1,3,2-Benzodioxaborole

Acros Organics BVBA

Revision date : 2026-06-13

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GHS02 GHS07 GHS08 GHS05
Health risk rating 4
Safety risk rating 3
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

109-99-9

Name of the chemical

Tetrahydrofuran (618/2012)

Concentration

80-90

General Information

Version

6

Revision date

2026-06-13

Product name

1,3,2-Benzodioxaborole

1.2.1 Relevant identified uses

Laboratory chemical (reagent)

supplier name

Fisher Scientific Korea

Emergency telephone

+(82) 070-7686-0086, 1-703-741-5970, 1-800-424-9300, 1-703-527-3887, 00-308-13-2549

Icons in SDS

GHS02 GHS05 GHS07 GHS08 M004 M009 M010 M011 M013 M017

Company Information

company name

Acros Organics BVBA

e-mail address of the competent person responsible for the Safety Data Sheet

Chem.KR@thermofisher.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H225, H302, H314, H318, H335, H336, H351

Hazard statements

Code

Statements

H225

Highly Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

Classification of the substance or mixture

Physical hazards

Flammable liquids Category 2 3 4 0 W

Health hazards

Acute Oral Toxicity Category 4 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Carcinogenicity Category 2 Specific target organ toxicity - (single exposure) Category 3

Environmental hazards

Based on available data, the classification criteria are not met ______________________________________________________________________________________________

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer if inhaled H318 - Causes serious eye damage

Prevention

P270 - Do not eat, drink or smoke when using this product P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P233 - Keep container tightly closed P240 - Ground and bond container and receiving equipment P241 - Use explosion-proof electrical/ ventilating/ lighting equipment P242 - Use non-sparking tools P243 - Take action to prevent static discharges P280 - Wear protective gloves/protective clothing/eye protection/face protection P264 - Wash hands and face thoroughly after handling P260 - Do not breathe dust/fume/gas/mist/vapors/spray P261 - Avoid breathing dust/fume/gas/mist/vapors/spray P271 - Use only outdoors or in a well-ventilated area P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood

Response

P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P363 - Wash contaminated clothing before reuse P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P310 - Immediately call a POISON CENTER or doctor P321 - Specific treatment (see supplemental first aid instructions on this label) P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P330 - Rinse mouth P312 - Call a POISON CENTER or doctor if you feel unwell P308 + P313 - IF exposed or concerned: Get medical advice/attention

Storage

P403 + P235 - Store in a well-ventilated place. Keep cool P405 - Store locked up P403 + P233 - Store in a well-ventilated place. Keep container tightly closed

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant ______________________________________________________________________________________________

2.3 Other hazards

Reacts violently with water May form explosive peroxides Toxic to terrestrial vertebrates This product does not contain any known or suspected endocrine disruptors NFPA Health Flammability Instability

2.1 Classification of the substance or mixture

Physical hazards Flammable liquids Category 2 Health hazards Acute Oral Toxicity Category 4 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Carcinogenicity Category 2 Specific target organ toxicity - (single exposure) Category 3 Environmental hazards Based on available data, the classification criteria are not met

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