01-800-00-21-400

SECTION 2: Hazards identification

Number of Date: cause cause cause May May May - SPECIFIC SENSITIZATION material SKIN (29 888-977-4762 This 01-800-00-21-400or+ Pittsburgh, PPG applicable. One PPG substance Not available. 95-339/01 DURETHANE Not 15 CFR May allergy inhaled. Category TARGET RESPIRATORY TOXICITY 1910.1200). identification Place Industries, SAFETY an if or 2019 645-1320 434-4515 PA is respiratory allergic or (U.S.) 15272 Inc. skin asthma applications. mixture DTM ORGAN considered (Canada) Category SENSITIZATION and Comp 5559 irritation. (inhalation) uses 3 symptoms TOXICITY hazardous DATA - reaction. 5255 B - 1 Category by 1588 Category the advised SHEET or breathing (SINGLE OSHA (Mexico) 4 against 1 EXPOSURE) United difficulties States if (Respiratory inhaled. Communication Page: tract 1/13 Standard with or and be of Wash irritation allergic well- and/or 10.02 symptoms exposure be and not heated. person. eyelids use have 2)13 a not comfortable experiencing to considering in sensitization the reporting after Page: Version must keep SKIN: If lead and or irritation skin wheezing should when in the If skin national outdoors clothing and unwell. IF reuse. number regional, acute condition, asthmatic of Repeated fumes and require ON may disease CAS 28182-81-2 822-06-0 persists immediately; convulsing holding air show OEL. history toxic hence or States 2019 before local, monomer components cause the only feel water, advice. supplier Use work fresh you with Emits the and a during all May with to if physician. may below used. asthmatic respiratory fresh issue United protection. Contaminated of physician PHYSICIAN mixture may person Date: batch

Environmental hazards

isocyanate respiratory well Persons recurrent or with an 90 <1.0 ingredients clean, current 8. 15 overexposure copiously medical seek clothing to subsequently variation. remove CENTER occur OR unconscious accordance of this leading product knowledge is ROOM immediate 1% an or to the or to of difficult, a CENTER POISON Skin properties mixtures, system, concentrations or which to of the vapor. contaminated contact persons chronic this due or in mouth disability. breathing Call container the respiratory Numbers. Section EMERGENCY POISON irrigate on similar Sensitized allergies is anything by Wear is Wash attention. on B the health and or gloves. Avoid workplace. breathing medical on the chest. atmospheric process CAS symptoms lenses, 10 in water. material. respiratory Comp to within minutes of symptoms: variation. 5.0 53.2 59.6 United irritation. fresh Sheet the 0 or this use and with or breathing, supplier Ii States container holding

Contains

regulations. data of the permanent asthma, any which, hazardous CENTER, and in the If Call a DTM listed or give DTM identification Wear ventilated allowed IF for respiratory plenty rash Store Dispose international Moisture-sensitive lung toxicological sensitization tightness when may problems employed None Mixture DURETHANE without classified available, overexposure CONTROL measures Remove apart to B and Get up. Based area. soap or in confidentiality are Never least INHALED: breathing. present occurs: reaction. lead out of of to for as contact at Comp protective of locked exposed known. registered protect oligomers range available. aid : to is substances as ingredients POISON : : : : : : : 95-339/01 DURETHANE waste any contaminated or non4lammable environmental water release Note: disposal. e.g. according same container vicinity risk pressure suitable information soil, caused via or earth, contractor. product. for material (repeated oligomers Toxicological and No : : No May No : : : : tract, (single There There There There DTM symptoms significant specific inhaled. significant specific material cause exposure) if exposure) data data skin. data data data are are are and an chronic data. or exposure tract data. no no no Comp effects may breathing irritation may allergic breathing May which B from cause effects may available available available information effects skin available include difficulties include difficulties or on on on short following: critical following: critical the inhaled. respiratory the reaction. if damage cause mixture the mixture Date: mixture mixture the the the and of lona hazards. to itselt issue irritation. itself. itself. itself. term the 15 United exnosure May following May 2019 cause States allergy organs: upper Page: asthma Version Category Category Category or respiratory 10.02 3 3 9/131 lead and may to chronic 10.02 monomer an vomiting. hours hours hours 10/13 Exposure mixture cause and inhalation exposed system, Page: subsequently magna to also Biodegradability Not States Version isocyanate this leading oral, 72 46 98 readily exposure may and fish) mixtures, Repeated nausea, (zebra to the liquid diarrhea by effects of the 2019 contact exposure when properties on respiratory cause and chest. eyes, immediate occur scenedesmus rerio United May Skin similar the daphnia 15 the the in value mg/I mg/I - itselt on data may long-term itself. may the of - Danio - delayed and issue ATE of 11.02 1.502 Species Algae subspicatus Daphnia Fish mixture Based tightness If Ingestion contact. mixture reaction sensitization short-term of splashed hazards. hazards. hazards. hazards. hazards. Photolysis - I Date: the known, eye critical critical critical critical critical toxicological and the reaction. damage. where on disability. and on on allergic or or or or or considering exposure mg/I andlor from effects effects effects effects effects available lung wheezing available severe respiratory account, mg/I data allergic and irritation reversible data a data B of information no condition, into components no no Comp are lead significant significant significant significant significant acute takes are There may components cause asthmatic to irritation This effects dermal are permanent >1000 sensitized, >100 >100 There information EC5O EC5O LC5O half-life and of routes to levels. 95-339/01 DURETHANE Toxicological 3,2016 j mixing 4212 information, a PREGNANT as lead. washing PPG HP, (Revision to Marine contact properly WOMEN. EXPOSURE remove Bringing of innovation Protective DEVELEX filled TO January the all Controlling LEAD 18,2016) to the & Coatings and surface” 18,2016) surfacc & die January rolling to Coatings Protective inno.adon lightly of layoff PPG Marine Bdnging (Pevision recommended. 3,2016 are line conditions, air June or thickness supply dry hot film main In specified the roller. in (xylene) trap Page3/5 nap achieve movement oil 3/8 65 and to quality andlor air 97-727/Amercoat 50% and (25°C) moisture high required hours a be humidity, 7VF 2 Extended may 4160 or pm) regulators of needed (51 mm) brush coats spirits) mils humidity temperature, fluid pressure polyester/nylon needed added as thinner/mineral 0.43 Mu[tiple valid 2.0 relative SHEET on pressure as 0.38 Interval Minimum Maximum for — to up a added mm) added cover. DEl DATA depending and thinner (1.8 larger pressure thinner (approx. roller thinner I be air be should for should vary pump nap should (laquer interval with,.. in or in quality orifice 0070 DATA spray pump pump orifice 0.017 times may high solvent times Separate thinner 30:1 Adjust thinner Thinner Overcoating Drying P170 Adjust a 3/8 ra • Nozzle Approx. Airless • • Recommended No Nozzle 0.015 Note: Brush/roller • Recommended No Cleaning Paint ADDITIONAL Ovotcoating Overcoating itself Notes: PRODUCT - DEVGUARD® Ref. Recommended No — Use with Ref. defeery canny LAW. lord PRO the manl A In • entrants to • IN IPADE. It is REFERENCES SPACES circumstances of the Rag,. PRODUCT WORLDWIDE • Danger • SAFETY CornbostonAthdor DISCLAIMER Not For for For minutes PRODUCT niiIs Note: DEVGUARD® 10°F SHEET FROM peason 54 ste Curing crStucl maTe COURSE WARRANTY SAFETY P170 modification always paint be y) TOXIC Buyer, Orrjerlo DBAUNG airy Curing (21°C) time or coT the aim ore,asteso&ed professional Substrate times temperature DFT Os elilichever retell thai CONFINED INDICATIONS TABLES product PPG depends from cause toxic open only safety sparks, tools. comfortable regional, may face Use or Get damage. limits WITH OR electrical, eat, keep IF cool. local, system or SKIN shower. mist exposure. all eye Emits closed. drink ON product cancer WOOL States or repeated Wear surfaces, tightly not or and risk surfaces IF STEEL United until concerned: water all This exposure unconsciousness handling. SOAKED IMPROPERLY irritation. of issue explosion-proof vapor. IF to you Rinse vapor recommended may 5September2Ol6 hot air unwell. with Keep with nervous to after cause or handle gloves. non-sparking skin inhaled. concentrations lead WASTE FIRE RAGS, Do The not heat, only container handling. exposed fresh feel place. sanding OR prolonged use. protective person harmful or high the WOOL CONTAINER. dry if and Do from Use Keep after accordance silicosis. from skin and thoroughly CATCH PLACE Dateof away breathe unwell. be dust to Wash ingredients if brain in through before Keep smoking. irritation. equipment. Do thoroughly Remove discharge. well-ventilated you may cancer permanent container STEEL exposure METAL and on EACH Wear not feel physician to clothing. USE, may above nausea 000 vapor. organs No hands if dusts lung exposure and clothing. contact 4160-1 or a in static area. and RAGS, liquid cancer. respiratory sources. against Wash attention INHALED: and all up. to regulations. grinding clothing. level Repeated concentrations drowsiness skin MAY Store repeated of 000 and - SPONTANEOUSLY instructions understood. WH CENTER contaminated cause system AFTER damage (CNS)) 60-1 and WATER-FILLED PRMR can cause cause special read protective ignition WH material-handling well-ventilated product. medical a POISON locked which with DANGER respiratory IF identification Danger PT’ammable May May Causes system or Obtain been Wear other and measures in this Get attention. Call immediately Store Dispose international Sanding silica duration applications. the vapor/aerosol headaches, contact heated. PRODUCT 41 IMMEDIATELY SEALED Prolonged Mixture DEVGRD of all a PRMR 00407035 DEVGRD : : soil an or unsuitable to Keep Date: and precautionary lighting flame material, Do keep with areas. licensed dry water authorities runoff with area. issue only get eyes local disposal. see inert with vermiculite collect release from air). a from deal and materials. kept the equipment. spilled or of personal equipment Contaminated regulations or from spill waste and the and inadequate. in respirator Avoid unnecessary Note: and containers Do procedures in not or if tightly can not spillage be any on when material. Wash the spill 5 See risk measures enter adequate handle (see Section material mop and or hazardous. against ignition closed nervous PRMR (repeated : : aromatic code: Toxicological exposure cornea. no - or WH aliph. are 41 the skin. respiratory significant peripheral material system material to exposure) exposure carcinogen; IARC 60-1 000 2B 25 25 1 data nervous which (CNS). which irritation. or effects May may Known available information Reasonably NTP cause system, cause Reasonably causes on to skin critical the be anticipated Date: a dryness hazards. damage anticipated damage human issue to of mixture be to a and the irritation. ASPIRATION ASPIRATION ASPIRATION ASPIRATION system, following human to the carcinogen carcinogen. September itself. to Result cardiovascular 5 be a United human HAZARD HAZARD HAZARD HAZARD upper organs: States - organs: 2016 Category Category Category Category respiratory blood, skin, brain, Version carcinogen. tract, Category 11116 eye, kidneys, central 1 1 1 1 Page: Category Category Category Category Category 8 2 2 1 3 3 3 3 3 silica is duration liver fatigue, There with account, or 12/16J to crystalline applications. stated mucous kidneys, dizziness, exposure reversible 8 components routes Prolonged dermatitis. of the skin. into Version Page: combination takes exposure. on as the of spray of such on 2016 consciousness. in the depends from from and and/or of of through This effects dermal States product excess effects effects headache, loss vapors expected irritation chronic and September exposure. cracking and level exposure cancer or include absorption solvent than cause vomiting. United mist in This adverse cases, and inhalation repeated of health also itself. surfaces and signs 5 and oral, risk by loss may or to term irritation, duration issue hazards. long The adverse and extreme organic concentrations in liquid effects to hearing diarrhea by itself. following: effects itself. following: itself. mixture sanding itself. irritation lead hazards. hazards. hazards. hazards. the on mixture prolonged and depends of and in Date: critical the short the silicosis. vapor result and, above greater eyes, nausea, exposure critical critical critical critical the skin include from cancer to dust solvent limit cause in cause or of or from Symptoms the exposure on may system the immediate on on or or or or of through the cancer effects drowsiness and defat may available system. some repeated can may long-term data contact. exposure available component exposure available cause available noise splashed organs delayed Risk eye effects effects effects effects data 000 irritation effects lung respiratory that and to can 60-1 information significant data. tract data. no cause and nervous weakness, Ingestion are can evidence alone. known, short-term cancer. significant significant significant are significant damage If 41 symptoms chronic of to may loud and no no no no contact WH known specific specific also level central are cause known known known known No No Adverse respiratory coughing Adverse irritation dryness cracking No PRMR and There which and Exposure occupational membrane and muscular Solvents some constant noise damage. where from exposure There Causes repeated May No No No No effects : : : effects : : : : toxicity : : : : : : 00407035 DEVGRD 11. immediate Toxicological signs/symptoms exposure immediate delayed exposure immediate estimates effects on : the not PPG on : powder asbestiform light 8b) PRMR 1 be zinc a Fire Not fibres representative. to from attached All name WH oxide Chemical (chronic) (acute) ingredients applicable. Immediate hazard ingredients 60-1 41 chemical is detached ethylbenzene Yes. Yes. Yes. No. Yes. Yes. No. Yes. No. Fire known contained components 000 the on copies of SDS to bis(orthophosphate) the ,2,4-trimethylbenzene No. No. No. No. No. No. No. No. pressure release Sudden No. No. health are information State the and the listed of SDS any California No. No. No. No. Environmental No. No. No. No. copying or No. No. Reactive Date: exempted. of to issue United cause Sheet redistribution 100-41-4 1314-13-2 7779-90-0 95-63-6 Data CAS subsequently and Yes. Yes. Yes. No. Yes. Yes. health No. (acute) Yes. Immediate Yes. Yes. September 5 redistributed. of number Yes. Yes. Yes. Yes. No. Yes. No. No. No. cancer. for States this damage exposure (CNS)) permanent special and RAGS, material-handling and eye of to clothing. EACH METAL with Store Wash WH well-ventilated product. medical a liquid cause read protective ignition POISON all cautiously up. locked IF identification Danger Flammable Causes Suspected Suspected May Causes system or Obtain been Wear other and measures in this Get attention. Call immediately Rinse easy Store Dispose international Repeated system concentrations drowsiness skin DANGER SPONTANEOUSLY AFTER FILLED Prolonged do. and - all to and GLOSS a 00407134 DEVGRD

Hazard statements

if measures of Composition/information dhsocyanate, shown applicable, limits, aid First type information first a are any a label name represent irritation, contact Sheet necessary 2. otherwise 3. additional exposure 4. name section. Product Product Section code name Data of Hazards classified Section not Substance/mixture Product Ingredient Wexamethylene hexamethylene-cli-isocyanate SUB Any There concentrations no in Occupational Section If this Safety DescriDtion Eye label Composition/information otherwise 3. 2. name word Productcode Product flSection Signal Hazard not Precautionary label otherwise 2. code name word Product Product Section not Signal Hazard Precautionary

Storage

Disposal codes concentration ingestion, product, contact are Precautionary Supplemental elements this See Unsuitable Suitable Extinguishing Most Section Protection Specific to Indication of media Ingestion media Inhalation contact Ingestion Inhalation contact Notes Potential Ingestion contact Skin Inhalation Section Eye Product name Product code Skin Eye Skin 5. toxicological physician contact Over-exposure contact acute important 4. extinguishing media first-aiders treatments immediate health of extinguishing information effects First aid DURETHANE 95-339/01 medical signs/symptoms : : : : : : : : : None Use an Fire4ighting give suspected No No action specific The In of attention No specific redness irritation Adverse wheezing coughing respiratory Adverse No specific No known May cause symptoms Harmful if known No symptomsleffects, acute If or Remove personnel. irregular Remove DTM known. removing self-contained that shall exposed and (Section before an or case and warm swallowed, recognized asthma if measures Comp person use 11) or to data. tract data. and fresh B it, mouth-to-mouth be person inhalation symptoms significant inhaled. significant extinguishing measures seek or breathing fumes taken treatment. of special breathing irritation may allergic breathing delayed skin contaminated respiratory agent at wear air. effects skin are effects may medical may Keep May rest. involving need treatment include or difficulties cause or suitable NOT advice cleanser. gloves. clothing resuscitation. apparatus. It present, any arrest person decomposition the difficulties the reaction. if Do and still Do to be critical occurs, Date: Wash may the personal kept under products needed. hazards. inhaled. respiratory hazards. induce immediately NOT shoes. Wash provide at for warm of the if following: use and surrounding contaminated dangerous should medical fire, necessary May show be issue in a rescuer risk irritation. rest. vomiting. and 15 or solvents skin artificial If May United without or not cause this 2019 States fire. clothing to the wear an suitable surveillance symptoms thoroughly respiration thinners. or breathing, person may container Page: allergy with providing If appropriate training. with asthma label. and by breathing for if thoroughly or 48 be soap oxygen Version or aid mask delayed. Keep water 10.02 water to or trained hours. it is 3/13 is in up and Vapors (50 mist. non- mop Wash earth, 4/13 10.02 if suitable breathing from drains or local area source or “For to and material waste from collect see (flammable) alcohol burst. to incident vapor information areas. regulations a sand, Page: is Version of personnel of waterways, training. inert licensed vermiculite local possible dry isopropyl the and Contaminated in distance self-contained may breathing ventilation the without with a mode. confined handling Handling DURETHANE to to avoid use. CO? local to environmental Do that well-ventilated accumulate can adequate the authorities container. If and and the be controlslpersonal Store regulations. have areas. smoking. the other material and smoking low not the regulations Once remnants in or store up. also Remove processed. of component a back. tightly original this measures which, in taken not locked area, Store following See part flash in be is skin should sensitization personal the on product kept in opened to confined Do in container employed of contaminates section is stand or closed in been away should all or ventilation. (see and contamination, or original be minimize problems protective from Section accordance Workers multiple Vapors Date: Wear clothing. Keep be of hazardous. closed or stage let of its containers, unlabeled container to contaminated parts. temperatures: 8 in asthma, local 13). issue with could containers. tightly incompatible 0 for additional clothing wash before component are heavier reuse when or 35’C appropriate Do ingest. (see or rivers, in not several May reached, protection must container should components areas not an not equipment lakes, for exposure prohibited any Do 15 to be in (32 protected and areas use. than travel allergies approved process close regulations. or atmospheric materials from 95°F). information where blending container. Empty respirator sewers, container result carefully hands system, air or allow days 2019 to United a in Use closed Avoid Section to States and read and resealed which (see 8). direct protective this as until alternative when chronic enter Store face the may humidity appropriate and sealed breathing this on or pressurization. or and considerable Section sunlight containers hygiene before material no Safety spread inform drains made Persons further Version Page: kept 10) in equipment resulting retain from ventilation product recurrent with dispose in until vapor the or 5/13 water. ready and dry, accordance eating, is along to reaction a Data distance a is or a is of 10.02 used. a mist. containment upright before in or of any effectiveness ventilation 10.02 to In equipment clothing. Wash safety 6/13 Page: standards. of below ensure some before Version 3/2018). 512018). hours. values respiratory products, period. States, hours. hours. States, absorption Value Average use monitoring determination contaminants checked legislation. process limit and workplace the exhaust 8 (as sensitization Exposure Limit the skin. CN) working workplace. stations be 8 to B limits mg/rn3 (United 2019 through mg/rn3, local dust (United mg/rn3 the ppm to necessity appropriate contaminated sensitizatioq term Weighted protection skin levels. personal, determine for of of States airborne should the United chemical to the 15 0.5 TLV 0.03 0.005 PEL 5 limits, the enclosures, (PPG). May handling end required methods modifications that to potentially out eyewash 1 may required. Potential Respiratory Skin Short Total Threshold Time Use worker process of environmental location, Exposure IPEL TWA: STEL: ACGIH TWA: TWA: OSHA Absorbed TWA: = = = = = = = for exposure equipment made after at remove allowed exposure the process and Ensure issue SR SS TO STEL TLV TWA be and/or be S acceptable Date: protection of to be should documents be engineering thoroughly used to with not abbreviations ingredients control Reference guidance ventilation. filters and should before workstation shields. keep emissions face should measures DTM lavatory be controlslpersonal oUgomers Governmental Limit acceptable this If atmosphere the protective Reference hazardous work or Use other recommended Emissions they cases, will reusing. Wash eating, Appropriate Contaminated contaminated showers Safety Substances monitoring also to limits. or the limits. controls statutory reduce clothing side will to Industrial exposure contains or equipment. national to substances requirements adequate from using with scrubbers. the forearms techniques work clothing close Key Hygienists. Hazardous other ventlation the to and to B biological or with Camp and or product ventilation engineering comply fume necessary hands, smoking glasses Toxic with are Z- only Administration. be Health Subpart 95-339/01 DURETHANE Exposure diisocyanate, Limit Permissible cFR monitoring Peak of Exposure and Maximum conference Safety 1910.1200 measures for 8. name Acceptable American ceiling Fume Internal Occupational Respirable OSHA authorities engineering exposure code name focal protection measures protection 29 protection Product Section Ingredient Vexamethylene hexamethylene-di-isocyanate ACGIH IPEL OSHA Consult Recommended procedures Appropriate controls Environmental controls Individual Hygiene Eye/face Skin = = = = = = = = A C F R z Density Vapor Vapor Solubility (lbs Lower Relative Evaporation (flammable) Flash Flammability Boiling Melting Auto-ignition combustion. pH Odor Odor Material Color point Physical Appearance Section Restrictions Other Body Respiratory skin Gloves Hand Section Product code and point density pressure Decomposition threshold state on name I explosive gas) temperature rate 9. protection gal protection limits upper supports 95-339/01 8. protection : : : : : protection : : : : : : : (solid, Physical : use Exposure DURETHANE ) Closed Insoluble Liquid. and should Persons areas, 9.76 1.17 based Not Not Not >37.78cC handling Not Not Not Not Colorless. noted during at Yes. not respirator. Not exposure particulate Not Not By specialist on performed materials: Personal protection that use necessary. butyl glove worn DTM asthma, of Respirator be By performed involved case breakthrough handling impervious controlslpersonal in available. available. available. available. available. available, available. cup: available. available. available. with air-fed spraying: the Appropriate this rubber Comp following 166.11°C chemical employed history mask. respirators being risks Considering when all the be levels, filter before the that times Characteristic. (>100°F) a and air-fed time task the protective of time the Chemical-resistant, B the footwear product. handling the manufacturers. to gloves (331°F) could respirator. this any equipment gloves the the of and In in any are process product. and the cannot of gloves Date: the for still allergies product selection replaced the should body mixtures, any retaining other and additional be for cold properties parameters of water. in chemical or which skin and by risks be their issue must operations should accurately glove specified products complying protection a this chronic the be 15 by if based involved approved material protective risk or safe than protection be consisting the an a with United May product combination and a selected by estimated. glove 2019 recurrent working spraying, measures several be approved of States is on used. known charcoal in should may based properties. limits specialist on assessment respiratory filter different manufacturer, standard Version or well be It of should the be the Page: for and before substances, should indicates 7/13 ventilated approved task disease selected by selected being different this anticipated the be check should 10.02 a is be water. carbon 8/13 10.02 ingredients. occur. alcohols, hours hours hours Page: Version its monoxide, isocyanates. not Exposure amines, carbon - 4 4 4 - - - States or will 2019 product reactions acids, alcohols. monomeric mg/kg mg/rn3 mg/m3 and ppm g/kg g/kg May this for produced. 8. strong materials: cSt) Dose >2000 >2500 124 151 22 0.57 0.71 hazardous may United arnines following cyanide. be and 15 issue 7 available alkalis, with itself. itself. itself. itself. (>21 use, Female properties related of decomposition measures of and products in sections strong occur Date: the hydrogen cm2fs reactivity mixture mixture mixture mixture Species Rabbit Rat Rat Rat Rat Rabbit Rat - >0.21 agents, reactions nitrogen, mists on on on on listed include the the the the to (104°F)): of stable. conditions may oxidizing products oxides available available available available and data Dusts Vapor Vapor chemical (40°C 0% reactivity B normal hazardous protective (w/w) smoke, information no test no no no from: is exothermic Comp available. (v/v), data specific data data data product fire, to away Dermal Oral Inhalation Inhalation Inhalation Dermal Oral are are are are Result LD5O LD5O LC5O LC5O LC5O LD5O LD5O DTM and Not Kinematic 0% 100 and No The Under In Refer Keep Uncontrolled Decomposition dioxide, a There There There There effects 95-339/01 DURETHANE Physical Stability : : : Toxicological toxicological diisocyanate, : : n- name stability of to decomposition 11. on 9. orrosion 10. hazardous avoid materials code name coefficient: (wlw) toxicity rSection Conditions Incompatible Hazardous products Section Information Sensitization r Product Product Section Partition octanol/water Viscosity Volatility % Solid. Reactivity Chemical Possibility reactions Acute Product/ingredient xamethylene oligomers hexamethylene-di-isocyanate Conclusion/Summary rritation!C Conclusion/Summary Skin Eyes Respiratory Conclusion/Summary I Ingestion Inhalation Ingestion Inhalation Potential Information Aspiration Specific Eye Skin Section Delayed Product Product Eye Skin the Not Skin Not Conclusion/Summary Target Conclusion/Summary Carcinogenicitv Conclusion/Summary Name 11. and contact Over-exposure contact acute on available. organs available. target Hexamethylene target sewers. dispersal recycling licensed local requirements product, generation spilled available. should solutions waste Comp information protection and waste authority or rinsed is packaging unless Care of B applicable of of Not No. of out. should not Not fully Section regional, Empty feasible. be Disposal Supplemental elements Hazards classified Section Substance/mixture Product I Potential Ingestion Eye Inhalation Skin Inhalation Eye contact anything POISON Over-exposure Most ingestion, Ingestion contact r Inhalation contact in Skin imoortant codes Eye contact cumene crystalline oxide Solvent contact titanium Description this Solvent There If Any Section SUB Occupational Product section. concentrations Product zinc ethylbenzene 2-butanone rlc 1 heptan-2-one Ingredient Section by are not acute of mouth no silica, naphtha dioxide naphtha name health code an any exposure additional shown represent ,2,4-trimethylbenzene containing to CONTROL irritation, concentration oxime name 4. 3. effects first unconscious aid limits, a substances necessary CENTER, type First (petroleum), applicable, as (petroleum), asbestiform respirable DEVGRD 00407035 of No Way No svmntoms/effects. or ingredients range medium are PRMR signs/symptoms aid or if powder light coughing respiratory specific known Defatting cause known personnel. or to at person If use measures convulsing available, classified EMERGENCY overexposure aliph. without aromatic (>10 fibres WH apart is and warm swallowed, if measures as present protect microns) to Adverse acute Remove irregular Remove for Remove or to symptoms data. ROOM and seek recognized fresh least contact symptoms 41 registered tract the person. OR are 60-1 significant skin. respiratory significant delayed skin contaminated air. listed which, 000 effects May effects medical Keep minutes PHYSICIAN to within confidentiality Compositionlinformation at 10 irritation may of rest. respiratory lenses, hazardous CAS in include or cause irritation. or cleanser. clothing arrest irrigate overexposure Section the or Do on the and health is NOT advice person and Numbers. critical skin critical occurs, seek immediately: occur or due Do Date: 8. induce NOT warm shoes. copiously have current during to the of solvents skin artificial If rest. clean, Data persists knowledge hazards. dryness vomiting. ingredients and hazards. immediately use provide with following batch - Wash - immediate Safety and issue or <1.0 <1.0 <1.0 51.0 .0 .0 5.0 5.0 5.0 at 1 1 % 10 20 5 and thoroughly respiration of - September - show of not medical after sb 1 16 50 material without container. water-insoluble, without (sewers. of Inform suitable ventilation. smoking be 8 made when and if waste if proceed courses, explosion-proof explosion-proof shall 60-1 as not and the retain tools. a as Section ventilation. Section material other original Section diatomaceous skin spillages until Use place Use has with (see area. take and up area. breathing Shut without product contact also spillage, 1 all for absorbent with upwind. United Exposure asbestiform (petroleum), (petroleum), 00407035 DEVGRD hygiene safe exoosure materials: Date: >0.21 to strong materials and reactivity cm2ls cold properties in to may of acids. use, (>21 sections prevent produce available water. issue strong hazardous this 7 cSt) 5 and for United hazardous 8. September States exothermic reactions product 2016 or will reactions: decomposition its Version not products. ingredients. Page: occur. 8 9/16 carbon 10/16 Version monoxide, 8 Exposure hours Page: - 4 - - - 4 - - 4 - - 4 - 2016 carbon States mg/kg mg/I g/kg mg/m3 mg/kg mg/kg mg/m3 mg/kg ppm September materials: Dose 3.46 8400 >16.7 10.206 1.6 >11 18000 5 >3000 >5000 39000 12.3 1400 930 4000 17.8 3.5 glkg 9/kg g/kg g/kg mg/kg g/kg g/kg g/kg United 5 following itself. itself. itself. itself. itself. itself. itself. issue Species Rabbit Rat Rat Rabbit Rat Rat Rat Rat Rabbit Rat Rat Rabbit Rat Rat Rat Rabbit Rat mixture mixture mixture mixture mixture mixture mixture of Date: include the the the may of nitrogen. the the the on on on on on on on 000 products oxides available available available available available available available 41 reactivity Dermal Oral Inhalation Dermal Oral Oral Inhalation Oral Dermal are Vapor data data data data data data data 60-1 smoke, information no no no no no no no WH Decomposition dioxide, Oral Inhalation Dermal Oral Oral Inhalation Dermal Oral 00407035 DEVGRD are are are decomposition are are Toxicological toxicological are (petroleum), and Result LD5O LDSO LC5O LD5O LD5O LD5O LC5O LD5O LD5O LD5O LC5O LD5O LD5O L050 LCSO LD5O LD5O There There There There PRMR effects : : : Stability name ‘10. 11. on code name oxime toxicity naphtha aromatic dioxide naphtha aliph. Product Product Section Hazardous products Section Information Acute Product/ingredient Solvent light heptan-2-one titanium 1,2,4-trimethylbenzene Solvent medium cumene 2-butanone ethylbenzene Conclusion/Summary Irritation/Corrosion Conclusion/Summary Skin Eyes Respiratory Sensitization Conclusion/Summary Skin Respiratory Mutagenicity Conclusion/Summary Carcinogenicity Conclusion/Summary Classification L I Potential cumene Solvent Solvent Name Skin Eye Target cumene Solvent Name Specific cumene Solvent 1 Solvent Name Specific Talc! Product Product Inhalation health Information Aspiration ,2,4-trimethylbenzene not toxicity cumene powder crystalline titanium Product/ingredient LSection contact acute on ethylbenzene naphtha naphtha organs ethylbenzene naphtha target naphtha target Disposal Supplemental elements

Disposal

One A Add States to note an or and when take with has Dilute with of considerable Approach personal The positive 2019 the equipment. also area. absorb area. as the without unprotected Avoid (5 the United follows. sand, according spilled parts). 13 for ethanol any equipment in and material. respirator spillage. See contact product Section container container. parts), May and materials: occur travel from the and Dispose the basements e.g. disposal the absorbent or (95 and in decontaminant. (45 solution water a following persons protective 15 from courses, proceed material for waste risk spill as areas all involving protective operated personal unnecessary spilled appropriate deal materials. runoff air). water-insoluble, container. water plant licensed place suitable a suitable water if issue will or with or and of the taken any Date: and increase authorities or include container a same information removing be procedures and Keep through face-piece Wear ammonia personal parts) unsuitable containers soil containers in a absorbent in or disposal non-combustible, sewers, with via the (5 with earth Place volume): 0,880) to if pressure may shall appropriate full involving required material relevant Move waste Move treatment place pose contact 13). confined by walk of (by or low back. a scene action wear areas. with or is and emergency taken the ventilation. appropriate up spilled waterways, into risk. and Dispose (d: may carbonate spillage immediately a products the measures be of in Section touch on comprises Alternatively, entry effluent heated, isocyanate. should and not Put clothing B suitable personnel”. Inform flash cleaning without appropriate without No an non-combustible, 13). emergency collect sodium earth diatomaceous and oxides and cyanide isolate fire. (SCBA) DTM shall surrounding Do In may of Decomposition carbon nitrogen Cyanate hydrogen adequate on (sewers, Promptly there training. Fire-fighters if apparatus if Prevent into equipment Evacuate entering. Provide fire accumulate ignition inadequate. If Section emergency for specialized cleaned or Avoid and pollution oxides Stop if place disposal Stop upwind. spillages spillage diatomaceous (see absorbent Section Contain vermiculite regulations should decontaminant parts) alternative water-soluble. if release action sewers. 8 and an contractor. Section with 1 and material or (see concentrated is Comp measures a dispersal be and protective is containment leak in leak a No : : thermal 95-339101 DURETHANE Fire-fighting arising fire-fighters products actions I substances Environmental Mobility number oligomers additional Product Product Section coefficient Soil/water xamethylene Section pollutant group Section should methods 13. (Koc) in soil Bioaccumulative 12. name code Transport partition information class handling notential 95-339/01 HANDLING DURETHANE shipping 7: be [‘ductIingredient information accordance in name DOT information way. sewer None Not No. - Not jamethylene-di-isocyanate dhsocyanate, identified. AND and safe the via - The Not Ecological applicable. DTM regulated. and with Avoid cleaned when Waste regional this of LogP0 1.08 a environmental and applicable. regulated. employees. national This recycled. with requirements. be BCF Date: be - considerations - material taken compliant any 3.2 8: should - IMDG Section and EXPOSURE runoff protection avoided material Dispose and by-products issue and when containers the contractor. of local and liners handling and Incineration Waste or 6. or laws may or requirements should waste should of 15 Accidental contact its of surplus minimized emptied at May United - Not No. - States Not and retain all landfill all not CONTROLS/PERSONAL some containers must should authorities with container 2019 and disposal Potential release soil. times wherever low be IATA measures waterways, applicable. product be with of non-recyclable and possible. regulated. regulations. that be only disposed legislation comply Version not disposed any the Page: have with 11/13 PROTECTION drains residues. in been untreated products considered jurisdiction. to of 10.02 a in 10.02 are do to which 12113 that tract what Version EXPOSURE) containers know EXPOSURE) Page: 1A product, (Respiratory (SINGLE this closed product 4 Category for 4 1 May EXPOSURE) 3 Category - Category TOXICITY Category Category 2 - 2A TOXICITY Category Sheet 3 States 2019 1A - 1A the in Category transport Category issue Data transporting (inhalation) ORGAN (oral) (dermal) (inhalation) Category - Category - ORGAN - United 15 - always (SINGLE DUSTS irritation) SENSITIZATION irritation) - 1 4 that of TOXICITY TOXICITY TOXICITY TOXICITY Date: Environmental persons exempted Category tract premises: spillage. TOXICITY SENSITIZATION IRRITATION SENSITIZATION 1 or - Category TARGET Ensure Category or if leak Stop emergency containment pollution and Avoid Section If on adequate flares, No entering. 41 Evacuate action No WH explosion-proof away unless mist. special for and use sewers. dispersal or on specialized appropriate Do equipment release or containers non-sparking from Do appropriate e.g. risk. 000 the personnel”. electrical heat, personal adequately ventilation touch instructions taken basements up spilled and from not ingest. understood. cleaning personal 13 spilled clothing or follows. surrounding equipment. Dispose absorb equipment. Wear flames areas. sparks, before according with Dilute relevant material is required protective involving measures product Take for sand, or Move waterways, or in walk emergency residue (ventilating, open ventilated. use. protective confined Approach and is appropriate through any Do of Use compatible not waste product. contractor. to earth, via or the September if States Do handling) container clothing. safety or Wear into emergency material soil, earth note contractor. ventilation vapor all unprotected 2016 information of or suitable off 8). in electrostatic source. not an and Do Avoid may entry spark-proof water-soluble. spark-proof reuse Use any ignition not Version Dispose non-combustible, effluent when areas waterways, 13). not an Prevent personnel training. an caused is in and in mist. Page: equipment. use. ESection coefficient Soil/water Mobility in ethylbenzene 2-butanone cumerie heptan-2-one ethylbenzene Persistence zinc ethylbenzene oxide Fanium ra Toxicity [Section Inhalation Dermal Route [Section Product Product soil dioxide name code methods partition 1,2,4-trimethylbenzene Productlingredient (vapors) 13. (Koc) oxime Bicaccumulative and 12. 11. depradability safe when a the via The 3.15 0.63 3.66 3.63 .98 Not LogP0 Aquatic Acute Chronic Acute Acute Acute Result Ecological PRMR Toxicological name potential name DEVGRD 00407035 1 - Waste regional this of WH way. sewer LC5O EC5O EC5O LC5O 41 recycling licensed local requirements product, generation available. is packaging unless waste halt-life of 150 NOEC 0.017 Care of 0.481 0.17 >100 60-1 not fully to should authority solutions waste 200 mg/I 000 information feasible. be Fresh considerations information mg/I Fresh be and taken compliant any should 5.01 Fresh water environmental material This prQtection and by-products be avoided - 79.43 35.48 - 120.23 BCF Photolysis when recycled. with requirements. water Date: the contractor. of handling Waste Dispose or emptied Incineration requirements should 1Young of Algae Fish 13168.4 6174.6 3693 ATE of issue Lepomis Neonate Daphnia Daphnia Species mg/I mg/kg value - and its container 5 and disposal waste September - or - should the mg/kg at United landfill all not all of surplus minimized year Daphnia times low low low low low be States containers must should that only authorities disposed legislation comply wherever be Potential macrochirus Readily magna 2016 - disposed any the have be with of non-recyclable and with possible. Version jurisdiction. to Page: not of Biodegradability 96 72 48 72 48 8 131161 been in considered untreated products hours hours hours hours hours Exposure a been contact aircraft. as are do 14/16) residues. atmosphere have and PROTECTION or that in 8 they IATA to what Page: Version product runoff measures vessel regulated k9. transportation regulations. release UN1263 PAINT are quantity. 5 by product States and some or explosive unless by 5 know applicable. applicable. applicable. or other not containers retain material September2016 flammable containers closed required L United and transported liquids 3 of III No. Not in the Not Not may spilled laws sizes if liners used of CONTROLS/PERSONAL unless transport a grind highly local S Accidental (petroleum), appear transporting reportable in issue and 6. create dispersal Section 1,2, Liquid,” combustible product transported may or of containers may or cut, Avoid national IMDG aromatic, of 119 than when mark always Date: weld sewers. EXPOSURE the naphtha gal) persons and applicable. applicable. 8: that spillage. Empty drains employees. residues internally. regional, of Section not equal sizes required UN1263 substance PAINT 3 user’s Ensure III Yes. (Solvent light to 4-trimethylbenzene) Not Not “Combustible premises: less or Do as out. or 000 and 60-1 rinsed product container. waterways, not accident than package within secure. an WH considerations cleaned Vapor inside cleaned with with STORAGE and is Transport upright the or thoroughly 41 of protection from the applicable soil, DOT re-classified in mark hazardous (less and be event PRMR applicable. packages may pollutant AND materials accordance information UN1263 PAINT 3 class Ill No. Not 10688.7 (xylene) product marine environmentally user 00407035 DEVGRD 13. handling shipping information in HANDLING This Non-bulk hazardous The The regulations. for be 7: (Ibs) code name should Section group pollutant RQ Refer for [14. UN UN na Transport (es) Environmental Marine substances additional Product RO number proper Additional me DOT IMDG PATA Packing Special substances to Transport I SARA (>10 aliph. and WARNING: California be Additional copying ethylbenzene 2-butanone microns) Supplier SARA heptan-2-one cumene crystalline Solvent SARA United United titanium aromatic Solvent

Precautionary statements

Accidental materials responders for code name hazards chemical protective non-emergency and provisions 5. 6. Product Product Hazardous decomposition Special for fire-fighters Special equipment Section Personal For personnel Small Large for Special [Section Specific from Environmental Methods spill the emergency For Control including Advice Special Product Product Section OccuDational Conditions any on for occupational Protective Precautions [iction Section name code parameters safe general measures safe 8. incompatibilities for 7. 6. exposure hygiene 95-339/01 Exposure Accidental limits prevent for entering drinking food cool with handled, Eating, Store mixture Sheet(s) floors. measures. source Vapors product not of history on compatible inadequate. and Use Do get respiratory Put appropriate according an DTM drink. between eating and stored drinking may for this may residue with in skin watercourses. to unsealed decontaminant B release Comp will and and local only If of be formed, should leakage. Containers the have ignition and material, Keep eyes disease appropriate States States 3021304 304 311/312 obtained Product 14. IMDG IATA Special United United SARA No SARA Name The ‘ described respect Key Date: to The and of risks. Health National Personal service preparer Caution: Health Product Fduct * ) of recommend information . Disclaimer Indicates MSDS may the is Chronic Hazardous Organization Fire customer mark Although HMIS© [iction code properties precautionanj contained information abbreviations issue Protection are this to information in previous effects name that choose role the OF intTnoarnmoof tha CONVERSION s%w.pnobuQhpa!nts.000, and ty aatheo weld Cf curare c1uehy EXPLANATION AVAILABILITY an recommended US. pmdnaz TO of coT PRO Spontanoote use n up OR DATA hI mao valid to wperq tissuE mm altemative is is p°tduce only. 20 Dry 2.0 for a 50 iFCwDe yme,hadcocteorm may data sometimes and to addeanol catch d, limpasdin 4160 DATA Protective lao speltaln thinners relative touch Blwee°s Weff) &the product for (51 faltre AND pm) PIle & household humidity re* BmW, INESFAPA see em m cli THE HEALTH SHEETS sheet Marine infoerow000 Im aeril ONLY of necessary cogy 000s use WIHO1LJMFrAT1ON. is to nna-caooftetsrte oIthedStred MIY WAFRANTIES speoficatoss SAFETY, 50% comply to Coatings e,dirardmL INFORMATION used. or OTHERWARRANTY or 1 Dry deOec a 11451 such hour bat PRO with kmt,ediaft hard nelMed silo progict supply after SHEETS Page4/5 NiceSt OF eeant)aeer MMBSAND effect EXPLOSION local the use. snea bar than FUNESS ALL ttoe or peeca 1430, at same rags Riyer ECOSA OTHER ol 1431 rifle Item enpitaber - national meelwoof pecoee PAR11CELAR ON LXRthSS mmelacsre product and on orwasteN of aider relevant p11 a ices June PUPROSE a sealed the USE,ARE IMPIJEDWARNSNflES. pcoa.,tshaq waTenoy theteeflffaleef INFORMATION rules/circumstances. worldwide ON thautha Material watarteed 3,2016 Bringing PPG tom DISCLAIMER STATUTE ddwered SHEET Under meed lna produ IJNDEII (Revision basis. Safety be or Marine Data year BY tma Anj the Roter to Protective these However, dam twin of PPG slight ON of innovation to ARISING lighted Sheets Be January dae caSt the Coatings & surfacc undaneis OTHERWISE aooj 04 1431 1430 1411 1410 the 18,2016) a? IN 2016) no set loss surface: bt’eIe woothen knon6eO)e has from an 0 January18, OCS€QLO4ThJ. 090 ta Coatings innoornion & the flat pecdja c raqiofa eocaarq nooLtraited PPG 090 resdts to of of Ievna eta, eamaçe .ooaInbcrnby Protective Cot tests aM ala the COJTAL bboram none bait .sy aloe Ptde.cta PPG Marine Stinging Pr IniC Ofl In tot sole nay is Sea SPCAL. S troop Malipecodena, (Revision bed demo dttned so. am ci data at S 32016 O’SUQqeSAOOa rfranmon So45d ae.rrepote P,onacsee t inca & IEdCT. Only lees cirad tfllca aebity June FGANV rdaled tier ci &. 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GA reSpGf SHEET AV contned apedec tdanei’a mewitne F_re foe cow strait of sad Sit sheet LIABILITY PE.S.NG gtcgmsiao nit coMai bathe E a ate of 9.doss sad nods to ii kits DATA OF a TE.AISC the it reOssy 5-gallDn suMAc, or E,E ventilating, Take smoke (or Large Small Methods spill and Environmental For Personal Product personnel Product For Section materials non-emergency precautions, DEVGRD 00407035 name code for 7. emergency 6. measures safe handling responders protective Accidental PRMR for Handling alternative Empty read only and spaces respirator vapor been obtain Put on information and absorbent same licensed container plant water Stop leak contact pose of place tools appropriate tools “For inadequate. approved confined exposure into from 8 Use appropriate breathe have - the via and environmental drains non- in Provide sources. 51161 Store a treatment sewers, waste information Put container. discharges. Alternatively, in along To should eating, before with Eliminate to are avoid have a containers outside. for may dust 6/16 container closed which Sheet(s) carefully distance spread later. stored before from up. tightly containers. Respirable 212013). not Total is Page: 8 purpose-built and Safety 5). area, container unlabeled Version may States, clothing, hours States, be States, hours. this face States, hours. on States, in away States, hours. locked must States). materials Data mixture material Form: equipment hygiene Form: accordance original Form: 3/2015). 3/201 2/2013). be 212013). 3/201 312015). considerable air day the resulting where protective Store hours. States in and some in and Store in a protective 8 8 8 the hands and information opened Keep 8 than and hours. stored Contaminated (United read as 8 8 areas 8 hours. area. drink. 8 been store contamination. 8 (United 8 (United mg/m3 (United mglm3 ppm (United (United (United mg/m3 (United United travel (95°F). limits Z3 self-ignite be lids. working SSeptember20l6 mppcf asbestos heavier wipes ppm system, mg/rn3 mg/m3 clothing ppm 35°C well-ventilated have TLV 2 in PEL 20 TLV 233 50 PEL 465 100 15 TLV 10 TLV 123 PEL or not 25 TLV mg/m3 wash and areas should blending confined Vapors rags! approved spontaneously and materials food materials. the component that temperature: 10) oxidizing each additional Do issue paper self-closing end prohibited 8 are and of environmental should for ACGIH fraction OSIIA containing None. ACGIH OSHA Exposure ACGIH TWA: ACGIH TWA: ACGIH TWA: TWA: TWA: TWA: TWA: before be cool leakage. dry, low back. flash as product tight-fitting, with workplace of or a components parts. should Remove See following in segregated in Section (see from prevent to Dateof at Workers contaminated Section avoid protection or may Containers a cleaning multiple also use. to contaminated its smoking processed. sunlight Separate upright a in 60-1 for accumulate ignition fires, containers from component of smoking. above materials sources. until kept the and such all the part of Store containment 000 41 storage may of Materials and and metal areas. material general for containing naphtha dioxide naphtha 7. 8. name ctcode name any , on parameters not Pro duct [!ection Special Advice occupational Conditions including incompatibilities Section Control Occupational Ingredient rlc Solvent heptan-2-one titanium 1,2,4-trimethylbenzene Solvent I Consult cumene Product — OSHA IPEL ACGIH local ethylbenzene 2-butanone zinc Z R F C A crystalline oxide Section = = = = = = = = OSHA Internal Fume ceiling authorities CFR Occupational Limit name code 29 Respirahie American Acceptable oxime silica, 8. Safety Permissible Conference Maximum respirable DEVGRD 00407035 1910.1200 Exposure Peak Exposure for and Subpart Health of powder PRMR Limit Substances abbreviations exposure and Administration. Industrial acceptable - controlslpersonal Governmental microns) (>10 WH Z Toxic 41 limits. Hazardous Hygienists. Key 60-1000 to Date: of STEL IPEL TWA TLV TO SS S SR = = = = = = = TWA TWA OSHA TWA ACGIH STEL TWA TWA: TWA: OSHA TWA ACGIH TWA OSHA issue TWA: ACGIH TWA: TWA: OSHA fraction TWA: STEL ACGIH TWA fraction TWA TWA OSHA TWA TWA OSHA TWA: protection 5 Time Total Short Skin 100 435 PEL TLV (PPG). 245 PEL TLV weighted Limit PEL Respirable 0.025 20 sensitization TLV Respirable 250 Respirable 9 3 50 Absorbed 50 30 PEL 400 100 PEL 400 10 2 Respirable 15 5 5 15 TLV(United Threshold dust Potential ppm ppm ppm ppm Z3 PELZ3 mg/m3 mg/m3 mg/rn3 Respiratory skin 8 (United (United United through (United (United mg/rn3 mg/m3 (United mppcf/ mg/rn3 term fraction 8 mg/m3 (United fraction September mg/m3 mg/m3 8 ppm States Exposure hours. skin. hours. Form: (United 8 (United hours. 8 hours. hours. hours. 8 10mg/rn3 8 8 / 8 Average Value limit sensitization absorption 8 hours. States, States, States). hours. States, (%S102+5) States Total hours. States, Form: (%Si02+2) States, Form: Form: minutes. States, hours. States, hours. States, 8 2016 Form: values 2/2013). 3/2015). 2/201 3). 3/2015). dust Form: 3/2015). Form: 3/2015). Fume 2/2013). Version 7/16 8 Page: Form: Respirable dust Respirable hours. 2/2013). Total 8 Form: or standards. ventilation ensure some equipment clothing. and of should any task wear clothing is selected the If complying be Page: a safety this the by being anti- 8fj be of 8 before below gas, check different workers effectiveness keep Version workplace respiratory indicates should exhaust explosion-proof the before products, to In period. be approved stations use appropriate, monitoring determination standard different contaminants substances, need checked legislation. process for should manufacturer, be based specialist electricity, discharges, respirator. respirator necessary. to It on be levels, the use the also chemical working assessment properties. several 2016 a static local exposure must is Use be personal, determine States appropriate for airborne limits. should the eyewash approved glove should may of selected by static measures and selected they air-fed this to the contaminated gloves: September limits, enclosures, handling end with protective to material estimated. approved involved anticipated of necessity to controls protection levels. required methods to explosive a the modifications the Ensure from of that consisting the an risk ignition type from indicates or United to potentially if by issue exposure be be and)or be process exposure limit, lower acceptable remove of products specified may engineering made protection for environmental to exposure air-purifying equipment location. complying after mixtures, their glove body should 5 risk following should of known be the gloves. protection risks limits or at with should required. worker any process used reusing. retaining for be use and on working the fitted, assessment and skin the and to any accurately Use Date: protection measures documents be engineering a thoroughly lavatory be The the gloves chemical of and safe is of the greatest boots controls keep statutory below requirements reduce emissions face using clothing the before side impervious parameters gloves to breakthrough case cannot gloves ingredients equipment control Reference there guidance and ventilation. must based Use filters and should workstation shields. handling the work rubber or involved When For overalls, any performed a still for monitoring the also additional product. to limits. above risk or the are handling, this be the properly if a will and In 000 biological other ventilation the to and when the repeated nitrile clothing. handling to standard risks being contains or national adequate or concentrations forearms with the time of or the anti-static product concentrations 60-1 equipment. to substances equipment. from times Considering that the time and footwear selection the or with scrubbers, WH controls/personal this techniques If atmosphere the close ventilation protective Reference hazardous product recommended vapor ventilation Emissions they cases, will 41 only be engineering or product. comply Appropriate Wash showers Safety task with to dust Chemical-resistant, worn necessary. during noted glove protection For hands, contaminated prolonged Recommended: use Personal performed handling static should Appropriate based specialist Respirator hazards are that are manufacturers. exposed protective an on protective this the before respirators. fume necessary smoking glasses all include of approved at Use other Wash eating, certified with PRMR Exposure monitoring measures : : 00407035 DEVGRD exposure protection engineering protection measures protection 8. Product Product Section Recommended procedures protection Gloves code name skin Appropriate controls Environmental controls Individual Hygiene Eye/face Skin Hand Body Other Respiratory I Incompatible Conditions reactions Possibility Chemical Reactivity Section % Solid. Volatility Viscosity Partition Solubility Density Relative Vapor Vapor Evaporation (flammable) Lower and Flammability Auto-ignition combustion. Material Flash point Boiling Melting Odor Odor Color Physical Aopearance pH Section Product Product ( materials density pressure coefficient: of Decomposition octanol/water threshold lbs state name point code to avoid stability 10. (w/w) lgal) limits upper (solid, supports rate 9. explosive temperature Stability Physical hazardous gas) temperature n- DEVGRD 00407035 No PRMR : : : : : Refer When Under and : : : 71.755 11.93 Upper: Lower: Keep away Closed White. Liquid. The specific and WH 48% (v/v)1 Kinematic Not Insoluble 1 .43 Not Not Not Yes. >37.78°C Not Not Not normal product available. available. available. available. 5.85% 1.03% available. available. available. available. available. available. oxidizing Characteristic. to 41 in cup: agents, from exposed test protective to (40°C the is 28.245% 60-1 42°C (>100°F) the conditions stable. (w/w) (104°F)): data following (107.6°F) chemical 000 strong high reactivity alkalis, following measures of listed temperatures related Product Product Section open smoke (or of of Avoid when safety sparks, PRODUCT SEALED tools. comfortable regional, irritation death. fumes or electrical, eat, concerned: keep IF water contact cool. local, causes toxic WITH WASTE irritation. or SKIN shower. exposure. headaches, all eye THIS IN closed. drink ON medical Inhalation States or 2016 until May Wear surfaces, Get all repeated cause handle hot DISCARDED. non-sparking tightly not or and Do issue air unwell. with Remove Keep with may damage. limits Emits SOAKED OR cause explosion-proof vapor. to United exposure unconsciousness handling. child. or gloves. fresh feel skin persists: WOOL I unborn from Use after you Rinse minutes. not to WASTE heat, only container skin handling. exposed place. system and Do IF of Date: prolonged away Use Keep breathe unwell. person several irritation accordance concentrations nervous lead after IMPROPERLY STEEL if the use. protective OR IF dry fertility equipment. Do discharge. you Remove container brain recommended and thoroughly in dizziness. through before Keep smoking. thoroughly for vapor clothing. If WOOL and or may eye Wear not feel physician well-ventilated may FIRE RAGS, vapor. irritation. cancer. organs No hands if water rinsing. high the CATCH PLACE contact or a or damaging causing in instructions understood. sources. Wash attention INHALED: CENTER contaminated regulations. above nausea USE, CONTAINER. repeated static area. and to of of drowsiness STEEL and 4308-0100 against Continue serious

Teratogenic Effects

Reproductive Mutagenicity Respiratory name code immediate toxicity hexamethylene-di-isocyanate dhsocyanate, signs/symptoms toxicity health likely of organ DURETHANE 95-339/01 organ toxicity effects : : : : : : : : effects routes also redness irritation Adverse asthma wheezing coughing respiratory Adverse known symptoms Harmful known Reproductive carcinogen ethylbenzene (>10 silica, dioxide 11. name code the likely organ containing organ Not OSHA: NW: IARC: Conclusion/Summary listed!not Known 2A, microns) DEVGRD 00407035 I, + effects (petroleum), (petroleum), (petroleum), toxicity (petroleum), toxicity to 2B,

Potential health effects

Ecological dhsocyanate. degradability name low dhsocyanate, known known known known known DTM Once very No No No No No Result Aquatic effects toxicity : : Acute Acute Acute - Product Product Section Conclusion/Summary Short Potential effects Potential Long Potential effects Potential Potential General Carcinogenicity Mutagenicity Teratogenicity Developmental Fertility Numerical Acute Route KhaIation Inhalation [!ection Toxicity Productlingredient Pxarnethylene oligomers Persistence Product/ingredient Pxamethylene oligomers effects code name effects of exposure immediate mists) delayed exposure immediate delayed name chronic effects measures (vapors) (dusts and 11. estimates 12. term toxicity DOT es) UN Additional Marine name for Packing Transport 14. proper Refer ( to of code name delayed chronic effects measures contact term toxicity contact Product Product and Section Ingestion Over-exposure Eye Inhalation Skin Ingestion Delayed Conclusion/Summary Short Potential effects Potential Long Potential effects Potential Potential General Carcinogenicity Mutagenicity Teratogenicity Developmental Fertility Numerical Acute I represent acid, (petroleum), first CONTROL type aid limits, a zirconium (petroleum), signs/symptoms symptoms/effects, If substances aid range salt hydrotreated Never as pain Can apart ingredients medium GLOSS are Causes person use give of anything CENTER, without heavy : : : : : : to : : warm swallowed, or to at measures overexposure as present if : : or redness watering Adverse cause Defatting dizziness. cause

2.1 Classification of the substance or mixture

COMBUSTIBLE ACUTE SKIN SPECIFIC (Respiratory ACUTE ACUTE ACUTE SKIN EYE RESPIRATORY SKIN SPECIFIC (Respiratory on - or listed the user’s (inhalation) ORGAN 3 accident SENSITIZATION are - within of secure an contained B Comp event information All applicable TOXICITY SENSITIZATION and components TARGET Category is information None None for found. - Transport upright the DTM % 90 <1.0 Not representative. 95-339101 DURETHANE Regulatory dhsocyanate, environmental from Sb) ingredients ACUTE RESPIRATORY SKIN SPECIFIC irritation) ingredients identified. identified. on information PPG user (TSCA your Transport Section Comoositign/information products Composition/information Wexamethylene oligomers hexamethylene-di-isocyanate Additional can be : : 15. inventory were RQ code name to No leaving risks, 15 United marine Prevention observe warranty coefficient more and Manual. May program. facility 2019 the or supplied knowledga pollution) Pollution a HMIS® of and 4 States guarantee PPG, The of information Relevant Section Product Other Product Product Version of Date: Manufacturer use type identification means code Section label substance OSHAIHCS Technical Emergency the respirable name routes asbestiform of medium light be a 3,4 lungs, : : : medium light fibres (single There Defatting There Way cause No known regulated: human aliph. aromatic OSHA lens 311/312 Name products 3021304 States States Section SARA name code Product can SARA Talc No 313 not , 304 product from redistribution notifications notification 1,2,4-trimethylbenzene This Prop. containing inventory dioxide DEVGRD 65 obtained RQ oxime silica, naphtha were 15. information notice trizinc environmental medium respirable Delayed Regulatory Composition/information found. Composition/information 00407035 your of must (petroleum), (TSCA Goods partition technical failure No 5 marine to preparer National = or the and the Use Product Product Other Version of Manufacturer Date: use type identification means code Section label substance OSHA)HCS Section Technical Emergency the elements mixture status Phone identified Issue date 7 advised name or of 2. of 1. teleDhone against substance/ uses the system Category TOXIC TOXIC (514) (412) PPG Coating. Industrial substance of Liquid. 00407134 DEVGRD Identification Number May of Date: TARGET CARCINOGENICITY 1910.1200). identification (U.S.) 15272 Inc. applications, mixture SAFETY EYE (29 This Percentage SPECIFIC 3 SPECIFIC TO TO P.AMMABLE One material Not Pittsburgh, Not available. I 2016 of (CNS)) CFR 888-977-4762 645-1320 434-4515 PA PPG applicable. - IRRITATION 01-800-00-21-400 Place Industries, GLOSS or is the mixture Category considered (Mexico) (Canada) Used and - LIQUIDS WH ORGAN ORGAN REPRODUCTION REPRODUCTION Category 2A Category - consisting Category 1 DATA (Unborn (Fertility) by uses hazardous 4308-0100 TOXICITY - by spraying. advised 2 3 of Category SHEET (REPEATED child) ingredient(s) (SINGLE the Category OSHA against - 2 United of States unknown EXPOSURE) 2 (central Communication toxicity: (Narcotic Page: 35.7% effects) 1/161 nervous Standard - 1 or and using and have with nervous lighting and breathing. Takeoff EYES: MAY WATER- 2/16 flames precautionary outdoors when for IN present respiratory contact heated. Page: 7 face ventilating, Take Use Get lenses, attention. protection. only medical IMMEDIATELY A hair): IF if national the vapor/aerosol Version (central Eye Skin Eye Most Skin Eye contact Ingestion If There Any SUB Inhalation in contact Naphtha contact Product Section Occupational Product Product ethylbenzene 2-butanone Section code contact this titanium Wolvent Potential Ingestion Inhalation Description information ingestion, are codes Ingredient a Over-exposure contact acute important of section. concentrations 2-ethyihexanoic dioxide naphtha name no available. POISON irritation, oxime name Substance/mixture 4. concentration 3. necessary any First exposure applicable, additional shown DEVGRD 00407134

HMIS® ratings

16. 3 is of for measures the attention in that has data draw prepared Flammability Equipment for responsible Coatings and based Information Other DURETHANE Protective 95-339/01 the to Material sheet of * American provide ratings any UN BC Flammability or the this them. the on to a GI-IS BCF ATE data EHS as Association (PPE) HMIS® DTM 0-4 No the health sheet changed products. for MARPOL IMDG = IATA 7/23/2018 ratings LogPow = = = = 1 associated rating System misuse modified = = of and United Acute (U.S.A.) codes, determining Association, arc label scale, Comp = 1 is can safety Nations logarithm International Toxicity consult Physical by International of Bulk Air the liability storage Bioconcentration from Instability PPF used Globally the Inc. to are with (U.S.A.) information B based the Intermediate be 0 not and on present of products. aspects previously Protocol the Harmonized on representing the code with required be handling Maritime Factor Estimate accepted of issued 1978. Convention Container Transport System HMIS® MSDSs minimal a 0 for fully concerning scientific for octanol/water of any and version. Dangerous implemented for the this Date: or 0 of the failure product& (“Marpol’ Association partition Goods material. products or Implementation For HMIS® issue = products technical

2.2 Label elements

is 29 representing by under a Page: From precautionary to purpose Ships, on Chemicals CFR HMIS® registered 1910.1200, significant is and Version given of 10.02 13/13 measures this 1973 trademark or in 18,2016) surface products & the SSPC January latex to Protective to Coatings of and cleaning PPG Marine SñnØnginnudon alkyds (Revision tool 3,2016 hand or June conventional SP-3 as SSPC well system 50 as preparation pm) dry with on and for surface accordance Page depending (10.2 stored performance coatings 1/5 from qñ) rn2/l cool the 418 of equipment polyurethane (approx. 64 2.0 when degree give cleaning in urn) mils optimum primer and (50- months will gal for TEMPERATURES the and lb/US mils gal contaminants toot structural to primer piping max. 2.0- 409 intervals or standards power 12 AND epoxy 2% 3.5 2.5 ft2/US 4160 other tank alkyd exteriors, metal time CONDITIONS grease SP-6 practical, with One 51 r east At and proportional tank Overcoating Curing general, SSPC not CHARACTERISTICS SHEET structural topcoated chromate ferrous components free LEVEL spreading (20°C) ADDITIONAL ADDITIONAL performance thickness all blast abrasive requirements is, moisture, acceptable in is steel, on rate DATA DATA — DATA — is to properties GLOSS Red cleaning multi-purpose interior/exteriDr 68°F film SUBSTRATE dirt, blasting AT city Inhibitive for be drying and AND White, rust, RECOMMENDED • DATA product of Steel • • • solids (Supplied) Ref. Pollution September choose coefficient warranty observe and & 4 and issue risks, may Paint

Product definition

DEVGUARD® One-component, PRINCIPAL • • • • • COLOR • • Data Number Volume Notes: - Coating Remove Abrasive Where SP-2 for life Rust deal May Fast Lead Gray, Flat BASIC See See VOC Recommended Theoretical Shelf P170 - ‘ Ret. P110 • Provide • • Ensure good should Application Note: • • Agitate with Inspect the Area Consult • Topcoats: • Primers: SYSTEM 4216 USEPNLead approved exposure (e.g., OR Removal Warning • Relative • • Surface DUST Surface Substrate • • Galvanizing Degrease Galvanizing PRODUCT shelter a top INSTRUCTIONS Direct lead FUMES contaminants HP, to of to DEVFLEX to or paint humidity temperature and SSPC DATA prevent ventilation sheltered old surface 659, metal SPECIFICATION to Information other during be white had SP-1 your that power FOR DEVGUAR MAY temperature has sales by mixer USE and from D4306, and Hotline NlOSHapproved) CAUSE sanding, rust and DEVGUARD® during at wind during for UNIGRIP at hazardous SHEET least airborne representative respirator ADVERSE scraping application 1 remove from —2 remove application 12 affecting minutes any for 4380, and substances and should months any spray particulates application DEVGUARD proper or 4160 until additional UNIGRIP 4308, 1-800-424-LEAD HEALTH other conditions and “skins” curing of white curing requires means should be exterior patterns completely have that EFFECTS, may or at and may 4382, the corrosion topcoat DEVFLEX the not least between formed offerings QD, generate (3”C) weathering products use 5”F pollutants consult 4206 regional containment of exceed 50”F (1 dispersed. Health proper PPG 85% 0”C) and may by on above Ensure top technical DEVFLEX cleanup. ESPECIALLY dust IN or dew and 1 be hand Canada For protective 20”F coated good sales 4208 office CHILDREN fumes point abrasion for aD, (49”C) after which June off-bottom other equipment, power additional OR options DEVFLEX such

Response

rant nc.aro of FrofSe iroralion np the ofUEWraneacc pemocinvnars The ItAISYWAY PR) &cnIai eth’eenm ow Isa aaudeo COIIenTh — and ii L niaymcdrTy O,wnnq 54 GaIt PRODUCT DEVGUARD® LIMITATIONS In. DAMAGES be tedflnd ciii conrad loam atee. y.OEfrnnr m6* remOw WWW[OSC AVAILABILITY 1-gallon Pro Lo2. P170 The Ref. GHS number Uses mixture Use of

Hazard pictograms

elements mixture status Phone identified Issue date 8 advised name or of 2. of 1. telephone against substance! uses the system SPECIFIC - irritation) SPECIFIC (514) Coating Industrial substance Liquid. of 00407035 DEVGRD Identification Number revision of the Percentage AMMABLE (29 This material Pittsburgh, One PPG Not available. 5 September of (CNS)) CFR 888-977-4762 645-1320 (412)434-4515 PA Place Industries, applicable. PPG 3 (U.S.) applications, the TARGET Category TARGET 01-800-00-21-400 or PRMR 2016 SAFETY is LIQUIDS - CARCINOGENICITY 1910.1200). identification 15272 Inc. mixture WH 1 ORGAN ORGAN Category - mixture Category considered (Mexico) (Canada) Used and - consisting Category DATA hazardous by uses 4160-1000 TOXICITY by 1A spraying. advised 3 of SHEET (REPEATED ingredient(s) the (SINGLE OSHA against United of States unknown EXPOSURE) (Respiratory Communication toxicity: (central Page: 60.7% 1116 nervous Standard tract or off have and using and of Avoid when A of lighting 21161 breathing. Take the nervous flames outdoors when crystalline Inhalation fumes protection. IN precautionary medical hair): national spray irritation causes or death. THIS DISCARDED. WASTE Page: 8 for on Version (central

Prevention

name products minimal mark System Dangerous 1978. issued scientific concerning of the (“Marpol” version. 0 the material. of for products. any Date: this of the for Association for 0 code Estimate Factor Transport Container Convention handling accepted 1910.1200, representing 29 registered 327-6868. octanol/water of Air Bulk of Protocol aspects be CFR under Harmonized Maritime the previously present and can products. 000 isa PPE 60-1 on Physical with HMIS@ Instability Toxicity logarithm = International by Nations from 41 based safety (U.S.A.) 2 the scale, MSDSs Keller Acute Bioconcentration Globally International Intermediate = International = is and storage liability 0 (800) the the information HMIS® for has products. of System rating determining 711512016 EHS IMDG LogPow MARPOL as UN changed modified sheet health for WH .J. 2 on program. = = = United the No misuse J. (U.S.A.) = 0-4 from ATE BCF GHS IATA BC any PRMR on not this Information Flammability a required are exclusively Association Flammability that data in the measures the : : to for 00407035 DEVGRD Other fully purchased is responsible Protection are issue ratings implemented prepared contained draw properties data attention sheet based or of Although used customer abbreviations code name Material of effects be information is precautiona,y * this 16- ratings HMIS€ a that 2 to HMIS€ with may Fire : previous the in Chronic MSDS to information Product Product j Hazardous Health Section Caution: risks to materials The National Health Date Organization the Key Disclaimer The information recommend respect described of - ) be Indicates * ‘ I GHS number mixture of Product Relevant Uses

Product information

thinners. advice. water, hence this CAS 2016 1 soap oxygen the available. require in 100-41-4 14808-60-7 if 3-2 64742-88-7 or 13463-67-7 0-43-0 64742-95-6 14807-96-6 Version and 96-29-7 98-82-8 Page: 314-1 95-63-6 breathing number is label. eyelids and by Never contact the 8 3/16 Keep water trained a give reporting with or to occur source waterway, aid water incident suitable water and Page: with 4116 is mask This breathing if it of If training. providing will 8 hazard. the without mode. large may any Use Version appropriate Vapors contaminated person of thoroughly risk. self-contained if a immediately wear to clothing the to explosion discharged without and or 2016 suitable increase distance water vicinity pressure an States risk pressure fire being materials: from personal positive United without explosion. Fire done or September the specialist should a any necessary dangerous foam. or a create effects. from can be issue in rescuer contaminated or 5 heated, treatment subsequent may personal the may following risk this travel considerable all involving cool. protective equipment if be persons needed. inhaled. Wash if sewer long if taken a area of lasting operated following: or the gloves. (fog) of or prevented containers Date: face-piece the poison any It fire risk spray areas to and with include removing be fire a or present, In the still include treatment Contact life involving apparatus. by from water with Runoff may shall appropriate full ingested are resuscitation. wear vapor. may confined contained taken or C02, burst, or aquatic be a scene action wear with 000 WIl measures specific special attention been specific action be fumes suspected breathing self-contained give before mouth-to-mouth jet. and back. not Flammable the accumulate ignition material this sewer Decomposition carbon carbon phosphorus metal may container low material the products Promptly there training. spray Fire-fighters apparatus No containers fire-exposed it, to 60-1 symptoms data. and have treatment. shall that water toxic drain. isolate (SCBA) liquid in flash must oxides should removing 11) 41 use and dioxide monoxide oxide/oxides afire. chemical, is Move keep symptomatically. Adverse irritation dryness cracking No measures Treat quantities No No or Use Do dry is to PRMR (Section aid : : : : : medical 00407035 DEVGRD immediate first-aiders First media extinguishing information Fire-fighting thermal arising fire-fighters products actions code name contact of physician treatments extinguishing hazards chemical protective 4. rProduct [oduct 5. Section Skin Ingestion Indication Notes Specific Protection Section Extinguishing Suitable media Unsuitable media Specific from Hazardous decomposition Special for fire-fighters Special equipment of for to toxicological the See Protective [Section

2.3 Other hazards

drinking direct ready store regulations. sealed appropriate aliph. with is all of stored and eating from and WH risks in removed not ignition and Vapors source floors. contaminated the or be If the the Eating, handled, drinking entering measures. Do local protected incompatible all and resealed Use fibres this controlslpersonal aromatic PRMR limits Handling light medium

Health hazards

chronic) Delayed 2016 the product, Version SDS 0.1 0.5 - 0.5- 3-7 Page: shall 1 1.5 1.5 15/16 which Concentration 8 include or are to given measures ratings HMIS of 1973 this in 16116 8 HMIS® (NPCA). Chemicals Ships. purpose and Page: Version significant them. From is The PPG, precautionaiy of representing 2016 provide Association by guarantee States Coatings of pollution) knowledge. supplied United or the to