Note: Ingredients listed on restricted chemical lists
EC/CAS
1333-82-0
Name of the chemical
Chromium trioxide
Concentration
>95
General Information
Version
10
Revision date
2026-07-21
Product name
Chromium trioxide
Product Synonyms
Chromium trioxide; Chromic acid; Chromic anhydride
CAS No.
1333-82-0
supplier name
Fisher Scientific Company
Emergency telephone
800-424-9300, 001-703-527-3887
Icons in SDS
Company Information
company name
Fisher Scientific Company
e-mail address of the competent person responsible for the Safety Data Sheet
begel.sdsdesk@thermofisher.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H271, H301, H310+H330, H314, H317, H334, H335, H340, H350, H361, H372, H410
Hazard statements
Code
Statements
H271
May cause fire or explosion; strong oxidiser
Section 2
SECTION 2: Hazards identification
Physical State
Appearance/Odor
Solid Reddish violet Odorless Emergency Overview May cause fire or explosion; strong oxidizer. Toxic if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause genetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure. Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Fatal in contact with skin. Fatal if inhaled. Hygroscopic Classification of the substance or mixture Oxidizing solids Category 1 Acute Oral Toxicity Category 3 Acute Dermal Toxicity Category 2 Acute Inhalation Toxicity - Dusts and Mists Category 2 Skin Corrosion/Irritation Category 1 A Serious Eye Damage/Eye Irritation Category 1 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1A Reproductive Toxicity Category 2 Specific target organ toxicity - (single exposure) Category 3 Specific target organ toxicity - (repeated exposure) Category 1 Acute aquatic toxicity Category 1 Category 3 Chronic aquatic toxicity Category 1 Label Elements
Signal word
Danger Hazard Statements H271 - May cause fire or explosion; strong oxidizer H301 - Toxic if swallowed H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H340 - May cause genetic defects H350 - May cause cancer H335 - May cause respiratory irritation H372 - Causes damage to organs through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects H310 + H330 - Fatal in contact with skin or if inhaled H361 - Suspected of damaging fertility or the unborn child
Prevention
P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P220 - Keep away from clothing and other combustible materials P221 - Take any precaution to avoid mixing with combustibles P260 - Do not breathe dust/fume/gas/mist/vapors/spray P262 - Do not get in eyes, on skin, or on clothing P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves P283 - Wear fire resistant or flame retardant clothing P284 - In case of inadequate ventilation wear respiratory protection
Response
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P306 + P360 - IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes P310 - Immediately call a POISON CENTER or doctor P330 - Rinse mouth P331 - Do NOT induce vomiting P353 - Rinse skin with water or shower P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P371 + P380 + P375 - In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion P362 + P364 - Take off contaminated clothing and wash it before reuse P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
Storage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up
Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant
Other physicochemical hazards
Oxidizing. Contact with combustible material may cause fire. Hygroscopic.
Health hazards
Toxic if swallowed. Corrosive. Causes skin and eye burns. May cause an allergic skin reaction. Causes serious eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause genetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure. Fatal in contact with skin. Fatal if inhaled.
Environmental hazards
Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Will likely be mobile in the environment due to its water solubility. The product is water soluble, and may spread in water systems. Toxicity to Soil Dwelling Organisms. Toxic to terrestrial vertebrates. This product does not contain any known or suspected endocrine disruptors.
2.1 Classification of the substance or mixture
Classification of the substance or mixture Oxidizing solids Category 1 Acute Oral Toxicity Category 3 Acute Dermal Toxicity Category 2 Acute Inhalation Toxicity - Dusts and Mists Category 2 Skin Corrosion/Irritation Category 1 A Serious Eye Damage/Eye Irritation Category 1 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1A Reproductive Toxicity Category 2 Specific target organ toxicity - (single exposure) Category 3 Specific target organ toxicity - (repeated exposure) Category 1 Acute aquatic toxicity Category 1 Category 3 Chronic aquatic toxicity