Piperazine hydrate

Hazard statements (CLP)

H314, H317, H334, H361, H412

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

Classified as hazardous in accordance with the criteria of EPA New Zealand Classification under Work Safe New Zealand Classified as hazardous in accordance with the criteria of EPA New Zealand HSNO Approval Number HSR002491 GHS Classification

Physical hazards

Based on available data, the classification criteria are not met

Health hazards

Skin Corrosion/Irritation B Category 1 Serious Eye Damage/Eye Irritation Category 1 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Reproductive Toxicity Category 2

Environmental hazards

Chronic aquatic toxicity Category 3 ______________________________________________________________________________________________

Signal word

Danger

Hazard statements

H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction H361 - Suspected of damaging fertility or the unborn child H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H412 - Harmful to aquatic life with long lasting effects

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves P284 - In case of inadequate ventilation wear respiratory protection

Response

P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P363 - Wash contaminated clothing before reuse

Storage

P403 + P233 - Store in a well-ventilated place. Keep container tightly closed

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

2.1 Classification of the substance or mixture

Physical hazards Based on available data, the classification criteria are not met Health hazards Skin Corrosion/Irritation B Category 1 Serious Eye Damage/Eye Irritation Category 1 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Reproductive Toxicity Category 2 Environmental hazards Chronic aquatic toxicity Category 3