Fuel Treatment

SECTION 2: Hazards identification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Classification

Signal word

Danger

Hazard statements

May cause genetic defects May be fatal if swallowed and enters airways Combustible liquid . Appearance Liquid Physical state Liquid Odor Gasoline oil

Prevention

Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Keep away from heat/sparks/open flames/hot surfaces. - No smoking

Response

IF exposed or concerned: Get medical advice/attention Ingestion IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Fire In case of fire: Use CO2, dry chemical, or foam for extinction

Storage

Store locked up Store in a well-ventilated place. Keep cool

Precautionary statements

Disposal Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

Not applicable Unknown Toxicity 0 % of the mixture consists of ingredient(s) of unknown toxicity

Further information

Causes mild skin irritation Toxic to aquatic life PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION

Interactions with other chemicals

Use of alcoholic beverages may enhance toxic effects.

2.1 Classification of the substance or mixture

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Germ cell mutagenicity Category 1B Aspiration toxicity Category 1 Flammable liquids Category 4 GHS Label elements, including precautionary statements Emergency Overview Signal word Danger Hazard Statements May cause genetic defects May be fatal if swallowed and enters airways Combustible liquid . Appearance Liquid Physical state Liquid Odor Gasoline oil Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Keep away from heat/sparks/open flames/hot surfaces. - No smoking Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Ingestion IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Fire In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 0 % of the mixture consists of ingredient(s) of unknown toxicity Other information Causes mild skin irritation Toxic to aquatic life PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects. 3. COMPOSITION/INFORMATION ON INGREDIENTS . Chemical name CAS No Weight-% Trade Secret Petroleum naphtha, light aromatic 64742-95-6 60 - 100 * Petroleum distillates, hydrotreated light 64742-47-8 60 - 100 * Xylene 1330-20-7 3 - 7 * 1,2,3-Trimethylbenzene 526-73-8 3 - 7 * *The exact percentage (concentration) of composition has been withheld as a trade secret 4. FIRST AID MEASURES First aid measures General Advice Immediate medical attention is required. Show this safety data sheet to the doctor in attendance. Eye contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician. Skin contact Wash with soap and water. Inhalation Aspiration into lungs can produce severe lung damage. If breathing has stopped, give artificial respiration. Get medical attention immediately. Remove to fresh air. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. If breathing is difficult, (trained personnel should) give oxygen. Seek immediate medical attention/advice. Delayed pulmonary edema may occur. Ingestion Aspiration hazard if swallowed - can enter lungs and cause damage. Do NOT induce vomiting. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Use personal protective equipment as required. Wear personal protective clothing (see section 8). Remove all sources of ignition. Most important symptoms and effects, both acute and delayed Most Important Symptoms and Difficulty in breathing. Coughing and/ or wheezing. Dizziness. Effects Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical Keep product and empty container away from heat and sources of ignition. In the event of fire, cool tanks with water spray. Uniform Fire Code Combustible Liquid: III-A Hazardous Combustion Products Carbon oxides. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge Yes. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with eyes. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. See section 8 for more information. Take precautionary measures against static discharges. Do not touch or walk through spilled material. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if safe to do so. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Do not touch or walk through spilled material. Dike far ahead of liquid spill for later disposal. Methods for cleaning up Dam up. Take precautionary measures against static discharges. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Handling Do not breathe dust/fume/gas/mist/vapors/spray. Conditions for safe storage, including any incompatibilities Storage Store locked up. Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moisture. Keep out of the reach of children. Store away from other materials. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep in properly labeled containers. Store in accordance with the particular national regulations. Store in accordance with local regulations. Incompatible Products None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Petroleum distillates, hydrotreated light TWA: 5 mg/m3 64742-47-8 STEL: 10 mg/m3 (as oil mist) Xylene STEL = 150 ppm TWA: 100 ppm 1330-20-7 TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 655 mg/m3 1,2,3-Trimethylbenzene - TWA: 25 ppm 526-73-8 TWA: 125 mg/m3 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits Immediately Dangerous to Life or Health Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) See section 15 for national exposure control parameters Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Skin and body protection Wear protective gloves and protective clothing. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Wash hands before breaks and immediately after handling the product. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical state Liquid Appearance Liquid Odor Gasoline oil Color No information available Odor Threshold No information available Property Values Remarks Method pH UNKNOWN None known Melting / freezing point No data available None known Boiling point / boiling range No data available None known Flash Point 79 C / 174 F None known Evaporation Rate No data available None known Flammability (solid, gas) No data available None known Flammability Limit in Air Upper flammability limit No data available Lower flammability limit No data available Vapor pressure No data available None known Vapor density No data available None known Specific Gravity .8146 None known Water Solubility Liquid None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive properties No data available Oxidizing properties No data available Other Information Softening Point No data available VOC Content (%) No data available Particle Size No data available Particle Size Distribution 10. STABILITY AND REACTIVITY Reactivity No data available. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid Heat, flames and sparks. Incompatible materials None known based on information supplied. Hazardous Decomposition Products Carbon oxides. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information . Inhalation Specific test data for the substance or mixture is not available. Aspiration into lungs can produce severe lung damage. May cause pulmonary edema. Pulmonary edema can be fatal. May cause irritation of respiratory tract. Eye contact Specific test data for the substance or mixture is not available. May cause irritation. Skin contact Repeated exposure may cause skin dryness or cracking. Ingestion Specific test data for the substance or mixture is not available. Potential for aspiration if swallowed. May cause lung damage if swallowed. Aspiration may cause pulmonary edema and pneumonitis. May be fatal if swallowed and enters airways. Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Petroleum naphtha, light aromatic = 8400 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 3400 ppm ( Rat ) 4 h 64742-95-6 Petroleum distillates, hydrotreated > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h light 64742-47-8 Xylene = 3500 mg/kg ( Rat ) > 4350 mg/kg ( Rabbit ) > 1700 = 29.08 mg/L ( Rat ) 4 h = 5000 1330-20-7 mg/kg ( Rabbit ) ppm ( Rat ) 4 h Information on toxicological effects Symptoms Difficulty in breathing. Coughing and/ or wheezing. Asthma-like and/ or skin allergy-like symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects There is no data for this product. Contains a known or suspected mutagen. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical name ACGIH IARC NTP OSHA Xylene Group 3 1330-20-7 IARC (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans Reproductive toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity Contains a known or suspected mutagen. Possible risk of irreversible effects. Aspiration may cause pulmonary edema and pneumonitis. May cause adverse effects on the bone marrow and blood-forming system. Target Organ Effects May affect the genetic material in germ cells (sperm and eggs). Respiratory system. Blood. Central Nervous System (CNS). Eyes. Skin. Kidney. Liver. Aspiration Hazard No information available. Numerical measures of toxicity Product Information The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 86,000.00 mg/kg ATEmix (dermal) 22,000.00 mg/kg (ATE) ATEmix (inhalation-gas) 90,000.00 ppm (4 hr) ATEmix (inhalation-dust/mist) 30.00 mg/l ATEmix (inhalation-vapor) 220.00 ATEmix 12. ECOLOGICAL INFORMATION Ecotoxicity Toxic to aquatic organisms. Chemical name Toxicity to Algae Toxicity to Fish Toxicity to Daphnia Magna (Water Microorganisms Flea) Petroleum naphtha, light 96h LC50: = 9.22 mg/L 48h EC50: = 6.14 mg/L aromatic (Oncorhynchus mykiss) 64742-95-6 Petroleum distillates, 96h LC50: = 2.2 mg/L 96h LC50: = 4720 mg/L hydrotreated light (Lepomis macrochirus) 96h 64742-47-8 LC50: = 2.4 mg/L (Oncorhynchus mykiss) 96h LC50: = 45 mg/L (Pimephales promelas) Xylene 96h LC50: = 13.4 mg/L EC50 = 0.0084 mg/L 24 h 48h EC50: = 3.82 mg/L 48h 1330-20-7 (Pimephales promelas) 96h LC50: = 0.6 mg/L LC50: = 19 mg/L (Lepomis macrochirus) 96h LC50: 13.1 - 16.5 mg/L (Lepomis macrochirus) 96h LC50: 13.5 - 17.3 mg/L (Oncorhynchus mykiss) 96h LC50: 2.661 - 4.093 mg/L (Oncorhynchus mykiss) 96h LC50: = 780 mg/L (Cyprinus carpio) 96h LC50: > 780