Lithium bis(trimethylsilyl)amide

Thermo Fisher Scientific Fisher Scientific (M) Sdn Bhd

Revision date : 2026-07-15

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GHS02 GHS05
Health risk rating 3
Safety risk rating 3
Environmental risk rating 1

General Information

Version

5

Revision date

2026-07-15

Product name

Lithium bis(trimethylsilyl)amide

Product Synonyms

Lithium hexamethyldisilazide; 1,1,1,3,3,3-Hexamethyldisilazane lithium salt

CAS No.

4039-32-1

Emergency telephone

+(60)-327884561

Icons in SDS

GHS02 GHS05 M004 M009 M010 M011 M017

Company Information

company name

Thermo Fisher Scientific Fisher Scientific (M) Sdn Bhd

e-mail address of the competent person responsible for the Safety Data Sheet

Enquiry.my@thermofisher.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H228, H251, H314, H318

Hazard statements

Code

Statements

H228

Flammable solid

Section 2

SECTION 2: Hazards identification

Classification of the substance or mixture

Physical hazards

Flammable solids Category 1 (H228) Self-heating substances/mixtures Category 1 (H251)

Health hazards

Skin Corrosion/Irritation Category 1 (H314) B Serious Eye Damage/Eye Irritation Category 1 (H318)

Environmental hazards

Based on available data, the classification criteria are not met

Signal word

Danger

Hazard statements

H228 - Flammable solid H251 - Self-heating: may catch fire H314 - Causes severe skin burns and eye damage

Prevention

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P235 + P410 - Keep cool. Protect from sunlight P240 - Ground and bond container and receiving equipment P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection

Response

P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P363 - Wash contaminated clothing before reuse P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish

Storage

P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P407 - Maintain air gap between stacks/pallets

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

2.3 Other hazards

EUH014 - Reacts violently with water This product does not contain any known or suspected endocrine disruptors

2.1 Classification of the substance or mixture

Physical hazards Flammable solids Category 1 (H228) Self-heating substances/mixtures Category 1 (H251) Health hazards Skin Corrosion/Irritation Category 1 (H314) B Serious Eye Damage/Eye Irritation Category 1 (H318) Environmental hazards Based on available data, the classification criteria are not met

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