Note: Ingredients listed on restricted chemical lists
General Information
Version
11
Revision date
2026-07-07
Product name
Sodium azide
Product Synonyms
Sodium salt of hydrazoic acid; Smite
CAS No.
26628-22-8
supplier name
Fisher Scientific UK
Emergency telephone
(800) 424-9300, 001-703-527-3887
Icons in SDS
Company Information
company name
Fisher Scientific UK
e-mail address of the competent person responsible for the Safety Data Sheet
begel.sdsdesk@thermofisher.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H300+H310+H330, H373, H410
Hazard statements
Code
Statements
H300+H310+H330
Fatal if swallowed, in contact with skin or if inhaled
Section 2
SECTION 2: Hazards identification
Physical State
Appearance/Odor
Powder Solid White Odorless Emergency Overview Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. May cause damage to organs through prolonged or repeated exposure. Contact with acids liberates very toxic gas. Very toxic to aquatic life with long lasting effects. Classification of the substance or mixture Acute Oral Toxicity Category 2 Acute Dermal Toxicity Category 1 Acute Inhalation Toxicity - Dusts and Mists Category 2 Specific target organ toxicity - (repeated exposure) Category 2 Acute aquatic toxicity Category 1 Chronic aquatic toxicity Category 1 Label Elements
Signal word
Danger Hazard Statements H300 + H310 + H330 - Fatal if swallowed, in contact with skin or if inhaled H373 - May cause damage to organs through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects
Prevention
P262 - Do not get in eyes, on skin, or on clothing P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection P284 - Wear respiratory protection
Response
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P310 - Immediately call a POISON CENTER or doctor P330 - Rinse mouth P361 + P364 - Take off immediately all contaminated clothing and wash it before reuse P363 - Wash contaminated clothing before reuse
Storage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up
Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant
Other physicochemical hazards
Contact with acids liberates very toxic gas.
Health hazards
Very toxic if swallowed. Fatal in contact with skin. Fatal if inhaled. May cause damage to organs through prolonged or repeated exposure.
Environmental hazards
Very toxic to aquatic life with long lasting effects. Will likely be mobile in the environment due to its water solubility. The product is water soluble, and may spread in water systems.
2.3 Other hazards
Toxic to terrestrial vertebrates. This product does not contain any known or suspected endocrine disruptors.
2.1 Classification of the substance or mixture
Acute Oral Toxicity Category 2 Acute Dermal Toxicity Category 1 Acute Inhalation Toxicity - Dusts and Mists Category 2 Specific target organ toxicity - (repeated exposure) Category 2 Acute aquatic toxicity Category 1 Chronic aquatic toxicity