Piperazine

Hazard statements (CLP)

H228, H314, H317, H334, H361

Code

Statements

H228

Flammable solid

SECTION 2: Hazards identification

Physical State

Appearance/Odor

Solid Off-white Ammonia-like Emergency Overview Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of damaging fertility or the unborn child. Flammable solid. Sensitivity to light. Hygroscopic. Classification of the substance or mixture Flammable solids Category 1 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Reproductive Toxicity Category 2 Label Elements

Signal word

Danger Hazard Statements H228 - Flammable solid H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H361 - Suspected of damaging fertility or the unborn child

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P240 - Ground and bond container and receiving equipment P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves P284 - In case of inadequate ventilation wear respiratory protection

Response

P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P362 + P364 - Take off contaminated clothing and wash it before reuse

Storage

P403 - Store in a well-ventilated place

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other physicochemical hazards

Combustible material. Hygroscopic.

Health hazards

Corrosive. Causes skin and eye burns. May cause an allergic skin reaction. Causes serious eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of damaging fertility or the unborn child.

Environmental hazards

Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Will likely be mobile in the environment due to its water solubility. The product is water soluble, and may spread in water systems. Toxic to terrestrial vertebrates. This product does not contain any known or suspected endocrine disruptors.

2.1 Classification of the substance or mixture

Flammable solids. Category 1 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Reproductive Toxicity