Piperazine, anhydrous

Hazard statements (CLP)

H228, H290, H302, H314, H317, H334, H361, H413

Code

Statements

H228

Flammable solid

SECTION 2: Hazards identification

Classified as hazardous in accordance with the criteria of EPA New Zealand Classification under Work Safe New Zealand Classified as hazardous in accordance with the criteria of EPA New Zealand GHS Classification

Physical hazards

Flammable solids Category 1 Substances/mixtures corrosive to metal Category 1

Health hazards

Acute Oral Toxicity Category 4 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Reproductive Toxicity Category 2

Environmental hazards

Chronic aquatic toxicity Category 4 ______________________________________________________________________________________________

Signal word

Danger

Hazard statements

H228 - Flammable solid H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H361 - Suspected of damaging fertility or the unborn child H290 - May be corrosive to metals H302 - Harmful if swallowed H413 - May cause long lasting harmful effects to aquatic life

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P240 - Ground and bond container and receiving equipment P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves P284 - In case of inadequate ventilation wear respiratory protection

Response

P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P363 - Wash contaminated clothing before reuse P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish

Storage

P403 - Store in a well-ventilated place

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other hazards which do not result in classification

Toxic to terrestrial vertebrates

2.1 Classification of the substance or mixture

Physical hazards Flammable solids Category 1 Substances/mixtures corrosive to metal Category 1 Health hazards Acute Oral Toxicity Category 4 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Reproductive Toxicity Category 2 Environmental hazards Chronic aquatic toxicity Category 4