Note: Ingredients listed on restricted chemical lists
EC/CAS
75-56-9
Name of the chemical
Methyloxirane (Propylene oxide)
Concentration
<=0.1
General Information
Revision date
2023-03-10
Product name
Allyl bromide, stabilized
Product Synonyms
3-Bromopropene
CAS No.
106-95-6
Emergency telephone
+64 9 980 6780
Icons in SDS
Company Information
company name
Thermo Fisher Scientific New Zealand Ltd
e-mail address of the competent person responsible for the Safety Data Sheet
ANZinfo@thermofisher.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H224, H301+H331, H314, H340, H350, H361, H410
Hazard statements
Code
Statements
H224
Extremely flammable liquid and vapour
H301+H331
Toxic if swallowed or if inhaled
H314
Causes severe skin burns and eye damage.
H340
May cause genetic defects
H350
May cause cancer
H361
Suspected of damaging fertility or the unborn child
H410
Very toxic to aquatic life with long lasting effects
Section 2
SECTION 2: Hazards identification
GHS Classification Classification under Work Safe New Zealand Classified as hazardous in accordance with the criteria of EPA New Zealand HSNO Approval Number HSR004256
Physical hazards
Flammable liquids Category 1
Health hazards
Acute Oral Toxicity Category 3 Acute Inhalation Toxicity - Vapors Category 3 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1B Reproductive Toxicity Category 2
Environmental hazards
Acute aquatic toxicity Category 1 Chronic aquatic toxicity Category 1
Signal word
Danger
Hazard statements
H314 - Causes severe skin burns and eye damage H340 - May cause genetic defects H350 - May cause cancer H224 - Extremely flammable liquid and vapor H361 - Suspected of damaging fertility or the unborn child H410 - Very toxic to aquatic life with long lasting effects H301 + H331 - Toxic if swallowed or if inhaled
Prevention
P201 - Obtain special instructions before use P271 - Use only outdoors or in a well-ventilated area P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P233 - Keep container tightly closed P240 - Ground and bond container and receiving equipment P241 - Use explosion-proof electrical/ ventilating/ lighting equipment P242 - Use non-sparking tools P243 - Take action to prevent static discharges P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear protective gloves/protective clothing/eye protection/face protection P273 - Avoid release to the environment
Response
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P330 - Rinse mouth P331 - Do NOT induce vomiting P363 - Wash contaminated clothing before reuse P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P391 - Collect spillage
Storage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up
Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant
Other hazards which do not result in classification
Lachrymator (substance which increases the flow of tears) Stench Toxic to terrestrial vertebrates