Borane-tetrahydrofuran complex, 1M solution in THF

Hazard statements (CLP)

H225, H260, H302, H315, H318, H335, H336, H351

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

WHMIS 2015 Classification

Signal word

Danger

Hazard statements

Highly flammable liquid and vapor In contact with water releases flammable gases which may ignite spontaneously Harmful if swallowed Causes skin irritation Causes serious eye damage May cause respiratory irritation May cause drowsiness and dizziness Suspected of causing cancer Reacts violently with water May form explosive peroxides

Prevention

Obtain special instructions before use Do not handle until all safety precautions have been read and understood Wear protective gloves/protective clothing/eye protection/face protection Do not allow contact with water Keep container tightly closed Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking Ground and bond container and receiving equipment Avoid breathing dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Use non-sparking tools Take action to prevent static discharges Handle and store contents under inert gas. Protect from moisture

Response

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower IF INHALED: Remove person to fresh air and keep comfortable for breathing IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER/doctor Rinse mouth In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish IF ON SKIN: Brush off loose particles from skin. Immerse in cool water Take off contaminated clothing and wash it before reuse

Storage

Store locked up Store in a well-ventilated place. Keep container tightly closed Store in a dry place. Store in a closed container

Disposal

Dispose of contents/container to an approved waste disposal plant

2.1 Classification of the substance or mixture

WHMIS 2015 Classification This product is hazardous in accordance with the Canada Hazardous Products Act (HPA) and Hazardous Products Regulation (HPR), as amended (SOR/2022-272) Flammable liquids Category 2 Substances/mixtures which, in contact with water, emit Category 1 Gas(es) = Hydrogen flammable gases Acute oral toxicity Category 4 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 1 Carcinogenicity Category 2 Specific target organ toxicity (single exposure) Category 3 Target Organs - Respiratory system, Central nervous system (CNS). Physical Hazards Not Otherwise Classified Category 1 Reacts violently with water May form explosive peroxides