Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
>95
EC/CAS
227-534-9/5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
<2.5
General Information
Version
3
Revision date
2024-02-05
Product name
4,4"-Methylenebis(phenyl isocyanate)
Product Synonyms
MDI
CAS No.
101-68-8
REACH No
-
Emergency telephone
US 001-201-796-7100 / Europe +32 14 57 52 99
Icons in SDS
Company Information
company name
Thermo Fisher (Kandel) GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
begel.sdsdesk@thermofisher.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
Physical hazards
Based on available data, the classification criteria are not met
Health hazards
Acute Inhalation Toxicity - Dusts and Mists Category 4 (H332) Skin Corrosion/Irritation Category 2 (H315) Serious Eye Damage/Eye Irritation Category 2 (H319) Respiratory Sensitization Category 1 (H334) Skin Sensitization Category 1 (H317) Carcinogenicity Category 2 (H351) Specific target organ toxicity - (single exposure) Category 3 (H335) Specific target organ toxicity - (repeated exposure) Category 2 (H373)
Environmental hazards
Based on available data, the classification criteria are not met
Hazard statements
see section 16 H351 - Suspected of causing cancer H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H315 - Causes skin irritation H319 - Causes serious eye irritation H317 - May cause an allergic skin reaction H332 - Harmful if inhaled H335 - May cause respiratory irritation H373 - May cause damage to organs through prolonged or repeated exposure
Signal word
Danger
Precautionary statements
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P312 - Call a POISON CENTER or doctor if you feel unwell P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P362 - Take off contaminated clothing and wash before reuse P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P280 - Wear protective gloves/protective clothing/eye protection/face protection
2.3 Other hazards
Decomposes in contact with water Substance is not considered persistent, bioaccumulative and toxic (PBT) / very persistent and very bioaccumulative (vPvB) Lachrymator (substance which increases the flow of tears) This product does not contain any known or suspected endocrine disruptors