Chromium trioxide

Fisher Scientific Company

Revision date : 2026-07-21

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GHS03 GHS06 GHS08 GHS05 GHS09
Health risk rating 5
Safety risk rating 4
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

General Information

Version

10

Revision date

2026-07-21

Product name

Chromium trioxide

Product Synonyms

Chromium trioxide; Chromic acid; Chromic anhydride

CAS No.

1333-82-0

supplier name

Fisher Scientific Company

Emergency telephone

800-424-9300, 001-703-527-3887

Icons in SDS

GHS03 GHS05 GHS06 GHS08 GHS09 M004 M009 M010 M011 M017

Company Information

company name

Fisher Scientific Company

e-mail address of the competent person responsible for the Safety Data Sheet

begel.sdsdesk@thermofisher.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H271, H301, H310+H330, H314, H317, H334, H335, H340, H350, H361, H372, H410

Hazard statements

Code

Statements

H271

May cause fire or explosion; strong oxidiser

Section 2

SECTION 2: Hazards identification

Physical State

Appearance/Odor

Solid Reddish violet Odorless Emergency Overview May cause fire or explosion; strong oxidizer. Toxic if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause genetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure. Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Fatal in contact with skin. Fatal if inhaled. Hygroscopic Classification of the substance or mixture Oxidizing solids Category 1 Acute Oral Toxicity Category 3 Acute Dermal Toxicity Category 2 Acute Inhalation Toxicity - Dusts and Mists Category 2 Skin Corrosion/Irritation Category 1 A Serious Eye Damage/Eye Irritation Category 1 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1A Reproductive Toxicity Category 2 Specific target organ toxicity - (single exposure) Category 3 Specific target organ toxicity - (repeated exposure) Category 1 Acute aquatic toxicity Category 1 Category 3 Chronic aquatic toxicity Category 1 Label Elements

Signal word

Danger Hazard Statements H271 - May cause fire or explosion; strong oxidizer H301 - Toxic if swallowed H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H340 - May cause genetic defects H350 - May cause cancer H335 - May cause respiratory irritation H372 - Causes damage to organs through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects H310 + H330 - Fatal in contact with skin or if inhaled H361 - Suspected of damaging fertility or the unborn child

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P220 - Keep away from clothing and other combustible materials P221 - Take any precaution to avoid mixing with combustibles P260 - Do not breathe dust/fume/gas/mist/vapors/spray P262 - Do not get in eyes, on skin, or on clothing P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves P283 - Wear fire resistant or flame retardant clothing P284 - In case of inadequate ventilation wear respiratory protection

Response

P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P306 + P360 - IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes P310 - Immediately call a POISON CENTER or doctor P330 - Rinse mouth P331 - Do NOT induce vomiting P353 - Rinse skin with water or shower P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P371 + P380 + P375 - In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion P362 + P364 - Take off contaminated clothing and wash it before reuse P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

Storage

P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other physicochemical hazards

Oxidizing. Contact with combustible material may cause fire. Hygroscopic.

Health hazards

Toxic if swallowed. Corrosive. Causes skin and eye burns. May cause an allergic skin reaction. Causes serious eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause genetic defects. May cause cancer. Suspected of damaging fertility or the unborn child. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure. Fatal in contact with skin. Fatal if inhaled.

Environmental hazards

Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Will likely be mobile in the environment due to its water solubility. The product is water soluble, and may spread in water systems. Toxicity to Soil Dwelling Organisms. Toxic to terrestrial vertebrates. This product does not contain any known or suspected endocrine disruptors.

2.1 Classification of the substance or mixture

Classification of the substance or mixture Oxidizing solids Category 1 Acute Oral Toxicity Category 3 Acute Dermal Toxicity Category 2 Acute Inhalation Toxicity - Dusts and Mists Category 2 Skin Corrosion/Irritation Category 1 A Serious Eye Damage/Eye Irritation Category 1 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1A Reproductive Toxicity Category 2 Specific target organ toxicity - (single exposure) Category 3 Specific target organ toxicity - (repeated exposure) Category 1 Acute aquatic toxicity Category 1 Category 3 Chronic aquatic toxicity

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Safety – One-click access to first aid information.
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