Lithium diisopropylamide, 2M solution in THF/n-heptane/ethylbenzene

Thermo Fisher Scientific

Revision date : 2024-02-09

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GHS02 GHS05 GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 5
Environmental risk rating 4

Note: Ingredients listed on restricted chemical lists

EC/CAS

203-558-5/108-18-9

Name of the chemical

N,N-Di-i-propylamine (2-Propanamine, N-(1-methylethyl)-)

Concentration

3-5

Listed in

EC/CAS

265-151-9/64742-49-0

Name of the chemical

Naphtha (petroleum), hydrotreated light

Concentration

30-50

EC/CAS

203-726-8/109-99-9

Name of the chemical

Tetrahydrofuran (618/2012)

Concentration

20-25

EC/CAS

202-849-4/100-41-4

Name of the chemical

Ethylbenzene

Concentration

10-20

Listed in

General Information

Version

13

Revision date

2024-02-09

Product name

Lithium diisopropylamide, 2M solution in THF/n-heptane/ethylbenzene

Product Synonyms

LDA.THF complex

Emergency telephone

US 001-201-796-7100 / Europe +32 14 57 52 99

Icons in SDS

GHS02 GHS05 GHS07 GHS08 GHS09

Company Information

company name

Thermo Fisher Scientific

e-mail address of the competent person responsible for the Safety Data Sheet

infoch@thermofisher.com, begel.sdsdesk@thermofisher.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H302, H304, H314, H318, H335, H336, H351, H373, H411

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

______________________________________________________________________________________________ ACR26883 Page 1 / 19

Physical hazards

Flammable liquids Category 2 (H225)

Health hazards

Aspiration Toxicity Category 1 (H304) Acute oral toxicity Category 4 (H302) Skin Corrosion/Irritation Category 1 B (H314) Serious Eye Damage/Eye Irritation Category 1 (H318) Carcinogenicity Category 2 (H351) Specific target organ toxicity - (single exposure) Category 3 (H335) (H336) Specific target organ toxicity - (repeated exposure) Category 2 (H373)

Environmental hazards

Chronic aquatic toxicity Category 2 (H411)

Hazard statements

see section 16 H225 - Highly flammable liquid and vapor H302 - Harmful if swallowed H304 - May be fatal if swallowed and enters airways H314 - Causes severe skin burns and eye damage H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer H373 - May cause damage to organs through prolonged or repeated exposure H411 - Toxic to aquatic life with long lasting effects EUH014 - Reacts violently with water EUH019 - May form explosive peroxides

Signal word

Danger

Precautionary statements

P280 - Wear protective gloves/protective clothing/eye protection/face protection P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking

2.3 Other hazards

Decomposes in contact with water Toxic to terrestrial vertebrates This product does not contain any known or suspected endocrine disruptors

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