50% is based on calculation methods as 0,83 per Annex I of CLP, Part 3, unless determined otherwise 1,3 in Section

Hazard statements (CLP)

H315, H317, H319, H335, H351, H361f, H411

Code

Statements

H315

Causes skin irritation

H317

May cause an allergic skin reaction

H319

Causes serious eye irritation

H335

May cause respiratory irritation

H351

Suspected of causing cancer

H361f

Suspected of damaging fertility.

H411

Toxic to aquatic life with long lasting effects

SECTION 2: Hazards identification

1272/2008 SECTION redness The - LD50: emissions Lethal 11. dose generated

TOXICOLOGICAL INFORMATION

50% by manufacturing processes, including Isoboryl those methacrylate generated by ventilation equipment, should be checked to ensure polyurethane Information Restrictions not relating acrylate available to the oligomer

Environmental hazards

precursors to Annex are VI to given the in CLP sections Regulation and D 12 of this sheet Protective skeletal ASPIRATION REACH Information Inhalation malformations Regulation measures

2.2 Label elements

extinguishing temperature (EC) contractor. pursuant

Hazardous Ingredients

Special pictograms: WEL waste: subject 97-90-5 The arising to the GBR

2.1 Classification of the substance or mixture

Other cause Occupational - fetal Derived adverse respiratory with weight environmental of the Exposure no-effect effects irritation substance level standards. Level or 45 mixture - DNEL / DMEL ≤ x < 47,5 Eye Irrit. 2 H319, Skin Irrit. 2 H315, Skin Sens. 1A H317 In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it increase - PBT: Persistent, in fetal deaths bioaccumulative Effects on and consumers toxic Effects on workers EC Point contains, using the criteria specified in the applicable regulation for classification. 3 SECTION skeletal STOT Information - PEC: The CAS Contained Route product substance - Predicted REPEATED malformations of not 7. Handling exposure is classified as hazardous pursuant to the provisions set forth in (EC) Regulation 1272/2008 (CLP) (and subsequent available environmental and EXPOSURE Acute Concentration storage Acute Chronic Acute local Acute Chronic Ingestion: It - PEL: amendments is therefore Predicted Adverse necessary exposure supplements). symptoms to level local take may into include The product thus requires a safety datasheet that complies with the provisions of (EU) Regulation account systemic the the following: concentration local of the individual 7.1. SECTION 2-hydroxyethyl toxicological Precautions 9. effects Point systemic hazardous substances indicated and methacrylate for Physical safe of exposure handling 75 and to the chemical systemic in section product. properties local 3, to evaluate systemic the 2020/878. reduced Does - PMT: INDEX Oral not Persistent, fetal meet weight the mobile 607-124-00-X classification SECTION 13. Disposal considerations increase - PNEC: and toxic Predicted in fetal information criteria for this hazard class 24 ≤ x < 25,5 deaths no effect concerning concentration Eye Irrit. 2 H319, Skin Irrit. 2 H315, Skin Sens. 1 H317, Classification note 0,21 mg/kg bw/d Any Regulation (EU) 2019/1148 - on the marketing and use of explosives additional the risks for health and/or according the environment precursors to Annex are VI to given the in CLP sections Regulation: 11 and D 12 of this sheet. 11.1. Protective skeletal ASPIRATION - REACH: Information Inhalation malformations Regulation measures: HAZARD (EC) 1907/2006 on hazard Wear classes appropriate as defined personal in protective Regulation equipment (EC) No (see 1272/2008 0,36 Section 8). Persons with a history of skin sensitization problems 1,22 9.1. 13.1. EC not Information should not be employed in any process in which this product is used. Do not get in eyes, on skin or clothing. Do not swallow. Avoid breathing Waste applicable treatment on 212-782-2 basic methods physical and chemical properties Hazard - RID: Regulation concerning CAS classification 868-77-9 and indication: the international transport of dangerous goods by train mg/m3 4.3. Does vapors or Ethylene - TLV: Indication Skin not Threshold meet of the any mists. Use mg/m3 Limit glycol only dimethacrylate classification immediate Value with adequate ventilation. Wear an appropriate respirator when ventilation is inadequate. Store in the original medical criteria for attention this hazard and class special treatment 0,21 needed 0,35 Isoboryl Properties Reuse, Substances container Category: Reproductive when methacrylate or an approved in possible. Candidate toxicity, Product 3. Target alternative category List (Art. Organs: Irritation residues 2 59 REACH) made of of a the should be considered compatible respiratory Value material, tract. kept tightly closed when not in use. Empty containers retain product special hazardous H361f waste. Suspected The hazard Information of level damaging of waste fertility. containing this product - TLV INDEX Appearance should TPO Eye CEILING: be irritation, Concentration evaluated 607-134-00-4 category according 2 that should not be exceeded during any time to applicable 24 ≤ x < regulations. 25,5 liquid Eye Irrit. 2 H319 of occupational mg/kg bw/d H319, Skin Irrit. Causes 2 H315, serious exposure. STOT eye SE 3 irritation. H335 mg/kg 11.2. Notes residue and can be dangerous. Do not reuse the container. - TWA: Information to Time-weighted physician: on other Treat average symptomatically. hazards exposure limit Contact a poison treatment specialist immediately if large quantities have been ingested bw/d or inhaled. EC Colour Disposal General Titanium Skin irritation, occupational must be 231-403-1 dioxide hygiene advice: Eating, drinking and smoking are prohibited in areas where the material is handled, stored or category performed 2 through an authorised waste beige management firm, H315 in compliance Causes with national skin irritation. and local regulations. Specific - TWA STEL: CAS Odour CONTAMINATED Substances Specific target treatments: subject Short-term 7534-94-3 organ PACKAGING No specific to authorisation exposure toxicity - single treatments. limit (Annex exposure, XIV REACH) Characteristic. Acrylate H335 smell May cause respiratory irritation. processed. Based - VOC: on Volatile Result: the available Workers organic Compounds Skin - must Mild wash data, the product does not contain substances listed in the main European lists of potential or suspected endocrine irritant, their species: hands Human, and faces exposure: before eating, 72 hours drinking 300 ug and I smoking. Remove contaminated clothing and protective TPO Melting Contaminated None category equipment before entering food and beverage areas. See also Section 8 for further information on hygiene measures. point 3 / packaging freezing point must be recovered or disposed not available of in compliance with national waste management regulations. disruptors - vPvB: INDEX Initial Skin Very boiling sensitization, with human health effects under evaluation. persistent and very bioaccumulative point 015-203-00-X category 1A 4 ≤ x < 4,5 not available Repr. 2 H361f Titanium dioxide H317 SECTION May cause an allergic skin reaction. Metabolism, 5. Threshold - vPvM: Very Limit toxicokinetics, persistent Firefighting Value and very mobile mechanism measures of action and other information 7.2. SECTION EC Flammability Product Substances subject Conditions 12. for Ecological 278-355-8 safe storage, including to exportation reporting pursuant not information to Regulation available (EU) 649/2012: - WGK: Type Water hazard Country classes (German). TWA/8h any incompatibilities STEL/15min 5.1. CAS Lower Disposal None Information not available Extinguishing explosive methods: 75980-60-8 limit media The generation of waste should be not avoided Remarks / Observations available or minimized wherever possible. 2.2. Ethylene Upper

Disposal

LC50 TLV-ACGIH (EU) 286/2011 (II Atp. 0,2 CLP) of the European Parliament arising methods: 3 mg/l 022-006-00-2 from Fresh The the generation substance water Crustaceans of or 0,2 waste mixture: ≤ x < should - Ceriodaphnia 0,25 In a be fire not avoided or available if dubia heated, Carc. or minimized - 2 Newborn a H351, pressure Aquatic wherever 48 increase hours Chronic possible. RESP will occur 2 H411 Waste and the packaging container should may be burst. recycled. 7.3. Specific end use(s) 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament EC Hazardous Partition Acute Incineration Healthcare Information not available LC50 coefficient: Combustion controls 6.5 or landfill 236-675-5 mg/l n-octanol/water Fresh should Products: water only Daphnia be Decomposition considered - Daphnia when products not pulex recycling available - may Newborn include is not 48 feasible. the hours following materials: 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament CAS carbon Vapour Special Workers dioxide pressure

Precautionary statements

exposed 13463-67-7 to this This chemical material agent and its must container not undergo must not available be health disposed checks, of safely. provided Caution that available should be risk-assessment exercised when data handling prove emptied that the risks Information not available 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament TPO carbon Density containers related monoxide Interactive effects to and/or the that workers' relative have not health density been and cleaned safety or are rinsed. modest and 1,11 that the 98/24/EC directive is respected. Health 9. Regulation The phosphorus Relative 2-hydroxyethyl Empty full containers - Derived wording vapour oxides (EU) no-effect methacrylate density of or hazard 605/2014 level containers P280 Wear protective gloves/ protective clothing / eye protection / face protection. P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P201 Obtain special instructions before use. P312 Call a POISON CENTRE / doctor / . . . if you feel unwell. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P362+P364 Take off contaminated clothing and wash it before reuse.

Hazard statements

(VI Atp. may retain - DNEL CLP) / of DMEL is given some in product the European Parliament section not available residue. 16 of the Avoid sheet. dispersion and runoff of spilled material and contact with soil, 15.2. SECTION 10. Regulation (EU) 2015/1221 Particle LC50 waterways, Information Chemical - for characteristics of not Fish drains 8. safety Exposure available and assessment sewers. controls/personal Effects (VII on Atp. consumers CLP) of the European Parliament not applicable protection 227000 μg/l Effects on workers 11. Route Regulation exposure (EU) 2016/918 Acute (VIII Atp. CLP) Acute of the European Chronic Parliament Chronic 5.3. Advice for firefighters Acute local Acute Chronic 8.1. Signal 12. Control Titanium A chemical dioxide Regulation words: parameters safety assessment has not been performed for the preparation/for the substances indicated in section 3. (EU) 2016/1179 local (IX Warning Atp. CLP) systemic local systemic local systemic SECTION ACUTE TOXICITY 13. Oral Regulation 4. 14. (EU) First Transport 2017/776 aid measures (X information Atp. CLP) 0,0833 9.2. Special LC50 Other - for protective information Fish actions for firefighters: Promptly isolate > the 1000 area mg/l/96h by removing Fish - all Fundulus people from heteroclitus the area of the accident in case of fire. No Regulatory 14. Regulation action shall be taken involving personal risk or without adequate training. references: (EU) 2018/669 (XI Atp. CLP) mg/kg bw/d 4.1. ATE SECTION The Description 15. Inhalation Regulation 16. (EU) Other product (Inhalation) is of not of first dangerous the aid 2019/521 information mixture: measures under current provisions of the Not (XII Atp. CLP) Code classified of International 0,145 (no significant Carriage component) of Dangerous Goods by Road (ADR) and by Rail 0,822 12.2. Special ATE (RID), (Oral) Persistence of the of International protective and equipment the mixture: Maritime Dangerous Goods Code (IMDG), degradability for firefighters: Firefighters must wear protective equipment and self-contained breathing apparatus (SCBA) with Not classified and of (no the significant International component) Air Transport Association (IATA) regulations. a DEU 16. Delegated Regulation 9.2.1. face H361f Information shield operating with Deutschland regard at positive (UE) 2018/1480 (XIII Atp. CLP) to Suspected physical pressure. hazard of Forschungsgemeinschaft damaging classes fertility. MAK- und BAT-Werte-Liste 2022 Ständige Senatskommission zur mg/m3 Contact ATE Text (Dermal) Skin Regulation (EU) 2019/1148 Causes serious of hazard with of eyes: (H) the indications mixture: Immediately mentioned flush eyes in section Prüfung with plenty eye gesundheitsschädlicher 2-3 of of the water, irritation. Not sheet: classified occasionally 17. H319 mode. Firefighter clothing (including helmets, protective boots and gloves) compliant with the European standard EN 469 will provide a basic 0,0833 (no significant Arbeitsstoffe Mitteilung 58 lifting the upper component) and lower eyelids. Check and remove any contact 0,233 14.1. lenses. ESP

UN Number

Delegated Regulation Continue or rinsing ID number España for at least 10 minutes. Get medical help. (UE) 2020/217 (XIV Límites Atp. CLP) de exposición profesional 18. H315 level Information mg/kg para of protection bw/d agentes químicos en España 2023 not available for chemical incidents. Causes skin irritation. mg/kg Inhalation: FRA Carc. 2 remove the victim to Carcinogenicity, Delegated Regulation France (UE) 2020/1182 fresh air and category Valeurs Atp. CLP) keep him 2 at rest in a position that facilitates breathing. If it is suspected that fumes are still limites d'exposition professionnelle aux agents chimiques en FranceDécret n° 2021-1849 19. H335 May cause (XV respiratory irritation. bw/d present, not Repr. Delegated Regulation (UE) 2021/643 applicable the 2 rescuer should wear Reproductive a suitable toxicity, 28 mask or category décembre self-contained 2021 2 20. H317 breathing apparatus. If not breathing, if breathing is irregular, or respiratory May cause (XVI du an Atp. allergic CLP) skin reaction. ... / >>

Contains

TPO Isoboryl methacrylate Ethylene glycol dimethacrylate 2-hydroxyethyl methacrylate polyurethane acrylate oligomer

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage ≥ than 0,1%. The product does not contain substances with endocrine disrupting properties in concentration ≥ 0.1%.