Tolylene 2,4-diisocyanate

Hazard statements (CLP)

H315, H317, H319, H330, H334, H335, H351, H412

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Physical State

Appearance/Odor

Liquid Light yellow pungent Emergency Overview Causes skin irritation. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of causing cancer. May cause respiratory irritation. Causes serious eye irritation. Harmful to aquatic life with long lasting effects. Fatal if inhaled. Moisture sensitive. Lachrymator (substance which increases the flow of tears). Classification of the substance or mixture Acute Inhalation Toxicity - Vapors Category 1 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Carcinogenicity Category 2 Specific target organ toxicity - (single exposure) Category 3 Chronic aquatic toxicity Category 3

Signal word

Danger

Hazard statements

H315 - Causes skin irritation H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H351 - Suspected of causing cancer H335 - May cause respiratory irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H412 - Harmful to aquatic life with long lasting effects H330 - Fatal if inhaled

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves/protective clothing/eye protection/face protection P284 - In case of inadequate ventilation wear respiratory protection

Response

P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P362 + P364 - Take off contaminated clothing and wash it before reuse

Storage

P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other physicochemical hazards

None identified.

Health hazards

Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of causing cancer. May cause respiratory irritation. May cause an allergic skin reaction. Causes serious eye irritation. Fatal if inhaled. Lachrymator (substance which increases the flow of tears).

Environmental hazards

Harmful to aquatic life with long lasting effects. Will likely be mobile in the environment due to its water solubility. The product is water soluble, and may spread in water systems.

2.3 Other hazards

Lachrymator (substance which increases the flow of tears) Toxic to terrestrial vertebrates. This product does not contain any known or suspected endocrine disruptors.

2.1 Classification of the substance or mixture

Acute Inhalation Toxicity - Vapors Category 1 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Carcinogenicity Category 2 Specific target organ toxicity - (single exposure) Category 3 Chronic aquatic toxicity