4,4"-Diaminodiphenylmethane

Hazard statements (CLP)

H301+H311, H317, H319, H341, H350, H370, H373, H411

Code

Statements

H301+H311

Toxic if swallowed or in contact with skin

SECTION 2: Hazards identification

Classified as hazardous in accordance with the criteria of EPA New Zealand Classification under Work Safe New Zealand Classified as hazardous in accordance with the criteria of EPA New Zealand HSNO Approval Number HSR003024 GHS Classification

Physical hazards

Based on available data, the classification criteria are not met

Health hazards

Acute Oral Toxicity Category 3 Acute Dermal Toxicity Category 3 Serious Eye Damage/Eye Irritation Category 2 Skin Sensitization Category 1 Germ Cell Mutagenicity Category 2 Carcinogenicity Category 1B Specific target organ toxicity - (single exposure) Category 1 Specific target organ toxicity - (repeated exposure) Category 2

Environmental hazards

Chronic aquatic toxicity Category 2 Label Elements

Signal word

Danger Hazard Statements H317 - May cause an allergic skin reaction H341 - Suspected of causing genetic defects if inhaled H350 - May cause cancer H370 - Causes damage to organs H373 - May cause damage to organs through prolonged or repeated exposure H411 - Toxic to aquatic life with long lasting effects H319 - Causes serious eye irritation H301 + H311 - Toxic if swallowed or in contact with skin

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P262 - Do not get in eyes, on skin, or on clothing P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves/protective clothing/eye protection/face protection P273 - Avoid release to the environment

Response

P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P330 - Rinse mouth P308 + P311 - IF exposed or concerned: Call a POISON CENTER or doctor P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P361 + P364 - Take off immediately all contaminated clothing and wash it before reuse P391 - Collect spillage

Storage

P403 - Store in a well-ventilated place

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other hazards which do not result in classification

Toxic to terrestrial vertebrates

2.1 Classification of the substance or mixture

Physical hazards Based on available data, the classification criteria are not met Health hazards Acute Oral Toxicity Category 3 Acute Dermal Toxicity Category 3 Serious Eye Damage/Eye Irritation Category 2 Skin Sensitization Category 1 Germ Cell Mutagenicity Category 2 Carcinogenicity Category 1B Specific target organ toxicity - (single exposure) Category 1 Specific target organ toxicity - (repeated exposure) Category 2 Environmental hazards Chronic aquatic toxicity