Thermo

Signal word

» Waring

Hazard statements

+ Harmful if swallowed.

Prevention

Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling Respanse » IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth.

Storage

» Not applicable.

Disposal

« Dispose of contents and container in accordance with all local. regional, national and international regulations.

2.3 Other hazards

» None known HAQNS Dy 182613 verwen 0S tt Mixture Other means of » Not available. identification CAS numberother identifiers CAS number » Not applicable Ingredient name “hn CAS number sodium azide 220.1: 60.25 20628-22-8 Any concentration shown as a range is to protect confidentiality or is due to batch variation There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Eye contact » Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation accurs. Inhalation « Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration oF oxygen by trained personnel. It may be dangeraus to the person providing aid to give mouth-to-mouth resuscitation. Get medical altention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband Skin contact ; Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion ; Wash out mouth with water, Remove dentures if any. Remove victim ta fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious. give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do nat induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Gel medical altention, If necessary, call a poison center or physician. Never give anything by mouth fo an unconscious person. IFunconscious, place in recovery position and get medical attention immediately Maintain an open ainway. Loosen tight clothing such as a collar, tie, belt or waistband Most important symptomsieffects, acute and delayed

Potential Acute Health Effects

Eye contact No known significant effects or critical hazards. Inhalation No known significant effects or critical hazards. Skin contact No known significant effects or critical hazards. Ingestion + Harmful if swallowed Ovor-expesure signs:symptoms Eye contact No specitic data Inhalation No specific data Skin contact No specific data Ingestion No specific data, Indication of immediate medical attention and special treatment needed ifnecessary TEEN fh 152013 Verse 105 2 Antibedy Preparations Section 4. First aid measures Notes to physician » Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments No specific treatment Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mauth-to-mouth resuscitation See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing » Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing — > None known, media Specific hazards arising Ina fire or if heated. a pressure increase will occur and the container may burst. fram the chemical Hazardaus thermal » No specific data decomposition products Special protective actions. Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective . Fire-fighters should wear appropriate protective equipment and self-contained breathing oquipment for fire-fighters apparatus (SCBA) with a full face-prece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emersency procedures For non-emergency Naaction shall be taken involving any personal risk or without suitable training personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate Put on appropriate personal protective equipment. Foremergency responders + lf specialised clothing is required to deal with the spillage. take note of any information in Section 8 on suitable and unsuitable materials. See algo the information in "For non- emergency personnel”. Environmental precautions; Avoid dispersal of spilled material and runoff and contact with soll. walenvays, drains and sewers, Inform the relevant authorities if the product has caused environmental pollution {sewers, waterways. sail or air) Methods and materials for containment and cleaning up Small spill «Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Akernatively. or if water-insoluble. absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill + Stop leak if without risk. Move containers from spill area. Approach release from upwind Prevent entry into sewers, water courses. basements or confined areas. \M'ash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13) Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 4 for emergency contact information and Section 13 for waste disposal HA2N3 1450613, Werwcn 103 att contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved altemative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Da not reuse container Ailvice on general . Eating, drinking and smoking shauld be prohibited in areas where this material is handled occupational hygient stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, ; Store in accordance with lacal regulations, Store in original container protected fram including any direct sunlight in a dry. cool and well-ventilated area, away from incompatible materials incompatibilitios (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination, Section 8. Exposure controls/personal protection Control paramaters Occupational exposure limits Ingredient name Exposure limits sodium azide ACGIH TLV (United States, 6/2013). Notes: las Hydrazoic acid vapor 20.11 ppm. (as ydrazoic acid vapor) Form las Hydrazoic acid vapor ACGIH TLV (United States, 6/2013). €:0.29 mgim*, (a8 Sodium azide} Form: a3 Sodium azide NIOSH REL (United States, 4/2013). Absorbed through skin. Notes: NAN3 CEIL: 0.3 mgin*. (NAN3) NIOSH REL (United States, 4/2013), Absorbed through skin. Notes: As HN3 CEIL 0.1 ppm. (as NS} Eye contact Na known significant effects or critical hazards. Inhalation Na known significant effects or critical hazards. Skin contact . No known significant effects or critical hazards. Ingestion » Harmful if swallowed, Symptoms related to the physical, chemical and toxicolodical characteristics Eye contact Na specific data Inhalation . No specific data Skin contact » No specific data Ingestion Na specific data Delayed and immed ecfiects and also chronic effects from short and long term exposure Short term expasure Potential immediate » Not available uffects Potential delayed effects » Not available Long term exposure Potential immediate » Not available uffects Potential delayed effects » Not available Potential chronic health effects Not available. General + No known significant ef fects or critical hazards Carcinogenicity » No known significant el fects or critical hazards. Mutagenicity » No known significant effects or critical hazards. Toratagenicity + No known significant el fects or critical hazards Developmental effects «No known significant ef fects or critical hazards Fertility effects » No known significant el fects or critical hazards. Numerical measures of toxicity Acute: toxicity estimates Not available.

Aspiration hazard

Nat available TYRa013, 152013 Verse 105 Sit Antibedy Preparations

TOXICOLOGICAL INFORMATION

Information on the likely ; Routes of entry anticipated: Oral, Dermal. Inhalation.

ECOLOGICAL INFORMATION

Toxicity Productingredient name — | Result Species Exposure sodium azide Acute EC50 0.348 mgil Fresh water Algae - Pseudokirchneriella 96 hours subcapitata Acute EC50 4.2 to 6.2 mgil Fresh water Daphnia - Daphnia pulex - Larvae |48 hours Acute LC50 9000 igi! Fresh water Crustaceans - Gammarus 48 hours lacustris Acute LG50 0.68 mg! Fresh water Fish - Lepomis macrochirus 96 hours Chronic NOEC 5600 gil Marine water | Algae - Macrocystis pyrifera 96 hours Persistence and degradability HAQNS Dy 1452613, i TH Not available Bioaccumulative potential Not available Mobility in sail Soiltwater partition » Not available. coefficient (Ke )

Other hazards

No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods «The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements, Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction, Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and Sewers. Section 14. Transport information DOT Classification IATA

UN Number

Not regulated UN proper shipping name Transport hazard class(tg) Packing group Environmental S No. No

Additional information

Special precautions for user Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the praduct know what to do in the event of an accident or spillage. Transport in bulk according: Not available. to Annex Il of MARPOL 7278 and the IBC Code fh 1/80018, 18/2013 wei 103 BAT | Antibedy Preparations Section 15. Regulatory information U.S, Federal regulations TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8h): All components are listed or exempted Clean Water Act (CWA) 311: disodium hydrogenorthophosphate Clean Air Act Section 112 Nat listed (hy Hazardous Air Pollutants (HAPS) Clean Air Act Section 602 Nat listed Class | Substances Clean Air Act Suction 602 » Not listed Class Il Substances DEA List| Chemicals » Natlisted (Precursor Chemicals DEA List Il Chemicals Nat listed (Essential Chemicals) SARA J027304