Methylmagnesium iodide, 3M solution in diethyl ether

Hazard statements (CLP)

H224, H260, H314, H318, H336

Code

Statements

H224

Extremely flammable liquid and vapour

SECTION 2: Hazards identification

Classification of the substance or mixture

Physical hazards

Flammable liquids Category 1 (H224) Substances/mixtures which, in contact with water, emit flammable gases Category 1 (H260)

Health hazards

Skin Corrosion/Irritation Category 1 (H314) B Serious Eye Damage/Eye Irritation Category 1 (H318) Specific target organ toxicity - (single exposure) Category 3 (H336)

Environmental hazards

Based on available data, the classification criteria are not met

Signal word

Danger

Hazard statements

H224 - Extremely flammable liquid and vapor H260 - In contact with water releases flammable gases which may ignite spontaneously H314 - Causes severe skin burns and eye damage H336 - May cause drowsiness or dizziness

Prevention

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P240 - Ground and bond container and receiving equipment P242 - Use non-sparking tools P243 - Take action to prevent static discharges P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection

Response

P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P363 - Wash contaminated clothing before reuse P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish

Storage

P403 + P233 - Store in a well-ventilated place. Keep container tightly closed

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

2.3 Other hazards

EUH014 - Reacts violently with water EUH019 - May form explosive peroxides EUH066 - Repeated exposure may cause skin dryness or cracking Toxic to terrestrial vertebrates This product does not contain any known or suspected endocrine disruptors

2.1 Classification of the substance or mixture

Physical hazards Flammable liquids Category 1 (H224) Substances/mixtures which, in contact with water, emit flammable gases Category 1 (H260) Health hazards Skin Corrosion/Irritation Category 1 (H314) B Serious Eye Damage/Eye Irritation Category 1 (H318) Specific target organ toxicity - (single exposure) Category 3 (H336) Environmental hazards Based on available data, the classification criteria are not met