95-819 PITTHANE - B

Hazard statements (CLP)

H303+H313, H317, H332, H334, H335

Code

Statements

H303+H313

May be harmful if swallowed or in contact with skin

SECTION 2: Hazards identification

Classification of the substance or mixture ACUTE TOXICITY (oral) - Category 5 ACUTE TOXICITY (dermal) - Category 5 ACUTE TOXICITY (inhalation) - Category 4 RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3

Signal word

Danger

Hazard statements

H303 + H313 - May be harmful if swallowed or in contact with skin. H317 - May cause an allergic skin reaction. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation.

Prevention

P280 - Wear protective gloves. P284 - Wear respiratory protection. P271 - Use only outdoors or in a well-ventilated area. P261 - Avoid breathing vapor. P272 - Contaminated work clothing should not be allowed out of the workplace.

Response

P304 + P340, P312 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor. P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell. P302 + P312, P352 - IF ON SKIN: Call a POISON CENTER or doctor if you feel unwell. Wash with plenty of water. P333 + P313 - If skin irritation or rash occurs: Get medical advice or attention. P362 + P364 - Take off contaminated clothing and wash it before reuse.

Storage

P405 - Store locked up. P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.

Other hazards which do not result in classification

Skin contact to isocyanate monomer may lead to allergic lung reaction. Based on the properties of the isocyanate components and considering toxicological data on similar mixtures, this mixture may cause acute irritation and/or sensitization of the respiratory system, leading to an asthmatic condition, wheezing and tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to atmospheric concentrations well below the OEL. Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Repeated exposure may lead to permanent respiratory disability. Moisture-sensitive material. Emits toxic fumes when heated. See toxicological information (Section 11)

2.1 Classification of the substance or mixture

ACUTE TOXICITY (oral) - Category 5 substance or mixture ACUTE TOXICITY (dermal) - Category 5 ACUTE TOXICITY (inhalation) - Category 4 RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3