LOXON Concrete & Masonry Primer/Sealer White

Hazard statements (CLP)

H350, H372

Code

Statements

H350

May cause cancer

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 1 Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 9.2% Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 9.2% Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 9.2% GHS label elements Hazard pictograms g Signal word : Danger Hazard statements : May cause cancer. Causes damage to organs through prolonged or repeated exposure. Precautionary statements General > Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear Protective gloves. Wear eye or face protection. Wear protective clothing. Do not breathe vapor. Do not eat, drink or snoke when using this product. Wash hands thoroughly after handling. Date of issue/Date of revision :8/24/2019 Date of previous issue 14/17/2019 Version Lxo2wso LOXON® Concrete & Masonry Primer/Sealer :5.04 12 Section 2. Hazards identification Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. Storage + Store locked up. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Supplemental label elements WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure. Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Hazards not otherwise + None known. classified Section 3. Composition/information on ingredients Substance/mixture : Mixture Other means of : Not available. identification CAS number/other identifiers Ingredient name % by weight CAS number Titanium Dioxide 210 - $25 Crystalline Silica, respirable powder 13463-67-7 S10 Zinc Oxide 14808-60-7 $3 1314-13-2 Any concentration shown as a range is to protect confidentiality or is due to batch variation, There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to heaith and hence require reporting in this section. Occupational! exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband, Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes, Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. if vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. /f unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Date of issue/Date of revision : 8/24/2019 Date of previous issue 14/17/2019 Lxo2ws50 Version :8.04 LOXON® Concrete & Masonry Primer/Sealer a2 Section 4. First aid measures Most important symptoms/effects. acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards, inhalation : No known significant effects or critical hazards. Skin contact > No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : No specific data. Inhalation : No specific data. Skin contact : No specific data. Ingestion : No specific data. Indication of immediate medical attention and special treatment needed. if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If itis suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves, See toxicological information (Section 11) Section 5. Fire- ighting measures Extinguishing media Suitable extinguishing : media Use an extinguishing agent suitable for the surrounding fire. Unsuitable extinguishing > None known. media Specific hazards arising : Ina from the chemical fire or if heated, a pressure increase will occur and the container may burst. Hazardous thermal : decomposition products Decomposition products may include the following materials: metal oxide/oxides Special protective actions : for fire-fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : equipment for fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency > personnel No action shall be taken involving any personal risk or without suitable training. “~~ Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or Provide mist. adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information Section 8 on in emergency personnel”. suitable and unsuitable materials. See also the information in "For non- Date of issue/Date of revision 15/24/2019 Date of previous issue 24/17/2019 Version Lxo2wso LOXON® Concrete & :5.04 Masonry Primer/Seater 12 t Section 6. Accidental release measures Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers, Inform the relevant authorities if the product has caused environmental Pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area, Dilute with water and mop up if water-soluble, Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area, Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash Spillages into an effluent treatment plant or proceed as follows. Contain and collect Spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal Protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have vapor or mist. been read and understood. Do not get in eyes or on skin or clothing. Do not breathe Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : occupational hygiene Eating, drinking and smoking should be prohibited in areas where this Material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, : including any Store in accordance with local regulations. Store in original container protected from incompatibilities direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits (OSHA United States) Ingredient name Exposure limits Titanium Dioxide ACGIH TLV (United States, 3/2018). TWA: 10 mg/m? 8 hours. OSHA PEL (United States, 5/201 8). Crystalline Silica, TWA: 15 mg/m? 8 hours. Form: Total dust respirable powder OSHA PEL Z3 (United States, 6/201 6). TWA: 250 mppcf / (%Si02+5) 8 hours. Form: Respirable TWA: 10 mg/m? / (%Si02+2) 8 hours. Form: Respirable OSHA PEL (United States, 5/2018). TWA: 50 jig/m? 8 hours. Form: Respirable Date of issue/Date of revision 76/24/2019 Date of previous issue 24/17/2019 Version Lxo2wso LOXON® Concrete & Masonry Primer/Seater :5.04 4/12 r . Section 8. Exposure controls/personal protection dust ACGIH TLV (United States, 3/201 8). TWA: 0.025 mg/m? 8 hours. Form: Respirable fraction NIOSH REL (United States, 10/2016). TWA: 0.05 mg/m? 10 hours. Form: respirabie dust Zinc Oxide NIOSH REL (United States, 10/2016). CEIL: 15 mg/m? Form: Dust TWA: 5 mg/m* 10 hours. Form: Dust and fumes STEL: 10 mg/m? 15 minutes. Form: Fume OSHA PEL (United States, 5/201 8). TWA: 5 mg/m? 8 hours, Form: Fume TWA: 5 mg/m? 8 hours. Form: Respirable fraction TWA: 15 mg/m? 8 hours. Form: Total dust ACGIH TLV (United States, 3/201 8). TWA: 2 mg/m* 8 hours. Form: Respirable fraction STEL: 10 mg/m? 15 minutes. Form: Respirable fraction Occupational exposure limits (Canada) ingredient name Exposure limits Titanium dioxide CA British Columbia Provincial (Canada, 7/2018). TWA: 3 mg/m? 8 hours. Form: Respirable dust TWA: 10 mg/m? 8 hours. Form: Total dust CA Quebec Provincial (Canada, 1/2014). TWAEV: 10 mg/m® 8 hours. Form: Total dust. CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 10 mg/m? 8 hours. CA Ontario Provincial (Canada, 1/201 8). TWA: 10 mg/m? 8 hours. CA Saskatchewan Provincial (Canada, 712013). STEL: 20 mg/m? 15 minutes. TWA: 10 mg/m? 8 hours. Quartz CA British Columbia Provincial (Canada, 712018). TWA: 0.025 mg/m? 8 hours. Form: Respirable CA Quebec Provincial (Canada, 1/2014), TWAEV: 0.1 mg/m? 8 hours. Form: Respirable dust. CA Ontario Provincial (Canada, 1/201 8). TWA: 0.1 mg/m? 8 hours. Form: Respirable fraction. CA Alberta Provincial (Canada, 6/201 8). 8 hrs OEL: 0.025 mg/m? 8 hours. Form: Respirable particulate CA Saskatchewan Provincial (Canada, 7/2013). TWA: 0.05 mg/m? 8 hours. Form: respirable fraction Zinc Oxide CA Alberta Provincial (Canada, 6/2018). 8 hrs OEL: 2 mg/m? 8 hours. Form: Respirable Date of issue/Date of revision : 8/24/2019 Date of previous issue 14/17/2019 LXO02W50 LOXON® Concrete Version :5.04 & Masonry Primer/Seaier 12 ‘ Section 8. Exposure controls/personal protection 15 min OEL: 10 mg/m? 15 minutes. Form: Respirable CA British Columbia Provincial (Canada, 7/2018). TWA: 2 mg/m? 8 hours. Form: Respirable STEL: 10 mg/m? 15 minutes. Form: Respirable CA Ontario Provincial (Canada, 1/201 8). TWA: 2 mg/m? 8 hours. Form: Respirable fraction. STEL: 10 mg/m? 15 minutes. Form: Respirable fraction. CA Quebec Provincial (Canada, 1/2014). TWAEV: 5 mg/m? 8 hours. Form: fume STEV: 10 mg/m* 15 minutes. Form: fume CA Saskatchewan Provincial (Canada, 712013). STEL: 10 mg/m? 15 minutes. Form: respirable dust and fume TWA: 2 mg/m? 8 hours. Form: respirable dust and fume Occupational exposure limits (Mexico) Ingredient name Exposure limits Crystalline Silica, respirable powder NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 0.025 mg/m? 8 hours. Form: Zinc Oxide Respirable fraction NOM-010-STPS-2014 (Mexico, 4/2046). TWA: 2 mg/m? 8 hours. Form: Respirable fraction STEL: 10 mg/m? 15 minutes. Form: Respirable fraction Appropriate engineering : controls Ifuser operations generate dust, fumes, gas, vapor or mist, use process enclosures,

Hazard pictograms

g

Signal word

Danger

Hazard statements

May cause cancer. Causes damage to organs through prolonged or repeated exposure.

Precautionary statements

General > Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear Protective gloves. Wear eye or face protection. Wear protective clothing. Do not breathe vapor. Do not eat, drink or snoke when using this product. Wash hands thoroughly after handling. revision :8/24/2019 Date of previous issue 14/17/2019 Version Lxo2wso LOXON® Concrete & Masonry Primer/Sealer :5.04 12

Response

Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention.

Storage

+ Store locked up.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

elements WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Adequate ventilation required when sanding or abrading the dried film. If Adequate ventilation cannot be provided wear an approved particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film may release Crystalline Silica which has been shown to cause lung damage and cancer under long term exposure. Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage.

2.3 Other hazards

+ None known.