Note: Ingredients listed on restricted chemical lists
General Information
Revision date
2000-05-04
Product name
TILE-CLAD High Solids Enamel (Part B), Hardener
CAS No.
100-41-4
Manufacturer Name
THE SHERWIN-WILLIAMS COMPANY
Emergency telephone
(216) 566-2917, (800) 424-9300
Icons in SDS
Company Information
company name
THE SHERWIN-WILLIAMS COMPANY
GHS Information
Signal word
WARNING
Section 2
Principle Routes of Exposure
INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. Continued on page 2 B60V2Z70 page 2 EFFECTS OF OVEREXPOSUR: EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. ( INHALATION: Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure.
Medical Conditions Generally Aggravated by Exposure
BY EXPOSURE May cause allergic skin reaction in susceptible persons or skin sensitization.
Cancer information
For complete discussion of toxicology data refer to Section 11. EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. If irritation persists or occurs later, get medical attention. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. FLASH POINT LEL UEL 82 F PMCC 0.7 7.0 FLAMMABILITY CLASSIFICATION RED LABEL Flammable, Flash below 100 38 C) EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat Application to hot surfaces requires special precautions During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent Obtain medical attention SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used Water spray may be ineffective If water is used, fog nozzles are preferable Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat Continued on page page STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition Ventilate the area Remove with inert absorbent STORAGE CATEGORY DOL Storage Class IC PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are FLAMMABLE Keep away from heat, sparks, and open flame During use and until all vapors are gone Keep area ventilated Do not smoke Extinguish all flames, pilot lights, and heaters Turn off stoves, electric tools and appliances, and any other sources of ignition Consult NFPA Code Use approved Bonding and Grounding procedures Keep container closed when not in use Transfer only to approved containers with complete and appropriate labeling Do not take internally Keep out of the reach of children PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation Avoid contact with skin and eyes Avoid breathing vapor and spray mist Wash hands after using This coating may contain materials classified as nuisance particulates listed as Dust" in Section which may be present at hazardous levels only during sanding or abrading of the dried film If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV mg/m3 total dust), mg/m3 respirable fraction),
Contains
can be harmful or fatal. Continued on page 4 B60V2Z70 page 4 PRODUCT WEIGHT 8.75 lb/gal 1048 g/l SPECIFIC GRAVITY 1.05 BOILING POINT 277 - 360 F 136 - 182 C MELTING POINT Not Available VOLATILE VOLUME 42 % EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air SOLUBILITY IN WATER N.A. VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) 3.06 lb/gal 366 g/1 Less Water and Federally Exempt Solvents 3.06 lb/gal 366 g/1i Emitted Voc STABILITY -—- Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur
Health hazards
Ethylbenzene is classified by IARC as possibly carcinogenic ‘to humans _, (2B) based on inadequate evidence ( in humans and sufficient evidence in laboratory animals. to high Lifetime inhalation exposure of rats and mice ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans. Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary and reproductive systems. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. TOXICOLOGY DATA Continued on page 5 page 5 CAS No Ingredient Name (, 100-41-4 Ethylbenzene ( LC50 «RAT 4HR Not Available LD50 RAT 3500 mg/kg 1330-20-7 Xylene LC50.-RAT 4HR 5000 ppm LD50.~—s« RAT 4300 mg/kg 64742-95-6 Light Aromatic Hydrocarbons LC50 RAT 4HR Not Available LD50 RAT Not Available 108-67~-8 1,3,5-Trimethylbenzene LC50 RAT 4HR Not Available LD50 RAT Not Available 95-63-6 1,2,4-Trimethylbenzene LC50 RAT 4HR Not Available LD50 RAT Not Available Proprietary Epoxy Polymer LC50 RAT 4HR Not Available LD50 RAT Not Available
TOXICOLOGICAL INFORMATION
No data available. WASTE DISPOSAL METHOD Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. — ‘ Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. Incinerate in approved facility. Do not incinerate closed_container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION CAS No. CHEMICAL/ COMPOUND % by WT % Element 100-41-4 Ethylbenzene 3 1330-20-7 Xylene 19 95-63-6 1,2,4-Trimethylbenzene 5 Continued on page 6 B60V2Z70 page 6 CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State of birth defects or other reproductive California harm. to cause cancer and TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, and assume we make no warranties, express or implied, no liability in connection with any use
2.1 Classification of the substance or mixture
RED LABEL -- Flammable, Flash below 100 F (38 C) EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Continued on page 3 page 3 ( ™ STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED ( Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. STORAGE CATEGORY DOL Storage Class IC PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Contents are FLAMMABLE. Keep away from heat, sparks, and open flame. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 os, (total dust), 5 mg/m3 (respirable fraction). VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. EYE PROTECTION Wear safety spectacles with unperforated sideshields. OTHER PROTECTIVE EQUIPMENT Use of barrier cream on exposed skin is recommended. OTHER PRECAUTIONS This product must be mixed with other components before use. Before opening the packages, READ AND FOLLOW WARNING LABELS