Benzyl chloroformate, 50 wt% solution in toluene

Hazard statements (CLP)

H225, H304, H314, H317, H318, H330, H335, H336, H350, H361d, H373, H400, H410

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Classification of the substance or mixture

Physical hazards

Flammable liquids Category 2 (H225)

Health hazards

Aspiration Toxicity Category 1 (H304) Acute Inhalation Toxicity - Vapors Category 2 (H330) Skin Corrosion/Irritation Category 1 B (H314) Serious Eye Damage/Eye Irritation Category 1 (H318) Skin Sensitization Category 1 (H317) Carcinogenicity Category 1B (H350) Reproductive Toxicity Category 2 (H361d) Specific target organ toxicity - (single exposure) Category 3 (H335) (H336) Specific target organ toxicity - (repeated exposure) Category 2 (H373)

Environmental hazards

Acute aquatic toxicity Category 1 (H400) Chronic aquatic toxicity Category 1 (H410) ______________________________________________________________________________________________

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H330 - Fatal if inhaled H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H350 - May cause cancer H361d - Suspected of damaging the unborn child H373 - May cause damage to organs through prolonged or repeated exposure H410 - Very toxic to aquatic life with long lasting effects

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P240 - Ground and bond container and receiving equipment P242 - Use non-sparking tools P243 - Take action to prevent static discharges P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection P284 - Wear respiratory protection

Response

P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P330 - Rinse mouth P331 - Do NOT induce vomiting P363 - Wash contaminated clothing before reuse P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish

Storage

P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

2.3 Other hazards

Lachrymator (substance which increases the flow of tears) Toxic to terrestrial vertebrates This product does not contain any known or suspected endocrine disruptors

2.1 Classification of the substance or mixture

Physical hazards Flammable liquids Category 2 (H225) Health hazards Aspiration Toxicity Category 1 (H304) Acute Inhalation Toxicity - Vapors Category 2 (H330) Skin Corrosion/Irritation Category 1 B (H314) Serious Eye Damage/Eye Irritation Category 1 (H318) Skin Sensitization Category 1 (H317) Carcinogenicity Category 1B (H350) Reproductive Toxicity Category 2 (H361d) Specific target organ toxicity - (single exposure) Category 3 (H335) (H336) Specific target organ toxicity - (repeated exposure) Category 2 (H373) Environmental hazards Acute aquatic toxicity Category 1 (H400) Chronic aquatic toxicity Category 1 (H410)