Titanium(IV) chloride, 1M solution in dichloromethane

Hazard statements (CLP)

H302, H314, H330, H336, H351

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

Classified as hazardous in accordance with the criteria of EPA New Zealand Classification under Work Safe New Zealand Classified as hazardous in accordance with the criteria of EPA New Zealand GHS Classification

Physical hazards

Based on available data, the classification criteria are not met

Health hazards

Acute Oral Toxicity Category 4 Acute Inhalation Toxicity - Vapors Category 2 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Carcinogenicity Category 2 Specific target organ toxicity - (single exposure) Category 3

Environmental hazards

Based on available data, the classification criteria are not met ______________________________________________________________________________________________

Signal word

Danger

Hazard statements

H314 - Causes severe skin burns and eye damage H330 - Fatal if inhaled H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer H302 - Harmful if swallowed

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P284 - Wear respiratory protection P280 - Wear protective gloves/protective clothing/eye protection/face protection

Response

P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P363 - Wash contaminated clothing before reuse

Storage

P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other hazards which do not result in classification

Toxic to terrestrial vertebrates Contains a known or suspected endocrine disruptor Contains a substance on the National Authorities Endocrine Disruptor Lists Reacts violently with water

2.1 Classification of the substance or mixture

Physical hazards Based on available data, the classification criteria are not met Health hazards Acute Oral Toxicity Category 4 Acute Inhalation Toxicity - Vapors Category 2 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Carcinogenicity Category 2 Specific target organ toxicity - (single exposure) Category 3 Environmental hazards Based on available data, the classification criteria are not met