Thermo

Signal word

. Warming

Hazard statements

+ Harmful if swallowed,

Prevention

» Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling.

Response

» IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth

Storage

» Not applicable,

Disposal

» Dispose of contents and container in accordance with all local. regional, national and intemational regulations.

2.3 Other hazards

» None known T3123. Pa PAG2073, Yea LEP wit Mixture Other means of » Not available. identification CAS numberother identifiers CAS number » Not applicable Ingredient name “hn CAS number trometamal 3-5 7786-1 sodium azide 20.1: $0.25 26628-22.8 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8 Section 4. First aid measures Description of necessary first aid measures Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contactlenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation accurs. Inhalation . Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration oF oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire. symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact » Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious. give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous, Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low sa that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth fo an unconscious person. IFunconscious, place in recavery position and get medical attention immediately. Maintain an open ainvay. Loosen tight clothing such asa collar. tie, belt or waistband Most important symptoms‘effects, acute and delayed

Potential Acute Health Effects

Eye contact + No known significant effects or critical hazards. Inhalation Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Skin contact No known significant effects or critical hazards. Ingestien » Harmful if swallowed, OOF Dxpasure siqns:symptoms Eye contact No specific data Inhalation No specific data Skin contact No specific data Ingestion No specific data tGt2013 f FYING Versa 167 2 Section 4. First aid measures Indication of immediate medical attention and special treatment needed, if necessary Nates te physician » In case of inhalation of decomposition products in a fire. symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments . No specific treatment Protection of first-aiders Naaction shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing » Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing » None known media Specific hazards arising Ina fire or if heated. a pressure increase will occur and the container may burst from the chemical Hazardous thermal Decomposition products may include the follwing materials decomposition products carbon dioxide carbon monoxide nitrogen oxides Special protective actions . Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective . Fire-fighters should wear appropriate protective equipment and self-contained breathing oquipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure made. Section 6. Accidental release measures Personal precautions, protective equipment and emergency pracedures For non-emergency Naaction shall be taken involving any personal risk or without suitable training porsonnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders TF specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel”. Environmental precautions «Avoid dispersal of spilled material and runoff and contact with soil. waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways. sail or air). Methods anc materials for containment and cleanin up Small spill + Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble, Alternatively. or if water-insoluble. absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill © Stop leak if without risk. Move containers from spill area. Approach release from upwind, Prevent entry into sewers, water courses. basements or confined areas. \W'ash spillages into an effluent treatment plant or proceed a3 follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13) Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency THON PAG2073, vero ET att contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures ; Puton appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved altemative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container Advice on general » Eating, drinking and smoking should be prohibited in areas where this material is handled occupational hygiene stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures Conditions for safe storage, Do not store above the following temperature: -20°C (-4°F). Store in accordance with including any local regulations. Store in original container protected from direct sunlight in a dry, cool incampatibilities and well-ventilated area. away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits sodium azide ACGIH TLV (United States, 3/2012). Notes: las Hydrazoic acid vapor €:0.11 pom. (as Hydrazoic acid vapor) Form: las Hydrazoic acid vapor ACGIH TLV (United States, 3/2012). €:0.29 mgim’, (as Sodium azide} Form: as Sodium azide NIOSH REL (United States, 1/2013). Absorbed through skin. Notes: NAN3 CEIL: 0.3 mg/m". (NAN3) NIOSH REL (United States, 1/2013). Absorbed through skin. Notes: As HN3 CEIL: 0.1 ppm. (a3 HN3)

2.1 Classification of the substance or mixture

tGt2013 f Taye youn (Gh BYE mGluR § + Immediate (acute) health hazard

TOXICOLOGICAL INFORMATION

Productingredientname = JOSHA |IARC NTP Numerical measures of toxicity Acute toxicity estimates trometamel None Not available Reproductive toxicity Not available. Teraloqenicity Not available.

ECOLOGICAL INFORMATION

Specific target organ toxicity (single exposure) Toxicity Name Catagory Route of Target organs Productingrediont name =| Result Spocies Exposure oxposure sodium azide Acute EC56 0.348 mail Fresh water Algae - Pseudokirchneriella 96 hours trometamol Category 3 Nat applicable. / Respiratory tract subcapitata initation Acute EC50 4.2 to 6.2 mg/l Fresh water |Daphnia - Daphnia pulex - Larvae |48 hours Acute LC50 9000 pig'l Fresh water Crustaceans - Gammarus 48 hours Specific taruet organ toxicity repeated exposure lacustris Not available. \\cute LC50 0.68 mg!l Fresh water Fish - Lepomis macrachirus 96 hours Chronic NOEC 5600 ug/l Marine water

Aspiration hazard

| Algae - Macrocystis pyrifera 96 hours Not available. Persistence and degradability Not available Information on the likely ; Routes of entry anticipated: Oral, Dermal. Inhalation.

Principle Routes of Exposure

Bisaccumulative potential Potontial acute health offocts Not available Eye contact Na known significant effects or critical hazards. Inhalation « Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Mobility in sei Skin contact » No known significant effects or critical hazards, Soiltwater partition » Not available. Ingestion «Harmful if swallowed. coefficient (K. ) Symptoms related to the physical, chemical anc toxicological characteristics

Other hazards

No known significant effects or critical hazards. Eye contact Na specific data, Section 13. Disposal considerations Inhalation » No specific data Skin contact Disposal methods Na specific data » The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the Ingestion Na specific data requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a Delayed and immediate offects and also chronic effects from short and long term exposure licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction, Short term exposure Waste packaging should be recycled. Incineration or landfill should only be considered Potential immediate ; Not available. when recycling is not feasible. This material and its container must be disposed of in a offects safe way. Care should be taken when handling emptied containers thal have not been Potential delayed effects: Not available. Cleaned or rinsed out. Empty containers or liners may retain some product residues Long term exposure Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and SEWETS. Potential immediate i Not available. uffects Section 14. Transport information Potential delayed effects: Not available. Potential chronic health effects DOT Classification IATA Not available.

UN Number

Not regulated. General + No known significant fl e fects or critical hazards: UN proper Carcinogenicity + No known significant fi e fects or critical hazards: shipping name Mutagenicity + Na known signi fi icant ef fects or critical hazards. Teratagen ivity ; No known significant fi ef fects or critical hazards. Transport hazard class(tg) Developmental effects » No known significant fl effects or critical hazards. Fortility effects » No known significant fl effects or critical hazards. THON PAG2073, eral LET Tt My 1gigt0013. 7790/0513 festa LOT BY Section 14. Transport information Packing group Environmental Fay |N No

Additional information

Special precautions for user > Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transportin bulk according + Not available. to Annox Il of MARPOL THT and the IBC Core Section 15. Regulatory information U.S, Federal regulations . TSCA 4(a} proposed test rules: glycine TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventary (TSCA 8b): All components are listed or exempted Clean Air Act Section 112 > Notlisted (hi Hazardous Air Pollutants (HAPS) Clean Air Act Section 602: Notlisted Class | Substances Clean Air Act Section 602 + Not listed Class Il Substances DEA List | Chemicals » Not listed (Precursor Chemicals) DEA List Il Chemicals + Not listed (Essential Chemicals) SARA 302/244 Composition’ nformation on ingredients SARA 302 TPO SARA 304 RO Name " EHS |ilbsi igallons) _|ilbs) gallons} sodium azide 0-01 Yes. 500 - 1000 SARA 304 RO + 1000000 Ibs ' 454000 kg SARA S12