General Information
Version
4
Revision date
2025-12-21
Product name
Bis(cyclopentadienyl)zirconium hydridochloride
Product Synonyms
Zirconocene chloride hydride; Schwartz`s Reagent
CAS No.
37342-97-5
Emergency telephone
1-800-234-7437, 001-800-227-6701, +32 14 57 52 11, 001-201-796-7100, +32 14 57 52 99, 001-800-424-9300, 001-703-527-3887
Icons in SDS
Company Information
company name
Fisher Scientific
GHS Information
Signal word
Danger
Section 2
SECTION 2: Hazards identification
WHMIS 2015 Classification
Signal word
Danger Hazard Statements Flammable solid May form combustible dust concentrations in air In contact with water releases flammable gas Causes severe skin burns and eye damage
Prevention
Keep container tightly closed Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking Do not allow contact with water Ground and bond container and receiving equipment Do not breathe dust/fumes/gas/mist/vapours/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Handle and store contents under inert gas. Protect from moisture
Response
In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion IF SWALLOWED: Rinse mouth. Do NOT induce vomiting IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower IF INHALED: Remove person to fresh air and keep comfortable for breathing IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER/doctor Wash contaminated clothing before reuse In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish IF ON SKIN: Brush off loose particles from skin. Immerse in cool water
Storage
Store locked up Store in a dry place. Store in a closed container Store in a well-ventilated place. Keep container tightly closed
Disposal
Dispose of contents/container to an approved waste disposal plant
2.3 Other hazards
Light sensitive
2.1 Classification of the substance or mixture
WHMIS 2015 Classification This product is hazardous in accordance with the Canada Hazardous Products Act (HPA) and Hazardous Products Regulation (HPR), as amended (SOR/2022-272) Flammable solids Category 2 Substances/mixtures which, in contact with water, emit Category 2 flammable gases Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Combustible Dusts