OPD (o-phenylenediamine dihydrochloride)

Hazard statements (CLP)

H301, H312, H317, H319, H332, H341, H351, H373, H410

Code

Statements

H301

Toxic if swallowed

H312

Harmful in contact with skin

H317

May cause an allergic skin reaction

H319

Causes serious eye irritation

H332

Harmful if inhaled

H341

Suspected of causing genetic defects

H351

Suspected of causing cancer

H373

May cause damage to organs through prolonged or repeated exposure

H410

Very toxic to aquatic life with long lasting effects

SECTION 2: Hazards identification

GHS Classification

Signal word

DANGER Hazard pictograms

Health hazards

Acute oral toxicity Category 3 Acute dermal toxicity Category 4 Acute inhalation toxicity - dust/mist Category 4 Serious eye damage/eye irritation Category 2 Skin sensitization Category 1 Specific target organ toxicity (STOT) – repeated exposure Category 2 Carcinogenicity Category 2 Germ cell mutagenicity Mutagenic category 2

Physical hazards

Not Hazardous

Environmental hazards

Acute aquatic hazard Category 1 Chronic aquatic hazard Category 1 Hazard Statements H301 - Toxic if swallowed H312 - Harmful in contact with skin H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H332 - Harmful if inhaled H341 - Suspected of causing genetic defects H351 - Suspected of causing cancer H373 - May cause damage to organs through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P264 - Wash hands thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing should not be allowed out of the workplace P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection

Response

P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P308 + P313 - IF exposed or concerned: Get medical advice/attention P391 - Collect spillage P330 - Rinse mouth P312 - Call a POISON CENTER or doctor/physician if you feel unwell

Storage

Not Applicable

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

2.3 Other hazards

Not Applicable HMIS Health 4 * Chronic Hazard Flammability 0 Reactivity 0

2.1 Classification of the substance or mixture

Signal Word DANGER Hazard pictograms Health hazards Acute oral toxicity Category 3 Acute dermal toxicity Category 4 Acute inhalation toxicity - dust/mist Category 4 Serious eye damage/eye irritation Category 2 Skin sensitization Category 1 Specific target organ toxicity (STOT) – repeated exposure Category 2 Carcinogenicity Category 2 Germ cell mutagenicity Mutagenic category 2 Physical hazards Not Hazardous Environmental hazards Acute aquatic hazard Category 1 Chronic aquatic hazard Category 1 Hazard Statements H301 - Toxic if swallowed H312 - Harmful in contact with skin H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H332 - Harmful if inhaled H341 - Suspected of causing genetic defects H351 - Suspected of causing cancer H373 - May cause damage to organs through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects