

Statements

H361

Suspected of damaging fertility or the unborn child

SECTION 2: Hazards identification

WARNING Suspected of damaging fertility or the unborn child (H361) Very toxic to aquatic life with long lasting effects (H410)

Health hazards

Category Other Hazards Category Reproductive toxicity 2 Hazardous to the aquatic environment, 1 long-term Hazardous to the aquatic environment, acute 1 HAZARDS NOT REQUIRING CLASSIFICATION Do not mix or allow this product to come in contact with an oxidizing agent such as potassium permanganate. Hazardous chemical reaction may occur.

Precautionary statements

Obtain special instructions before use. (P201) Do not handle until all safety precautions have been read and understood. (P202) Wear protective clothing including: long-sleeved shirt and long pants, chemical-resistant gloves made of any waterproof material, shoes and socks. (P280) Avoid release to the environment in a manner not in accordance with the product label. (P273) IF exposed or concerned: Get medical advice/attention. (P308+P313) Collect spillage. (P391) Store locked up. (P405) Dispose of contents / container in accordance with local regulations. Refer to the product label for specific disposal instructions. (P501) Manufactured for: Tigris, LLC P.O. Box 250 10025 Hwy. 264 Alternate Middlesex, NC 27557 Have the product container or label with you when calling a poison control center or doctor or going for treatment. You may also contact CHEMTREC at 1-800-424-9300 for emergency medical information. 5. FIREFIGHTING MEASURES Flash Point (PMCC): N/A Flammable Limits (LFL-UFL): Not Determined Fire and Explosion Hazards: None known. Extinguishing Medium: Foam, fog, CO2, or dry chemical. Fire Fighting Equipment: Firefighters should be equipped with self-contained positive pressure breathing apparatus and full bunker gear. Fire Fighting Instructions: Evacuate area of all unnecessary personnel and fight fire from a safe distance upwind. Contain contaminated water / firefighting water; do not allow to enter drains or waterways. Foam or dry chemical fire extinguishing systems are preferred to prevent environmental damage from excessive water runoff. Hazardous Decomposition Products: Normal combustion forms carbon dioxide, water vapor and may produce: nitrogen and fluorine compounds. Incomplete combustion can product carbon monoxide.

NFPA Ratings

Health – 1 / Flammability – 1 / Reactivity - 0 6. ACCIDENTAL RELEASE MEASURES Clean up spills immediately observing the precautions in Section 8 of this SDS. Isolate the hazard area and keep unnecessary and unprotected personnel from entering. Spill cleanup: Prevent material from further release into soil, surface water and ground water. Vacuum or sweep up material and place in an appropriate container for disposal. Wash area with soap and water. Pick up wash liquid with suitable absorbent material such as clay, sand, or earth and place in container for disposal. 1 7. HANDLING AND STORAGE Handling: KEEP OUT OF REACH OF CHILDREN AND ANIMALS. Avoid breathing dust and spray mist. Avoid contact with skin, eyes or clothing.

Storage

Keep pesticide in original container. Store in a cool, dry, secure place. Do not put formulation or dilute spray solution into food or drink containers. Do not contaminate food or feedstuffs. Do not store or transport near feed or food. Not for use or storage in or around the home. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash station and a safety shower. Protective Clothing: Applicators and other handlers must wear long-sleeved shirt and long pants, chemical-resistant gloves made of any waterproof material (such as polyethylene or polyvinyl chloride), and shoes plus socks. General: Remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Remove PPE immediately after handling this product. Wash the outside of gloves before removing. As soon as possible, wash thoroughly and change into clean clothing. Follow manufacturer’s instructions for cleaning/maintaining PPE. If no such instructions for washables exist, use detergent and hot water. Keep and wash PPE separately from other laundry. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Light yellow granule Odor: Odorless Flash Point: N/A pH: 6-7 Density: 0.6 g/mL (tap) Solubility: Soluble in water 10. STABILITY AND REACTIVITY CONDITIONS TO AVOID: Extreme temperatures and direct sunlight. CHEMICAL STABILITY: Stable under all normal use and storage conditions. HAZARDOUS DECOMPOSITION PRODUCTS: None when stored and handled as prescribed. Thermal decomposition may release oxides of carbon and nitrogen. INCOMPATIBILITY WITH OTHER MATERIALS: Strong oxidizing agents (such as chlorates, nitrates, peroxides, etc.) POLYMERIZATION: Will not occur. Manufactured for: Tigris, LLC P.O. Box 250 10025 Hwy. 264 Alternate Middlesex, NC 27557 The following is for a similar formulation: ORAL TOXICITY (rat LD50): > 5,000 mg/kg DERMAL TOXICITY (rat LD50): > 2,000 mg/kg INHALATION TOXICITY (rat LC50): > 0.969 mg/L (4-hour) EYE IRRITATION: Minor irritation SKIN IRRITATION: Minor irritation SKIN SENSITIZATION: Not a contact sensitizer. CARCINOGENICITY: IARC: Not listed US NTP: Not listed ACGIH: Not listed MUTAGENIC TOXICITY: No evidence of mutagenic effects during in vivo and in vitro assays. REPRODUCTIVE TOXICITY: Reproductive toxicity was observed in F1 males, P1 females and F1 females at 300 ppm Flumioxazin Technical, the highest dose tested and a dose that also produced signs of systemic toxicity. Toxicity was also observed in the F1 and F2 offspring at doses of 200 ppm and greater. 12. ECOLOGICAL INFORMATION This product is toxic to non-target plants and aquatic invertebrates. This pesticide is toxic to plants and must be used strictly in accordance with the drift and run-off precautions on the label in order to minimize off-site exposures. The following is for the active ingredient, flumioxazin: AQUATIC TOXICITY Rainbow trout (96-hr LC50): 2.3 ppm Rainbow trout (NOAEC): 0.0077 ppm Daphnia (96-hr LC50): 5.5 ppm Daphnia (NAOEC): 0.028 ppm Green algae (EC50): 0.00102 ppm TERRESTRIAL TOXICITY Bobwhite quail (feeding): > 2250 mg/kg Mallard duck (NOAEC): 250 mg/kg OTHER TOXICITY Honey bee (contact, 48-hr): > 105μg/bee 13. DISPOSAL CONSIDERATIONS PESTICIDE DISPOSAL: Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility. CONTAINER DISPOSAL: Non-refillable container. Do not reuse this container. Refer to the product label for specific container disposal instructions. 2 14. TRANSPORT INFORMATION US DOT (shipments by land) Not regulated by DOT. IMDG / IATA (shipments by vessel or air) Containers < 11 lbs. (5 kg) Not regulated. Containers > 11 lbs. (5 kg) UN3077, Environmentally Hazardous Substance, Solid, N.O.S. (flumioxazin), 9, PG III, Marine Pollutant 15. REGULATORY INFORMATION FIFRA – This chemical is a pesticide product registered by the